• 제목/요약/키워드: galvanic

검색결과 351건 처리시간 0.023초

인공해수 침지조건에 따른 부식촉진시험과 염화물침투해석에 대한 연구 (A Study of Accelerated Corrosion Test and Chloride Penetration Analysis with Artificial Seawater Immersion Condition)

  • 박상순;정지원
    • 한국구조물진단유지관리공학회 논문집
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    • 제18권1호
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    • pp.93-100
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    • 2014
  • 해수중 환경에서 콘크리트 구조물 내에 매립된 철근은 용존산소의 부족으로 부식이 잘 발생하지 않는다. 이 때문에 해수중 환경의 부식촉진시험은 전기화학적인 방법으로 실시되어, 실제 부식 메커니즘과 맞지 않고 장기거동과의 상관성 도출도 어려운 실정이다. 본 연구에서는 해수중 환경에서의 부식촉진시험법을 정립하기 위해 온도와 염화물농도를 주된 변수로 부식촉진시험을 실시하였다. 부식의 발생 유무는 갈바닉 전위측정법과 반전지전위법을 통한 철근부식모니터링 결과로 판단하였다. 부식촉진시험 결과 온도의 영향이 가장 지배적이라고 평가되었다. 염화물량은 시험 시편의 깊이별 염화물 농도를 측정하였다. 동일한 조건으로 FEM 내구성 해석 프로그램인 DuCOM을 통해 염화물침투 해석을 실시하여 입증하였다. 또한, 인공해수 침지 조건에 따른 용존 산소량은 실험을 통해 구했으며 이를 통해 부식촉진시험 결과의 타당성을 검증하였다.

Synergistic Effect of Molybdate and Monoethanolamine on Corrosion Inhibition of Ductile Cast Iron in Tap Water

  • Kim, K.T.;Chang, H.Y.;Lim, B.T.;Park, H.B.;Kim, Y.S.
    • Corrosion Science and Technology
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    • 제16권1호
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    • pp.31-37
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    • 2017
  • A synergistic effect was observed in the combination of nitrite and ethanolamines. Ethanolamine is one of the representative organic corrosion inhibitors and can be categorized as adsorption type. However, nitrosamines can form when amines mix with sodium nitrite. Since nitrosamine is a carcinogen, the co-addition of nitrite and ethanolamine will be not practical, and thus, a non-toxic combination of inhibitors shall be needed. In order to maximize the effect of monoethanolamine, we focused on the addition of molybdate. Molybdate has been used to alternate the addition of chromate, but it showed insufficient oxidizing power relative to corrosion inhibitors. This work evaluated the synergistic effect of the co-addition of molybdate and monoethanolamine, and its corrosion mechanism was elucidated. A high concentration of molybdate or monoethanolamine was needed to inhibit the corrosion of ductile cast iron in tap water, but in the case of the co-addition of molybdate and monoethanolamine, a synergistic effect was observed. This synergistic effect could be attributed to the molybdate that partly oxidizes the metallic surface and the monoethanolamine that is simultaneously adsorbed on the graphite surface. This adsorbed layer then acts as the barrier layer that mitigates galvanic corrosion between the graphite and the matrix.

Newly Developed BioDegradable Mg Alloys and Its Biomedical Applications

  • 석현광;김유찬;;차필령;조성윤;양석조
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.55.2-55.2
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    • 2012
  • Intensive theoretical and experimental studies have been carried out at Korean Institute of Science and Technology (KIST) on controlling the bio absorbing rate of the Mg alloys with high mechanical strength through tailoring of electrochemical potential. Key technology for retarding the corrosion of the Mg alloys is to equalize the corrosion potentials of the constituent phases in the alloys, which prevented the formation of Galvanic circuit between the constituent phases resulting in remarkable reduction of corrosion rate. By thermodynamic consideration, the possible phases of a given alloy system were identified and their work functions, which are related to their corrosion potentials, were calculated by the first principle calculation. The designed alloys, of which the constituent phases have similar work function, were fabricated by clean melting and extrusion system. The newly developed Mg alloys named as KISTUI-MG showed much lower corrosion rate as well as higher strength than previously developed Mg alloys. Biocompatibility and feasibility of the Mg alloys as orthopedic implant materials were evaluated by in vitro cell viability test, in vitro degradation test of mechanical strength during bio-corrosion, in vivo implantation and continuous observation of the implant during in vivo absorbing procedures. Moreover, the cells attached on the Mg alloys was observed using cryo-FIB (focused ion beam) system without the distortion of cell morphology and its organ through the removal of drying steps essential for the preparation of normal SEM/TEM samples. Our Mg alloys showed excellent biocompatibility satisfying the regulations required for biomedical application without evident hydrogen evolution when it implanted into the muscle, inter spine disk, as well as condyle bone of rat and well contact interface with bone tissue when it was implanted into rat condyle.

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온열 환경 반응에 대한 사상체질간 차이에 대한 실험적 연구 (An Experimental Study on Individual Difference in Reaction to Mild Environment in Adult Males - On the Perspective of Sasang Constitution)

  • 김선호;이은선;김지은;박경모;이주연;최호선
    • 대한한의학회지
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    • 제26권1호
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    • pp.123-133
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    • 2005
  • Objective : We investigated the sasang constitutional difference of physiological and psychological response in various thermal environmental conditions. Methods: Among 210 volunteers, 30 healthy subjects were selected through the QSCC II (a questionnaire for constitutional discrimination) and the manual examination of a specialist in sasang constitution. Subjects consisted of 10 each Soyang(少陽), Soeum(少陰), and Taeum(太陽). Experimental environments were set by six different conditions to be $23^{\circ}C,\;50\%\;RH,\;0.lm/s;\;25^{\circ}C,\;25\%\;RH,\;0.lm/s;\;25^{\circ}C,\;50\%\;RH,\;0.lm/s;\;25^{\circ}C,\;50\%\;RH,\;0.4m/s;\;25^{\circ}C,\;75\%\;RH,\;0.1m/s;\;and\;27^{\circ}C,\;50\%\;RH,\;0.1m\s$ (respectively temperature, relative humidity, and wind velocity). Skin temperature, core temperature, heart rate variability (HRV), and galvanic skin response (GSR) were measured for each subject Additionally, subjects were asked about comfort through the questionnaire. Results: From the viewpoint of external temperature sensibility, in all experimental environments, generally the Taeum type feels hotter and the Soeum feels colder than other types. In relative comfort, Soeum types were most sensitive to wind velocity change. From the viewpoint of body temperature, Taeum type was lower and Soyang was higher than other types. The measurements of HRV and GSR showed no difference between the types. Conclusion : The four sasang constitution types showed different responses to various thermal environmental conditions. Accordingly, our research could provide basic data for building the optimal thermal conditions for individuals based on sasang constitution. Consequently, it will help to build a healthy environment for everyday life.

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열차 시뮬레이터 조작 시 운전자의 생체신호 변화에 대한 연구 (A Study on Driver's Physiological Response in Train Simulator)

  • 장혜연;장재호;김태식;한창수;한정수;안재용
    • 대한인간공학회지
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    • 제25권4호
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    • pp.129-135
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    • 2006
  • he purpose of this study is to measure bio-signal to investigate the driver's physiological response change under real situation using train simulator. The train simulator used in this study is KTX model and according to changes of driving situation, The bio-signal controlled by autonomic nervous system, such as GSR(Galvanic Skin Response), SpO2(Saturation percent O2), HR(Heart Rate), ECG(Electrocardiograph), EEG(Electroencephagram) and movement and response of eye were measured. Statistically significant difference in bio-signal data and eye movement activity pattern were investigated under several different driving speeds using analysis of variance (p<0.05). The GSR and HR value measured in average and mission speed operation is higher than in high-speed operation. β wave of EEG in average speed operation become more activated than in high speed operation. In accordance with a characteristic of rail vehicle, movement and response of eye in high-speed operation requiring relatively simple maneuver become less activated than in either average or mission speed operations. Conclusively, due to more careful driving controls in average and mission speed operation are required than in high-speed operation, level of mental and physical stresses of train driver was increased and observed through changes of bio-signal and eye movement measured in this study.

가상현실 에이전트와의 감성적 상호작용 기법 (Affective interaction to emotion expressive VR agents)

  • 최아영
    • 한국컴퓨터그래픽스학회논문지
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    • 제22권5호
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    • pp.37-47
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    • 2016
  • 최근 인간과 에이전트 간의 감성적인 상호작용을 지원하기 위해 에이전트의 기쁨, 슬픔 등의 얼굴 표정에 대한 사용자의 반응을 분석하는 연구들이 진행되었다. 그러나 기존의 연구에서는 사용자가 긍정적 혹은 부정적으로 평가하는 지를 검증하기 위해 주로 설문지를 통해 사용자 피드백을 획득하는 방법을 사용하였다. 본 연구에서는 인간과 에이전트 상호작용에서 에이전트의 얼굴 표정에 대한 사용자의 생체신호를 측정하여 감성적인 영향이 있는지 살펴보았다. 일관성 있는 생체 신호 해석 결과를 도출하기 위해 실시간으로 심박수와 피부전도도 등의 생체 신호를 획득하고, 명시적 혹은 비명시적인 피드백 분석방법을 통합하여, 해석을 안정적으로 하도록 하였다. 실험결과 에이전트의 긍정(혹은 부정)적인 얼굴 표정이 사용자의 긍정(혹은 부정)적인 반응을 이끌어 냄을 확인할 수 있었다. 또한, 인간과 에이전트와의 상호작용에서도 인간과 인간의 상호작용과 유사하게 에이전트의 긍정적인 얼굴 표정이 사용자의 부정적인 감정을 감소시킴을 확인할 수 있었다. 본 연구는 인간과 에이전트의 감성적인 상호작용을 위해 에이전트의 얼굴 표정을 디자인하기 위한 근거로 활용할 수 있다.

공포영상 및 소음자극에 의한 스트레스의 전기피부반응, 심박변이도 및 뇌파 해석 (GSR, HRV and EEG Analysis of Stress caused by Horror Image and Noise Stimulation)

  • 김민수;조영창
    • 전기전자학회논문지
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    • 제21권4호
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    • pp.381-387
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    • 2017
  • 직장에서의 스트레스는 많은 직업, 생활환경 및 연령대의 사람들에게 영향을 끼치는 심각한 문제가 되었다. 스트레스 관리는 스트레스가 질병을 일으키기 시작하기 훨씬 전에 시작해야 한다. 본 연구에서는 영상 및 소음 자극 시 발생하는 전기피부반응도, 심전도 및 뇌파를 측정하여 스트레스를 평가하는 연구를 수행하였다. GRS 진폭은 스트레스 상황이 안정 상태(baseline)보다 27.9% 높게 나타났다. 그리고 자극 후 baseline의 응답시간은 스트레스 상황보다 71.6% 이상 시간이 더 길었다. 심박변이도에서 스트레스 응답 특성은 RMSSD의 변화율이 16.4% 차이가 났으며, HF power의 변화율은 29.7% 차이를 보였다. 뇌파는 스트레스 자극 시 주파수 대역이 ${\theta}$파 대역으로 점점 변함을 알 수 있었다. 우리는 영상자극 및 소음자극이 스트레스와 상관관계를 파악함으로써 객관적지표로 활용 가능할 것이다.

Relationship between squamous cell carcinoma of the tongue and the position of dental prosthesis

  • Fan, Huan;Yoon, Ki-Yong;Kim, Soung-Min;Myoung, Hoon;Lee, Jong-Ho;Kim, Myung-Jin
    • The Journal of Advanced Prosthodontics
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    • 제7권2호
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    • pp.129-137
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    • 2015
  • PURPOSE. Squamous cell carcinoma (SCC) of the tongue has a relatively high incidence of all oral cancers. Some studies have reported a relationship between intraoral dental prosthesis and SCC of the tongue; however, this relationship remains controversial. The purpose of this study was to investigate the relationship between SCC of the tongue and the positional aspects of dental prosthesis using a retrospective analysis. MATERIALS AND METHODS. A total of 439 patients with SCC of the tongue were diagnosed and treated in the Department of Oral and Maxillofacial Surgery, Seoul National University Dental Hospital. Patients were treated over a 12.5-year period ranging from January 1, 2001 to June 30, 2013. Statistical analysis was performed to examine potential differences between the groups. RESULTS. The number of patients with a crown and/or a bridge (134, 63.5%) was significantly different than the number of patients without a prosthesis (77, 36.5%). Even after accounting for different types of prostheses such as crowns, bridges, and dentures, no significant differences were observed between the position of the prosthesis and the location of the SCC of the tongue, with significance defined as a P-value less than .05 by the Pearson-Chi square test. CONCLUSION. Patients with crowns and/or bridges exhibited more frequent SCC of the tongue compared with patients without these prosthesis. These data support the hypothesis that mechanical trauma and galvanic phenomena play a role in the etiology of SCC of the tongue.

다이폴 모델링 기법을 이용한 수중 전기장 신호 특성 예측 기법 연구 (A Study on Prediction Technique for Underwater Electric Field Signature Characteristic using Dipole Modelling Method)

  • 양창섭;정현주;이종주;전재진
    • 한국자기학회지
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    • 제18권6호
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    • pp.221-224
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    • 2008
  • 본 논문에서는 함정 선체의 갈바닉 부식 전류에 의해 발생되는 수중 전기장 신호를 경계요소 해석 도구인 FNREMUS 소프트웨어를 이용하여 예측하고, 예측된 신호로부터 함정 전기장 신호 특성을 특이치 분해(singular value decomposition) 방법을 이용하여 등가적으로 다이폴 모델링하는 방법에 대해 기술하고 있다. 제안된 다이폴 모델링 기법은 30 m 심도에서 예측된 경계요소 해석 결과와의 평균 차이 비교 방법을 통해 타당함이 확인되었다. 본 논문에서 제안된 모델링 기법을 이용하면 함정에서의 다양한 심도 변화에 따른 수중 정 전기장 신호 분포 특성 예측 및 분석이 가능하다.

AL계 희생양극에 의한 2종스테인리스 강축의 음극방식 실용화 연구 (Study of Practical Cathodic Protection of 2nd Class Stainless Steel Shaft by means of Al Sacrificial Anode)

  • 손영태;이명훈;이희준
    • 선박안전
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    • 통권22호
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    • pp.34-53
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    • 2007
  • In the case of hull material. large sized merchant ships are made of steel, on the other hand FRP or wood are used for small sized fishing boats. At present in Korea approximately 88,500 fishing boats are in operation of which 70% are made of FRP In the meantime, stainless steel is frequently used as shaft materials of the small-size FRP fishing boat. Namely, the kinds of shaft materials are STS 304(18Cr-8Ni), STS 316(18Cr-12Ni-2.5Mo steel) and STS 630(17Cr-Ni-Nb steel)etc. Among these things, STS 304 which is the cheapest and having ordinary corrosion resistance is most widely used as 2nd class shaft material. But, using STS 304 for shaft system material of the small-size FRP fishing boat on seawater environments entails a severe corrosion which causes shaft system troubles. Particularly, the corrosions tend to be concentrated of the stern and bow side, propeller shaft surface of inside of stern tube and the boat having no stern cooling pipe line system. As a solution for those problems, research on the ways to mitigate corrosion on the part of 2nd class stainless steel shaft have been undertaken. In the result, not only clarification for the reason of corrosion of the part of stainless steel shaft used mainly for the small-size FRP fishing boat was done, but also most optimal corrosion protection system was developed by experimenting shaft's protection simulation based of the electrochemical cathodic protection principle. In addition, verification through the field test on the optimal cathodic corrosion protection method by means of aluminum sacrificial anode was carried out. In this study, effective and economical shaft's protection system is suggested to the small-size FRP fishing boat operator by substantiating the results obtained from the research on the optimal cathodic protection.

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