• Title/Summary/Keyword: gas volume

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Physicochemical properties of rice-distilled spirit matured in oak and stainless steel containers (숙성용기를 달리한 전통 쌀 증류식 소주의 숙성 중 이화학 특성 및 향기성분의 변화)

  • Kang, Sun-Hee;Kim, Jae-Ho;Lee, Ae-Ran;Kim, A-Ra;Kim, Tae-Wan
    • Korean Journal of Food Science and Technology
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    • v.49 no.4
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    • pp.369-376
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    • 2017
  • Maturation of distilled spirit can generate diverse flavors and tastes. Rice Soju was matured in oak casks (MSO) and stainless steel containers (MSS) for one year at ambient temperature. Ipguk (Aspergillus luchuensis) and Saccharomyces cerevisiae Y88-4 were used, and reduced pressure ($110{\pm}20Torr$) distillation was applied to brew Soju. Acidity and conductivity were increased in both MSO and MSS. MSO reduced alcohol content (from 43 to 40%) and volume (from 18,000 to 12,730 mL), and significantly altered yellowness (from 0.2 to 30.2). Furthermore, MSO increased the isoamyl alcohol (from 276.7 to $339.2{\mu}g/mL$) and isobutyl alcohol (from 122.3 to $144.2{\mu}g/mL$) content. Gas chromatography-mass spectrometry was used to detect volatile compounds in Soju, which included 20 esters, 7 alcohols, 2 acids, and 5 miscellaneous compounds. Oak lactone was detected only in MSO and was considered as a specific flavor component associated with oak maturation. Thus, maturation materials contribute to the physicochemical property of distilled spirits.

A Numerical Study on the Extinguishing Effects of CO2 in Counterflow Diffusion Flames with the Concept of Local Application System (국소방출방식 개념의 대향류 확산화염에서 CO2 소화효과에 관한 수치해석 연구)

  • Mun, Sun-Yeo;Park, Chung-Hwa;Hwang, Cheol-Hong;Oh, Chang-Bo
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.55-62
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    • 2012
  • The suppression mechanisms of carbon dioxide ($CO_2$) as a representative fire suppression agent were revisited using a counterflow diffusion flame which could be applied the concept of a local application system. To end this, the low strain rate $CH_4$/air counterflow diffusions with $CO_2$ addition in either fuel or oxidizer stream were examined numerically using detailed-kinetic chemistry. Radiative heat loss due to radiating gas species including $CO_2$ added was considered by the optically thin model (OTM). As a result, the critical $CO_2$ volume fractions in the oxidizer stream required to extinguish the flame were in good agreement with the experimental data reported in the literature, while somewhat under-prediction was observed with $CO_2$ added in the fuel stream. The surrogate agents were adopted to estimate the quantitative contribution with changing in global strain rate ($a_g$) on the flame extinguishment among pure dilution effect, thermal effects including radiation heat loss and chemical effect due to the $CO_2$ fire suppression agent.

Biomonitoring of Toxic Effects of Pesticides in Occupationally Exposed Individuals

  • Arshad, Muhammad;Siddiqa, Maryam;Rashid, Saddaf;Hashmi, Imran;Awan, Muhammad Ali;Ali, Muhammad Arif
    • Safety and Health at Work
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    • v.7 no.2
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    • pp.156-160
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    • 2016
  • Background: Workers in pesticide manufacturing industries are constantly exposed to pesticides. Genetic biomonitoring provides an early identification of potential cancer and genetic diseases in exposed populations. The objectives of this biomonitoring study were to assess DNA damage through comet assay in blood samples collected from industry workers and compare these results with those of classical analytical techniques used for complete blood count analysis. Methods: Samples from controls (n = 20) and exposed workers (n = 38) from an industrial area in Multan, Pakistan, were subjected to various tests. Malathion residues in blood samples were measured by gas chromatography. Results: The exposed workers who were employed in the pesticide manufacturing industry for a longer period (i.e., 13-25 years) had significantly higher DNA tail length ($7.04{\mu}m$) than the controls ($0.94{\mu}m$). Workers in the exposed group also had higher white blood cell and red blood cell counts, and lower levels of mean corpuscular hemoglobin (MCH), MCH concentration, and mean corpuscular volume in comparison with normal levels for these parameters. Malathion was not detected in the control group. However, in the exposed group, 72% of whole blood samples had malathion with a mean value of 0.14 mg/L (range 0.01-0.31 mg/L). Conclusion: We found a strong correlation ($R^2=0.91$) between DNA damage in terms of tail length and malathion concentration in blood. Intensive efforts and trainings are thus required to build awareness about safety practices and to change industrial workers' attitude to prevent harmful environmental and anthropogenic effects.

The Study of Fermented Chestnut Meal and Its Rumen Fermentation Characteristics (밤의 부위별 발효사료 제조 및 이들의 반추위 내 발효특성에 관한 연구)

  • Joo, Young-Ho;Kim, Dong-Hyeon;Lee, Hyuk-Jun;Lee, Seong-Shin;Paradhipta, Dimas H.V.;Ha, Chang-Ju;Kim, Sam-Churl
    • Journal of Environmental Science International
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    • v.28 no.6
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    • pp.527-533
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    • 2019
  • The aim of present study was to investigate the effect of three types of Chestnut Meals (CM) on chemical composition and rumen fermentation characteristics of the fermented diet. The inoculants consisted of Lactobacillus acidophilus, Bacillus subtilis, and Sacaromyces cerevisiae and were applied to three different types of CM; Whole Chestnut (WC), endodermis (EN), and kernel (KE). All types of CMs were ensiled at $39^{\circ}C$ for 0, 1, 2, 4, or 6 days. After ensiling, the fermented CMs were sub-sampled for laboratory assays. On day six of fermentation, counts of the lactic acid-producing Bacillus subtilis, and yeast were higher (P<0.05) in WC than in the other CM types. On day four, KE had higher (P<0.05) crude protein content but lower (P<0.05) neutral detergent fiber and acid detergent fiber contents than the other treatments. In terms of rumen digestibility, KE had the highest (P<0.05) in vitro digestibility of dry matter (IVDMD), neutral detergent fiber digestibility (IVNDFD), total volatile fatty acid (VFA), propionate, butyrate concentrations, and total gas volume, as well as the lowest (P<0.05) acetate concentration. On the other hand, EN had the highest (P<0.05) pH and ammonia-N concentration in the rumen. In the rumen, even though WC application produced the highest microbial count and fermentation characteristics, it did not have a beneficial effect on rumen digestibility. Therefore, this study concluded that application of KE could be recommended due to the observed improvements in IVDMD and IVNDFD.

Formation Estimation of Shaly Sandstone Reservoir using Joint Inversion from Well Logging Data (복합역산을 이용한 물리검층자료로부터의 셰일성 사암 저류층의 지층 평가)

  • Choi, Yeonjin;Chung, Woo-Keen;Ha, Jiho;Shin, Sung-ryul
    • Geophysics and Geophysical Exploration
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    • v.22 no.1
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    • pp.1-11
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    • 2019
  • Well logging technologies are used to measure the physical properties of reservoirs through boreholes. These technologies have been utilized to understand reservoir characteristics, such as porosity, fluid saturation, etc., using equations based on rock physics models. The analysis of well logs is performed by selecting a reliable rock physics model adequate for reservoir conditions or characteristics, comparing the results using the Archie's equation or simandoux method, and determining the most feasible reservoir properties. In this study, we developed a joint inversion algorithm to estimate physical properties in shaly sandstone reservoirs based on the pre-existing algorithm for sandstone reservoirs. For this purpose, we proposed a rock physics model with respect to shale volume, constructed the Jacobian matrix, and performed the sensitivity analysis for understanding the relationship between well-logging data and rock properties. The joint inversion algorithm was implemented by adopting the least-squares method using probabilistic approach. The developed algorithm was applied to the well-logging data obtained from the Colony gas sandstone reservoir. The results were compared with the simandox method and the joint inversion algorithms of sand stone reservoirs.

Evaluation of Decomposition Characteristics of Organochlorine Pesticides Using Thermal Method (열적방법을 활용한 유기염소계 폐농약의 분해 특성 평가)

  • Kwon, Eun-Hye;Yoon, Young-Sam;Bea, Ji-Su;Jeon, Tae-Wan;Lee, Young-Ki
    • Journal of Korea Society of Waste Management
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    • v.35 no.8
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    • pp.744-753
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    • 2018
  • The Stockholm Convention, which was adopted in Sweden in 2001 to protect human health and the environment, includes regulations for Persistent Organic Pollutant Rotors such as toxic and bioaccumulatives. Currently, there are 28 types of materials. This prohibits and limits the production, use, and manufacture of products. Korea is a member of the Convention, and it is necessary to prepare management and treatment plans to address the POP trends. Thus, we experimentally investigate whether the environmentally stable incineration is achieved when the sample is thermally treated using the Lab-scale (1 kg/hr). The target samples is pesticides in liquid phase and solid phase. In this study, organic chlorinated pesticides and their thermal characteristics were analyzed. We calculated the theoretical air volume based on the element analysis results. Because the interior of the reactor is small, more than 10 times of the air ratio was injected. The retention time was set to at least 4 seconds using a margin. The incineration temperature was $850^{\circ}C$ and $1100^{\circ}C$. Thus, we experimentally investigated whether the environmentally stable incineration was achieved when the sample was thermally treated using the Lab-scale (1 kg/hr). We analyzed five types of exhaust gas; the 02 concentration was high, but the CO amount decreased. Complete combustion is difficult because of the small size of the furnace due to the nature of Lab-scale. The organic chlorine-containing pesticide had an average decomposition rate of 99.9935%. Considering the decomposition rates of organic chlorine-containing pesticide in this study, the incineration treatment at over 2 ton/hour, which is typical for a conventional incinerator, is possible. Considering the occurrence of dioxins and unintentional persistent organic pollutants, it can operate at more than $1,100^{\circ}C$.

Analysis of Components to Determine Illegal Premium Gasoline (가짜 고급휘발유 판정을 위한 성분 분석)

  • Lim, Young-Kwan;Kang, Byung-Seok;Lee, Bo-O-Mi;Park, So-Hwi;Park, Jang-Min;Go, Young-Hoon;Kim, Seung-Tae;Kang, Dea-Hyuk
    • Tribology and Lubricants
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    • v.37 no.6
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    • pp.232-239
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    • 2021
  • Petroleum is the most consumed energy source in Korea with a usage rate of 38.7% among the available primary energy sources. The price of liquid petroleum products in Korea includes taxes such as transportation·environment·energy tax. Thus, illegal production and distribution of liquid petroleum is widespread because of its huge price difference from that of the normal product and its tax-free nature. Generally, the illegal petroleum product is produced by mixing liquid petroleum with other similar petroleum alternatives. The two kinds of gasoline, common gasoline and premium gasoline, are being distributed in Korea. The premium gasoline is often adulterated with cheaper common gasoline that lowers the octane number of gasoline. It is possible to distinguish them with their color difference, green and yellow for different grade gasoline. However, when small volume of common gasoline is added to premium gasoline, it is difficult to determine whether premium gasoline contained common grade or not. In this study, we inspect gasoline, which is illegally produced by mixing common gasoline to premium gasoline. When the ratio of mixing common gasoline is increased, premium gasoline shows decreasing absorbance at 600 nm and 650 nm under UV-Vis spectrometer. Moreover, the detected intensity (mV·s) of green dye in high performance liquid chromatography (HPLC) was decreased by common gasoline under 0.99 correlation value. The more the common gasoline is mixed, the more olefin and naphthene are detected by gas chromatography. In addition, trimethyl pentane as octane improver, paraffin and toluene are decreased by common gasoline mixing. The findings of this study suggests that illegal petroleum can be identified by analysis of components and simulated samples.

A Study on Future Changes of Sea Surface Temperature and Ocean Currents in Northwest Pacific through CMIP6 Model Analysis (CMIP6 모형 결과 분석을 통한 북서태평양 해면수온과 해류의 미래변화에 대한 고찰)

  • JEONG, SUYEON;CHOI, SO HYEON;KIM, YOUNG HO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.4
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    • pp.291-306
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    • 2021
  • From the climate change scenario experiments of 21 models participating in Coupled Climate Model Inter-comparison Project Phase 6, future changes of sea surface temperature (SST) and Kuroshio in the Northwest Pacific were analyzed. The spatial feature of SST change was found to be related to the change of the current speed and spatial distribution of Kuroshio. To investigate the relationship between the change in latitude of the Kuroshio extension region, which flows along the boundary between the subtropical gyre and the subarctic gyre in the North Pacific, and the large-scale atmospheric circulation due to global warming, the zero-windstress curl line for each climate change experiment from 9 out of 21 models were compared. As the atmospheric radiative forcing increases due to the increase of greenhouse gases, it was confirmed that the zero-windstress curl line moves northward, which is consistent with the observation. These results indicate that as the Hadley Circulation expands to the north due to global warming, the warming of the mid-latitudes to which the Korean Peninsula belongs may be accelerated. The volume transport and temperature of the Tsushima Warm Current flowing into the East Sea through the Korea Strait also increased as the atmospheric radiative forcing increased.

Proposal of a Pilot Plant (2T/day) for Solid Fuel Conversion of Cambodian Mango Waste Using Hybrid Hydrothermal Carbonization Technology (하이브리드 수열탄화기술을 이용한 캄보디아 망고 폐기물 고형연료화 실증플랜트 (2T/day) 제안)

  • Han, Jong-il;Lee, Kangsoo;Kang, Inkook
    • Journal of Appropriate Technology
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    • v.7 no.1
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    • pp.59-71
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    • 2021
  • Hybrid hydrothermal carbonization (Hybrid HTC) technology is a proprietary thermochemical process for two or more organic wastes.The reaction time is less than two hours with temperature range 180~250℃ and pressure range 20~40bar. Thanks to accumulation of the carbon of the waste during Hybrid HTC process, the energy value of the solid fuel increases significantly with comparatively low energy consumption. It has also a great volume reduction with odor removal effect so that it is evaluated as the best solid fuel conversion technology for various organic wastes. In this study of the hybrid hydrothermal carbonization, the effect on the calorific value and yield of Cambodian mango waste were evaluated according to changes in temperature and reaction time. Through the study, parameter optimization has been sought with improving energy efficiency of the whole plant. It is decomposed in the Hydro-Carbonation Technology to Generate Gas. At this time, it is possible to develop manufacturing and production technologies such as hydrogen (H2) and methane (CH4). Based on the results of the study, a pilot plant (2t/day) has been proposed for future commercialization purpose along cost analysis, mass balance and energy balance calculations.

Prediction of Change in Growth Rate of Algae in Jinhae Bay due to Cooling Water Discharge (냉배수 방류에 따른 진해만의 해조류 성장 속도 변화 예측)

  • Park, Seongsik;Yoon, Seokjin;Lee, In-Cheol;Kim, Byeong Kuk;Kim, Kyunghoi
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.2
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    • pp.308-323
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    • 2021
  • In this study, we aimed to evaluate the environmental changes in Jinhae Bay caused by cooling water using numerical modeling. Cooling water discharge volume from the results of Case 1 (10 m3 sec-1) showed that the environmental changes in Jinhae Bay were extremely insignificant throughout the study period. In the simulation conditions of Case 2 (100 m3 sec-1), there was a decrease in water temperature of approximately 1 - 3℃ within a 5 km radius from the discharge outlet. In Case 3 (1000 m3 sec-1), a decrease in water temperature of up to 4 - 5℃ was observed within a radius of 8 km from the discharge outlet and cooling water discharge spread throughout the Bay. Growth rate of microalgae decreased by up to 15 % in November, whereas it increased by up to 6 % near the Hangam Bay in Case 3. From the above results, we confirmed that the environmental changes in Jinhae Bay due to cooling water discharged from Tongyeong LNG station are extremely insignificant. Moreover, it is expected that cooling water discharge could be utilized as a counter measure for 'red tide bloom' or 'macroalgae growth'.