• 폴리머
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• 제39권1호
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• pp.71-77
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• 2015

본 연구에서는 전자가 풍부한 구조단위(dithienosilole 및 benzodithiophene)와 전자가 부족한 구조단위(difluorobenzothiadiazole)를 주사슬에 교대로 갖는 작은 밴드갭 공중합체를 Stille 짝지움 반응을 이용하여 합성하였다. $^1H$ NMR을 통하여 각 단계별 화합물과 고분자의 구조를 확인하였다. GPC, TGA, UV-vis 분광분석기 및 cyclic voltammetry를 이용하여 합성한 고분자의 특성을 조사하였다. 합성한 공액고분자와 $PC_{70}BM$을 1:1.5, 1:2, 1:3, 1:3.5 및 1:4의 중량비로 혼합하여 ITO/PEDOT:PSS/polymer:$PC_{70}BM/Al$의 구조로 유기태양전지 소자를 제작하여 그 광전특성을 조사하였다. 고분자:$PC_{70}BM$의 혼합비율이 1:3에서 최고 1.0%의 광전변환효율이 달성되었다. TEM 실험을 통하여 1:3 혼합비율에서 유기태양전지에 가장 적합한 나노규모로 상분리가 일어났으며, 다른 혼합비율에서는 고분자와 $PC_{70}BM$의 뭉침현상에 기인하여 태양전지 특성이 낮아졌다.

• 한국강구조학회 논문집
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• 제22권2호
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• pp.109-119
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• 2010

600MPa급 고강도 강관은 항복강도와 항복비에 대한 제한이 따른다. 현재 여러 기준에는 항복강도 360MPa 이하, 항복비 80% 이하를 사용하도록 권장하고 있다. 한계상태에서 고강도 강재의 압축세장비가 저강도 강재보다 작아져 압축지관의 좌굴발생이 야기되기 때문에 압축좌굴에 대한 거동을 이해하는 것은 필수적이다. 또한 각형강관에 대한 많은 실험데이터는 있지만 고강도 원형강관에 대한 실험은 많지 않다. 그래서 이 논문의 주된 목적은 실험에 앞서 원형강관을 유한요소 해석을 통하여 압축 좌굴과 고강도 강재의 접합부 한계상태식에 대한 검증을 통하여 600MPa와 400MPa 강재의 사용성을 알고자 하는 것이다. 이 해석은 구조물의 거동을 이해하기 위하여 폭두께비, 지관각도, 항복비, 편심을 주된 변수로 하여 범용프로그램인 아바쿠스를 사용하여 해석을 수행하였다. 그 결과 같은 하중에서 고강도 강재의 압축지관은 탄성좌굴이 발생하고 저강도 강재는 비탄성좌굴이 발생하는 것을 확인하였고 항복비가 80%이상인 경우 접합부가 취성파괴 되었다. 그리고 고강도 강재에서 주강관의 폭두께비를 변화시켰을 때 주관과 지관의 상대적인 폭두께비로 인해 해석값이 기준값보다 감소함을 알 수 있었다. 그러나 그 외 변수들로 인한 해석상 고강도 강재의 접합부 하중의 변화는 없는 것으로 확인하였다.

• 한국가스학회지
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• 제23권3호
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• pp.1-6
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• 2019

본 연구는 폐기물 소각로에서 질소산화물 저감을 위해 고온의 배기가스를 연소로에서 재순환하여 연소용 공기와 혼합하여 배기가스 재순환을 이용한 방법에서 고온의 배기가스를 별도의 동력 팬이 없이 코안다 노즐을 이용한 배기가스 재순환 장치에 관한 연구이다. 코안다 노즐에서 공기 공급 노즐 간극의 변화와 공기 공급 노즐의 위치에 따른 배기가스 재순환 유량 특성과 혼합 가스의 출구에서 평균온도 변화를 살펴보았다. 공기 공급 노즐의 간극이 3.22, 4.03, 4.84 mm로 변할 때 가장 좁은 3.22 mm일 때가 배기가스 재순환 유량과 공기 공급 유량의 비인 배기가스 재순환 유량비가 2.227로 가장 재순환 유량이 크게 나타났고 혼합가스 평균 온도는 $594.8^{\circ}C$로 나타났다. 공기 공급 노즐의 위치가 코안다 노즐 목의 전방 위치, 목 위치, 확관 위치로 변할 때를 살펴보았으며 전방 위치와 목 위치일 때는 재순환 유량비가 1.843으로 거의 같은 값이고 확관 위치에서는 1.696으로 나타났으며 평균 온도는 $559.8^{\circ}C$와 $544.3^{\circ}C$로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.393-397
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• 2012

We report a new route to synthesize high quality zinc blende CdS and ZnS nanocrystals in noncoordinating solvent 1-octadecene, using dodecanethiol (DDT) molecules as both the sulfur source and surface capping ligands. Different reaction temperatures and Cd(Zn)/DDT molar ratios were tested to optimize the synthesis conditions. Absorption photoluminescence (PL) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) pattern, and transmission electron microscopy (TEM) were used to characterize assynthesized nanocrystals. The narrow half width at the half-maximum on the long wavelength side of the firstexcitonic absorption peak and TEM images demonstrated nearly monodisperse size distributions of asprepared CdS, ZnS, and CdS/ZnS core/shell nanocrystals. Only trap emissions of the nanocrystals were detected when the amount of DDT was excessive, this came from the strong quenching effect of thiol groups on the nanocrystal surfaces. After overcoating with ZnS shells, band-gap emissions of CdS nanocrystals were partially recovered.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.267.2-267.2
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• 2016

Semiconductor photo-catalysis offers the potential for complete removal of toxic chemicals through its effective and broad potential applications. Various new compounds and materials for chemical catalysts were synthesized in the past few decades. As one of the most important II-VI group semiconductors, zinc sulfide (ZnS) with a wide direct band gap of 3.8 eV has been extensively investigated and used as a catalyst in photochemistry, environmental protection and in optoelectronic devices. In this work, the ZnS films and nanostructures have been successfully prepared by wet chemical method. We show that the agglomerates with four successive scales are always observed in the case of the homogeneous precipitation of zinc sulfide. Hydrodynamics plays a crucial role to determine the size of the largest agglomerates; however, other factors should be invoked to interpret the complete structure. In addition, studies of the photocatalytic properties by exposure to UV light irradiation demonstrated that ZnS nanocrystals (NCs) are good photo-catalysts as a result of the rapid generation of electron-hole pairs by photo-excitation and the highly negative reduction potentials of excited electrons. A combination of their unique features of high surface-to volume ratios, carrier dynamics and rich photo-catalytic suggests that these ZnS NCs will find many interesting applications in semiconductor photo-catalysis, solar cells, environmental remediation, and nano-devices.

• 복식
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• 제65권6호
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• pp.48-62
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• 2015

Practice is essential in art and design. Through practice, artists gain tacit knowledge that is hard to acquire from conventional academic studies. This paper characterizes practice-led research in the study of fashion and textile design through the investigation of practice-led research theses in the UK. According to relevant literature, which includes four exemplary case studies, the following features can be drawn: First, the methodology is different in each case and the use of practice is unconventional. Second, the research is not always aimed at making products. Third, the structure follows an iterative process. Fourth, the ratios of theory and practice are different and various theories are used. Fifth, a personal journal or diary is used for reflection as a major aid to research. Lastly, the process should be recorded by a thorough academic method. Practice-led research can have unexpected outcomes in theory and practice. It can be a good option for fashion practice research to develop a better evaluation method and reduce the gap between subjectivity and objectivity.

• 대한기계학회논문집B
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• 제21권1호
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• pp.1-14
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• 1997

Natural convection cooling of discrete heaters located in a two-dimensional vertical open top cavity is investigated experimentally. The five discrete heaters with same heat generation are located on the wall of the cavity. The heaters are arranged in two configurations; flush-mounted on a vertical wall and protruding from the wall about 4.5 mm. The materials used for the vertical walls are copper and epoxy-resin, and air is used as the cooling fluid. The temperature and flow fields in the cavity were visualized by means of Mach-Zehnder interferometer and smoke-method. Also, local temperature measurements are made along the vertical wall. Results are obtained for cavity aspect ratios of 4.6, 7.5 and 9.5 and modified Rayleigh numbers ranging from 10$^{3}$ to 10$^{6}$ . Results indicate that the cooling efficiency for the copper wall is superior to that of the epoxy-resin. For the epoxy-resin wall, the protrusion of the heaters plays a role in decreasing the heat transfer performance. The location of maximum temperature is significantly influenced by the wall materials and heater configurations. Correlations relating the Nusselt number to the modified Rayleigh number are proposed.

• 한국작물학회지
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• 제52권1호
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• pp.55-59
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• 2007

This experiments were conducted to evaluate suitable plant-type and cultivars for producing fresh pod peanut from late seeding as succeeding crop, compared with early seeding as proceeding crop or single cropping. 12 cultivars according to grain weight and plant types, 6 virginia typed cultivars(ssp. hypogaea) and 6 shinpung typed cultivars(ssp. fastigiata), were used for early and late seedings. The plant growth and yield potential in early seeding were better than those in late seeding. But the ratios of dry/fresh pod and of mature pod in late seeding were higher than those of early seeding. The yield of fresh pod by cultivars in two seeding times showed significant correlation with pod scale such as fresh pod weight, 100-grain weight, and dry seed yield positively, but pod number negatively in early seeding only. Yield of fresh peanut between Virginia and Shinpung types didn't show significant difference in early seeding, but showed in late seeding. Average yield of Virginia typed cultivars showed significantly higher than that of Shinpung typed ones. This yield gap between two plant types was the same tendency on extending seedings to July 20.

• 한국정밀공학회지
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• 제27권11호
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• pp.17-23
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• 2010

Titanium alloy is one of the hard processing materials made by the traditional manufacturing method because of the excellent mechanical strength. Ablation of titanium alloy is investigated by using a femtosecond laser which is a regenerative amplified Ti:sapphire laser with 1kHz repetition rate, 184fs pulse duration time and 785nm wavelength. Experiments are carried out under various ablation conditions with different pulse overlap ratios for the rectangular shape and micro hole. Test results show that the ablation characteristic according to pulse overlap ratio of titanium alloy seems to be as non-linear type at the different zone of energy fluence. The optimal condition of rectangular shape processing is obtained at the laser peak power 1.3mW, pulse overlap ratio of 90%, beam gap of $1\;{\mu}m$. The micro hole has a good quality from the pulse overlap ratio of 99% at the same laser peak power. With the optimal processing condition, the fine rectangular shape and micro hole without burr and thermal damage are achieved.

• 대한기계학회논문집A
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• 제33권8호
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• pp.793-798
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• 2009

In this paper, the simulation and optimization of SRH (Surface Relief Hologram) masks for printing LCD gate patterns using TIR (Total Internal Reflection) holographic lithography was investigated. A simulation and optimization algorithm based on SDTA (Scalar Diffraction Theory Analysis) method was developed. The accuracy of the algorithm was compared to that of the RCWA (Rigorous Coupled Wave Analysis) method for estimating the Fresnel diffraction pattern of Cr amplitude masks for the given system geometry. In addition, the results from the optimization algorithm were validated experimentally. It was found that one to the most important conditions for the fabrication of SRH masks is to avoid nonlinear shape distortions of the resulting grating. These distortions can be avoided by designing SRH masks with recorded gratings having small aspect ratios of width versus depth. The optimum gap size between the Cr and SRH masks was found using the optimization algorithm. A printed LCD gate pattern with a minimum line width of $1.5{\mu}m$ exposed using the optimized SRH mask was experimentally demonstrated.