• 한국분말재료학회지
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• 제16권5호
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• pp.316-325
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• 2009

Fe based (Fe$_{68.2}$C$_{5.9}$Si$_{3.5}$B$_{6.7}$P$_{9.6}$Cr$_{2.1}$Mo$_{2.0}$Al$_{2.0}$) amorphous powder, which is a composition of iron blast cast slag, were produced by a gas atomization process, and sequently mixed with ductile Cu powder by a mechanical ball milling process. The experiment results show that the as-prepared Fe amorphous powders less than 90 $\mu$m in size has a fully amorphous phase and its weight fraction was about 73.7%. The as-atomized amorphous Fe powders had a complete spherical shape with very clean surface. Differential scanning calorimetric results of the as-atomized Fe powders less than 90 $\mu$m showed that the glass transition, T$_g$, onset crystallization, T$_x$, and super-cooled liquid range $\Delta$T=T$_x$-T$_g$ were 512, 548 and 36$^{\circ}C$, respectively. Fe amorphous powders were mixed and deformed well with 10 wt.% Cu by using AGO-2 high energy ball mill under 500 rpm.

• 한국주조공학회지
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• 제31권1호
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• pp.26-30
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• 2011

For the fabrication of bulk near-net-shape Ti-Ni-Cu shape memory alloys, consolidation of Ti-Ni-Cu alloy powders are useful because of their brittle property. In the present study, $Ti_{50}Ni_{30}Cu_{20}$ shape memory alloy powders were prepared by gas atomization and martensitic transformation temperatures and microstructures of those powders were investigated as a function of powder size. The size distribution of the powders was measured by conventional sieving, and sieved powders with the specific size range of 25 to $150\;{\mu}m$ were chosen for this examination. XRD analysis showed that the B2-B19 martensitic transformation occurred in the powders. In DSC curves of the as-atomized $Ti_{50}Ni_{30}Cu_{20}$ powders as a function of powder size, only one clear peak was found on each cooling and heating curve. The martensitic transformation start temperature($M_s$) of the $25-50\;{\mu}m$ powders was $31.5^{\circ}C$. The $M_s$ increased with increasing powder size and the difference of $M_s$ between $25-50\;{\mu}m$ powders and $100-150\;{\mu}m$ powders is only $1^{\circ}C$. The typical microstructure of the rapidly solidified powders showed cellular morphology and very small pores were observed in intercellular regions.

• 한국자기학회지
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• 제26권1호
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• pp.7-12
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• 2016

전기비저항이 높아 1 MHz 이상 고주파용 코어재료로 적합한 Fe-9%Si-2%Cr 합금분말의 열처리 온도에 따른 투자율 거동과 규칙-비규칙 전이에 대해 연구하였다. 분무과정에서 B2 규칙상의 생성이 억제되지 않았으며, $550^{\circ}C$ 이상에서 열처리 했을 경우 $DO_3$ 상의 회절선을 검출할 수 있었다. 열처리 온도가 증가할수록 격자상수와 보자력은 감소하였으나 $450^{\circ}C$에서 보자력의 갑작스런 큰 증가가 있었다. $150^{\circ}C$의 비교적 낮은 열처리 온도에서 가장 높은 투자율을 나타내었고, 이후 열처리 온도가 증가할수록 투자율은 감소하였다. 이상의 거동은 $DO_3$ 규칙상의 생성과 이에 따른 비저항의 변화로 설명할 수 있었다.

• 한국주조공학회지
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• 제41권3호
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• pp.235-240
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• 2021

진공 가스분사법으로 제조된 Fe₇₅B₁₃P₅Nb₂Hf₁C₄ 합금의 응고중 액상의 크기와 이에 따른 냉각속도의 변화가 정출상의 형성에 미치는 영향에 대한 고찰을 하였다. 고온 액상에서 동일한 조건으로 응고된 서로 다른 크기의 액상이 구형의 분말형태로 응고될 때 크기에 따른 임계냉각속도의 차이를 계산하였으며, 액상의 평균 반지름이 3배정도 크기 차이가 날 경우 고상으로 변태할 때 임계냉각속도가 13.5배까지 차이가 나는 것을 알 수 있었다. 이러한 임계냉각 속도의 차이에 따른 정출상의 형성과 정출상의 형태와 크기에 따른 탄화물의 형성 거동을 조사하여 열역학 계산으로 예측된 결과와 비교 분석하였으며, 분말입자의 크기가 20~45 마이크론일 경우 Hf과 Nb이 포함된 MC타입의 탄화물이 초정으로 형성 되는 것을 알 수 있었으며 이때 Hf과 Nb의 비율은 합금의 조성 및 냉각속도에 따라 변화됨을 관찰 할 수 있었다.

• 한국분말재료학회지
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• 제15권2호
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• pp.142-147
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• 2008

The hypereutectic Al-20 wt%Si powders including some amount of Cu, Fe, Mg, Mn were prepared by a gas atomization process. In order to get highly densified Al-Si bulk specimens, the as-atomized and sieved powders were extruded at $500^{\circ}C$, Microstructure and tensile properties of the extruded Al-Si alloys were investigated in this study. Relative density of the extruded samples was over 98%. Ultimate tensile strength (UTS) in stress-strain curves of the extruded powders increased after T6 heat treatments. Elongation of the samples was also increased from 1.4% to 3.2%. The fracture surfaces of the tested pieces showed a fine microstructure and the average grain size was about $1{\mu}m$.

• 한국분말재료학회지
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• 제29권2호
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• pp.99-109
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• 2022

Powder flowability is critical in additive manufacturing processes, especially for laser powder bed fusion. Many powder features, such as powder size distribution, particle shape, surface roughness, and chemical composition, simultaneously affect the flow properties of a powder; however, the individual effect of each factor on powder flowability has not been comprehensively evaluated. In this study, the impact of particle shape (sphericity) on the rheological properties of Ti-6Al-4V powder is quantified using an FT4 powder rheometer. Dynamic image analysis is conducted on plasma-atomized (PA) and gas-atomized (GA) powders to evaluate their particle sphericity. PA and GA powders exhibit negligible differences in compressibility and permeability tests, but GA powder shows more cohesive behavior, especially in a dynamic state, because lower particle sphericity facilitates interaction between particles during the powder flow. These results provide guidelines for the manufacturing of advanced metal powders with excellent powder flowability for laser powder bed fusion.

• 한국분말재료학회지
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• 제24권2호
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• pp.115-121
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• 2017

In this work, p-type Bi-Sb-Te alloys powders are prepared using gas atomization, a mass production powder preparation method involving rapid solidification. To study the effect of the sintering temperature on the microstructure and thermoelectric properties, gas-atomized powders are consolidated at different temperatures (623, 703, and 743 K) using spark plasma sintering. The crystal structures of the gas-atomized powders and sintered bulks are identified using an X-ray diffraction technique. Texture analysis by electron backscatter diffraction reveals that the grains are randomly oriented in the entire matrix, and no preferred orientation in any unique direction is observed. The hardness values decrease with increasing sintering temperature owing to a decrease in grain size. The conductivity increases gradually with increasing sintering temperature, whereas the Seebeck coefficient decreases owing to increases in the carrier mobility with grain size. The lowest thermal conductivity is obtained for the bulk sintered at a low temperature (603 K), mainly because of its fine-grained microstructure. A peak ZT of 1.06 is achieved for the sample sintered at 703 K owing to its moderate electrical conductivity and sustainable thermal conductivity.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2004년도 International Symposium on Powder Materials and Processing
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• pp.100-101
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• 2004

• 한국분말재료학회지
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• 제9권3호
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• pp.153-160
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• 2002

A nitrogen gas atomized aluminum powder was consolidated by powder-in sheath rolling method. A pure aluminum tube with outer diameter of 12 mm and wall thickness of 1mm was used as a sheath. The aluminum tube filled with the aluminum powder, first, was cold-rolled to the thickness of 6mm for performing, and then consolidated by the cold rolling and/or subsequent hot rolling at 360, 460 and $560^{\circ}C$. The aluminum powder compact fabricated by the sheath rolling showed high relative density more than 0.96 at any rolling conditions. The 0.2% proof stress increased with increasing hot rolling reduction and hot rolling temperature. Tensile strength was hardly affected by change in the hot rolling reduction, whereas it decreased with increasing hot rolling temperature. The powder compact showed the large elongation when cold rolling or hot rolling reduction was large. It was found that the sheath rolling was an effective method for consolidation of aluminum powder.

• 한국분말재료학회지
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• 제1권1호
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• pp.85-94
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• 1994

In order to predict droplet velocity and temperature profiles and fractional solidification with flight distance during spray forming, the Newtonian heat transfer formulation has been coupled with the classical heterogeneous nucleation and the specific solidification process. It has been demonstrated that the thermal profile of the droplet in flight is significantly affected by process parameters such as droplet size, initial gas velocity, undercooling. As the droplet size and/or the initial gas velocity increase, the onset and completion of solidification are shifted to greater flight distances and the solidification process also extends over a wider range of flight distances. The amounts of solid fractions formed during recoalescence, segregated solidification and eutectic solidification are insensitive to droplet size and initial gas velocity whereas those are strongly affected by the degree of undercooling. There are good linear relations between the undercooling and the corresponding solid fractions generated during recoalesced, segregated and eutectic stages.