• Journal of the Korean Magnetics Society
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• v.9 no.1
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• pp.29-34
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• 1999

$Y_{2.5}La_{0.5}Fe_5O_{12}$ is fabricated by a sol-gel method and the magnetic properties of single phase garnet are investigated by using X-ray diffraction, vibrating sample magnetometer, scanning electron microscopy and M$\"{o}$ssbauer spectroscopy. The single phase powders garnet was fired at 100$0^{\circ}C$ for 8 hours. The crystal structures of samples are cubic garnet. Mossbauer spectroscopy were measured from 13 K to 750 K. M$\"{o}$ssbauer spectra show that the iron exist ferric trivalence in sample. The spin wave constants were determined $B_{3/2}=0.32{\pm}0.05,\; C_{5/2}=0.18{\pm}0.05$ and Debye temperature were determined 382 K at 24(d) site and 246 K at 16(a)-site. The saturation magnetization $M_s$ of powder is 25 emu/g. 25 emu/g.

• Journal of the Korean Magnetics Society
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• v.13 no.1
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• pp.1-5
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• 2003

Magnetic and structural properties of $(CoFe_2O_4)_{1-x}(Y_3Fe_5O_{12})_x$ powders (0 $\leq$ x $\leq$ 1) grown by a conventional ceramic method were investigated using X-ray diffractormeter (XRD), scanning electron microscopy (SEM), Mossbauer spectroscopy and vibrating sample magnetometer (VSM). The XRD results for the powders annealed at 120$0^{\circ}C$ indicated that no other peak was observed except for the ones from cobalt ferrite and the garnet powder. SEM micrographs indicated that cobalt ferrite and garnet powders were aggregated and completely formed together. It was hard to identify which part of the powders was the garnet or the cobalt ferrite. Mossbauer spectra for powders grown separately and mixed mechanically consisted of sub-spectra of cobalt ferrite and garnet, however, powders annealed together had an extra sub-spectrum, which was related with the interaction between iron ions at the grain surfaces of cobalt ferrite and the garnet: cobalt ferrite and garnet particles were located very closely. The value of the saturation magnetization measured by a VSM as a function of composition ratio agreed very well with the ones based on the theoretical calculation.

• Journal of the Korean Magnetics Society
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• v.8 no.4
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• pp.203-209
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• 1998

Crystallographic and magnetic properties of single phase garnet $Y_{3-x}Bi_xFe_5O_{12}$ (x=0.0, 0.25, 0.5, 0.75, 1.0) were studied by using x-ray diffraction, Mossbauer spectroscopy and vibrating sample magnetometer (VSM). Ultra-fine polycrystalline cubic samples have been prepared by sol-gel method. The lattice constant increase linearly with increasing an amount of Bi. Annealing temperature was larger than 800 $^{\circ}C$ for the growth of a single-phase garnet powder. The second phase of garnet, $(BiFeO_3)$, was at 1000 $^{\circ}C$ for x=0.75, and 950 $^{\circ}C$ for x=1.00. From Mossbauer spectroscopy and VSM measurements, the magnetization and the coercivity were decreased and the Curie temperature $Y_{3-x}Bi_xFe_5O_{12}$(x=0.0, 0.25, 0.5, 0.75, 1.0) was slightly increased as increasing the Bi content.

• KCI Concrete Journal
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• v.11 no.3
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• pp.89-97
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• 1999

The purpose of this research is to investigate the utilization of recycled fine aggregates as a material to apply to a building finished walls or as a decorating material in combination with a polymer. The strengths of two resin mortars using recycled fine aggregates and natural fine aggregates was made. In order to improve the workability and the strength of the resin mortar with recycled fine aggregates, partial replacement of recycled fine aggregates with natural ones was made with the application of various type of fillers. The results, it show that the compressive strength and flexural strength of resin mortar using the recycled fine aggregates were about 70% to 100% of those of resin mortar using natural fine aggregates. It was enough to assure the utilization of the recycled fine aggregates as a material for the production of resin mortar. From the result of partial replacement of recycled fine aggregates with natural ones, the compressive strength was Increased from 5% to 15% and the flexural strength was much as 5% to 20% as a result of 70% substitution It was also found that the use of garnet powder shows a similar tendency in the compressive strength and slag powder does in the flexural strength and tensile strength.

• Journal of the Mineralogical Society of Korea
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• v.22 no.4
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• pp.353-358
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• 2009

The ability of natural abrasives which were recovered from CRT glass polishing process was evaluated. Comparing the center line average roughness values of a glass polished with new pumice (Ra = $0.039{\mu}m$) and with new garnet (Ra = $0.031{\mu}m$), the glass surface polished with the recycled pumice and the garnet had less pits on the surface with smaller Ra values (Ra = $0.025{\mu}m$ for recycled pumice and Ra = 0.029 for recycled garnet). Recycled rouge contains amorphous glass fragments so that it should be used as a cement replacement rather than recycle into an abrasive. Nnatural abrasives, pumice and garnet powder, which are used in CRT glass polishing process can be recycled into abrasives so that it can help to minimize costs and environmental impact from the production of abrasives and the disposal of waste sludge.

• Magazine of the Korea Concrete Institute
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• v.11 no.1
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• pp.183-190
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• 1999

This paper investigated the possibility of appling to concrete through fundamental experiment for garnet, which was industrial wastes generated in kyung pook region, in aspects of development of new materials and recycling of industrial wastes due to shortage of natural resources. Consequently, garnet powder showed the possibility of admixture as showed in the chemical composition because the content of silica and alumina in relation to pozzolanic activity was about 50%. The time of setting was more or less diminished as the increasing of replacement ratio of garnet. In flow test, flow values tended to increase to some degree as the increasing of replacement ratio of garnet. Therefore, application of garnet was expected to improve the workability of concrete. The compressive strength of mortar replaced by garnet was respectively increased as compared with plain mortar and the maximum strength was showed in replaced by 10%, however a little different to the change of W/B ratio. Also, the possibility of admixture to reduce the amount of cement and to improve the property of concrete was showed as the strength of mortar replaced by garnet was comparable to that by existing admixture(silica fume, fly-ash).

• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.2917-2921
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• 2014

Cerium-activated yttrium aluminate ($Y_3Al_5O_{12}:Ce^{3+}$) exhibiting a garnet structure has been widely utilized in the production of light emitting diodes (LEDs) as a yellow emitting phosphor. The commercialized yttrium aluminum garnet (YAG) phosphor is typically synthesized by a solid-state reaction, which produces irregular shape particles with a size of several tens of micrometers by using the top-down method. To control the shape and size of particles, which had been the primary disadvantage of top-down synthetic methods, we synthesized YAG:Ce nanoparticles with a diameter of 500 nm using a coprecipitation method under the atmospheric pressure without the use of template or special equipment. The precursor particles were formed by refluxing an aqueous solution of the nitrate salts of Y, Al, and Ce, urea, and polyvinylpyrrolidone (55 K) at $100^{\circ}C$ for 12 h. YAG:Ce nanoparticles were formed by the calcination of precursor particles at $1100^{\circ}C$ for 10 h under atmospheric conditions. The phase identification, microstructure, and photoluminescent properties of the products were evaluated by X-ray powder diffraction, scanning electron microscopy, absorption spectrum and photoluminescence analyses.

• Korean Journal of Materials Research
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• v.6 no.3
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• pp.275-281
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• 1996

YIG 전구체 분말은 요소의 열분해반응을 이용한 균일침전법에 의해서 질산염으로부터 제조하였다. 침전은 철이온이 먼저 침전한 후 이트륨이온이 침전하는 과정으로 이루어졌다. YGI전구체 분말은 철산화물과 비정질로 구성되어 있으며 그 분말의 대략적인 화학식은 2.5Fe2O3.Y3(OH)9-2x(CO3)x.nH2O로 되어있다. YIG 전구체 분말의 열분해과정은 dehydration, 철산화물의 recrystallization, yttrium carbonate 및 yttrium oxide의 형성과 고상반응등 여러단계로 구성되어 있다. 열처리온도가 증가함에 따라 Y2O3와 Fe2O3의 고상반응에 의해 YFeO3 intermediate을 경유해서 YIG상이 형성됨을 확인하였다. 단일상의 YIG는 120$0^{\circ}C$에서 6시간 공기중에서 소성함에 의해서 얻을 수 있었다.

• Journal of the Korean Ceramic Society
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• v.35 no.4
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• pp.413-419
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• 1998

${\beta}$-silicon carbides with yttrium aluminum garnet of 2,5,10 mol% were prepared by a liquid--phase sint-ering and the microstructural evolution and phase transformation were investigated during sintering as functions of liquid-phase amount and sintering time. The rate of grain growth decreases with the addition of the amount of yttrium aluminum garnet (YAG) in the SiC starting powder however the apparent density and the aspect ratio of grains in sintered body increase. The phase transformation from ${\beta}$-SiC to ${\alpha}$-SiC were dependent on the liquid-phase amount and sintering time.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.36-39
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• 2003

In this study, we made the high strength light weight concrete which was composed of the garnet minute powder to be the industry by-product in the YoungJoo region and the artificial light weight aggregate which the high temperature(1100℃) plastic process. The characteristic of the autogenous shrinkage had been considered about strength characteristic and the age passage In the following addition: The concrete's each unit quantity was determined 145,160,175㎏f/㎥.w/b and s/a was determined 30%, 43%, 45%. the each garnet's substitution ratio was determined 0, 10%. In this results, the compressive strength appeared greatly as the unit joining discretion grew bigger. The autogenous shrinkage ratio was increased rapidly until 7th day but it was reduced after 7th day regardless of the mixed factor. The autogenous shrinkage ratio which follows the change of the unit quantity and s/a increased together as the unit quantity and the s/a increases.