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RELATION BETWEEN MICROSTRUCTURE AND SOFT MAGNETIC PROPERTIES OF Fe-TM-C-N (TM:Hf, Zr AND Nb) NANOCRYSTALLINE FILMS

  • Ryu, H.J.;Choi, J.O.;Han, S.H.;Kim, H.J.;Lee, J.J.;Kang, I.K.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.519-523
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    • 1995
  • The Fe-TM-C-N nanocrystalline films (TM : Hf, Zr and Nb) are investigated to examine the relation between microstructure and soft magnetic properties. In these films, as the atomic radius of TM element increases, $P_{N2}$ which was added to get good soft magnetic properties was decreased and the maximum value of the permeability shifted to the high Fe range in the composition diagram. The best soft magnetic properties achieved in these films are : Hc of 0.15 Oe, $\mu_{eff}$ of 7800 (1MHz) and $4{\pi}M_{s}$ of 17.5 kG in Fe-Hf-C-N film ; Hc of 0.06 Oe, $\mu_{eff}$ of 2750 (1MHz) and $4{\pi}M_{s}$ of 16.8 kG in Fe-Zr-C-N film and Hc of 0.31 Oe; $\mu_{eff}$ of 2100 (1MHz) and $4{\pi}M_{s}$ of 15.5 kG in Fe-Nb-C-N film. It was considered that the stronger the bonding force between TM and C(N), the finer TM(C,N) phase is precipitated and therefore, the finer $\alpha$-Fe grains are formed. The effective permeability of the Fe-Zr-C-N films and Fe-Nb-C-N films remains nearly constant up to 10 MHz.

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Performance Evaluation of Semi-Persistent Scheduling in a Narrowband LTE System for Internet of Things (사물인터넷을 위한 협대역 LTE 시스템에서의 준지속적 스케줄링의 성능 평가)

  • Kim, Sunkyung;Cha, Wonjung;So, Jaewoo;Na, Minsoo;Choi, Changsoon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.41 no.9
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    • pp.1001-1009
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    • 2016
  • In LTE networks, the base station transmits control information over the physical downlink control channel (PDCCH) including scheduling grants, which are used to indicate the resources that the user equipment uses to send data to the base station. Because the size of the PDCCH message and the number of the PDCCH transmissions increase in proportion to the number of user equipments, the overhead of the PDCCH may cause serious network congestion problems in the narrowband LTE (NB-LTE) system. This paper proposes the compact PDCCH information bit allocation to reduce the size of the PDCCH message and evaluates the performance of the semi-persistent scheduling (SPS) in the NB-LTE system. The simulation results show that the SPS can significantly reduce the signaling overhead of the PDCCH and therefore increase the system utilization.

Microstructure Development during Sintering of $Nb_2O_5$-doped $UO_2$ pellets under $H_2$ and $CO_2$ atmospheres ($Nb_2O_5$ 첨가 $UO_2$ pellet의 수소 분위기와 이산화탄소 분위기 소결 중 미세조직의 형성에 대한 연구)

  • Song, K.W.;Kim, S.H.;Kim, B.G.;Lee, Y.W.;Yang, M.S.;Park, H.S.
    • Nuclear Engineering and Technology
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    • v.26 no.4
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    • pp.484-492
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    • 1994
  • Microstructures of Nb$_2$O$_{5}$-doped UO$_2$ pellets have been investigated during sintering under H$_2$ and $CO_2$ atmospheres. Pellets are sintered at 1$700^{\circ}C$ in H$_2$ atmosphere and at 130$0^{\circ}C$ in $CO_2$ atmosphere for 1 to 41 hr. The addison of Nb$_2$O$_{5}$ causes the formation of large pores, which shrink to some extent in H$_2$ atmosphere but very little in $CO_2$. Fine pores in the Nb$_2$O$_{5}$-doped UO$_2$ pellet are almost annihilated when sintered under H$_2$ atmosphere but little changed under $CO_2$ atmosphere. The increase in grain size due to Nb$_2$O$_{5}$ addition is much larger in H$_2$ atmosphere than in $CO_2$. Thus the enhancement of uranium diffusion in UO$_2$ due to the Nb$_2$O$_{5}$ addition is thought to be more significant in H$_2$ atmosphere. Microstructures of Nb$_2$O$_{5}$-doped UO$_2$ pellets sintered in H$_2$ atmosphere are discussed from the viewpoint of in-reactor performance. Possible defects formation due to Nb$_2$O$_{5}$ addition is discussed to explain the enhancement of uranium diffusion in H$_2$ and $CO_2$ atmospheres.> atmospheres.

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A Comparison Study of Heat Loss Characteristics in Monofilament and Multifilament Superconducting Coils Driven with AC Currents (단일필라멘트와 다중필라멘트 초전도 코일의 교류 전류에 의한 발열 특성 비교 평가)

  • Hwang, S.M.;Kim, K.;Kang, C.S.;Lee, S.J.;Lee, Y.H.
    • Progress in Superconductivity
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    • v.13 no.2
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    • pp.111-116
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    • 2011
  • Since superconducting wires have no resistance, electromagnets based on the superconducting wires produce no resistive heating with DC current as long as the current does not exceed the critical current of the wire. However, unlike resistive wires, superconducting wires exhibit AC heat loss. Embedding fine superconducting filaments inside copper matrix can reduce this AC loss to an acceptable level and opens the way to AC-capable superconducting coils. Here, we introduce an easy and accurate method to measure AC heat loss from sample superconducting coils by measuring changes in the rate of gas helium outflow from the liquid helium dewar in which the sample coil is placed. This method provides accurate information on total heat loss of a superconducting coil without any size limit, as long as the coil can fit inside the liquid helium dewar. With this method, we have evaluated AC heat loss of two superconducting solenoids, a 180-turn solid NbTi wire with 0.127 mm diameter (NbTi coil) and a 100-turn filamented wire with 1.4 mm diameter where 7 NbTi filaments were embedded in a copper matrix with copper to NbTi ratio of 6.7:1 (NbTi-Cu coil). Both coils were wound on 15 mm-diameter G-10 epoxy tubes. The AC heat losses of the NbTi and NbTi-Cu coils were evaluated as $53{\pm}4.7\;{\mu}W/A^2Hzcm^3$ and $0.67{\pm}0.16\;{\mu}W/A^2Hzcm^3$, respectively.

Synthesis of Cd1-xZnxS/K4Nb6O17 Composite and its Photocatalytic Activity for Hydrogen Production

  • Liang, Yinghua;Shao, Meiyi;Liu, Li;Hu, Jinshan;Cui, Wenquan
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1182-1190
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    • 2014
  • $Cd_{1-x}Zn_xS$-sensitized $K_4Nb_6O_{17}$ composite photocatalysts (designated $Cd_{1-x}Zn_xS/K_4Nb_6O_{17}$) were prepared via a simple deposition-precipitation method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), $N_2$ sorption, ultraviolet-visible light diffuse reflectance spectroscopy (UV-Vis DRS), photoluminescence measurements (PL), and X-ray photoelectron spectroscopy (XPS). The $Cd_{0.8}Zn_{0.2}S$ particles were scattered on the surface of $K_4Nb_6O_{17}$, and had a relatively uniform size distribution around 50 nm. The absorption edge of $K_4Nb_6O_{17}$ was shifted to the visible light region and the recombination of photo-generated electrons and holes suppressed after $Cd_{0.8}Zn_{0.2}S$ loading. The $Cd_{0.8}Zn_{0.2}S$(25 wt %)/$K_4Nb_6O_{17}$ composite possessed the highest photocatalytic activity for hydrogen production under visible light irradiation, evolving 8.278 mmol/g in 3 h. Recyclability tests were performed, and the composite photocatalysts were found to be fairly stable. The mechanism of charge separation between the photogenerated electrons and holes at the $Cd_{0.8}Zn_{0.2}S/K_4Nb_6O_{17}$ composite was discussed.

Nano-crystallization Behavior and Optical Properties of Na2O-Nb2O5-TeO2Glasses (1) (Na2O-Nb2O5-TeO2계 유리의 광학적 성질과 나노-결정화거동 (1))

  • 김현규;류봉기;차재민;김병관;이재성
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1078-1084
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    • 2003
  • In order to develop a new type of nonlinear optical materials or photocatlaysts, Na$_2$O-Nb$_2$ $O_{5}$-Te $O_2$ glasses were prepared using conventional melt quenching method, and the crystallization behaviors and optical properties of these glasses was investigated. The optical and physical properties for Na$_2$O-Nb$_2$ $O_{5}$-Te $O_2$ glasses are: refractive index, n=2.04$\pm$0.04; density, p (g/㎤)=4.87$\pm$0.58; optical energy band of the transmission cut-off wavelength, E$_{0}$ (eV)=3.14$\pm$0.04. The transparent glass ceramics consisting of the nanocrysatls were obtained when the Na$_2$O-Nb$_2$ $O_{5}$-Te $O_2$ glass was first heat-treated at 3$50^{\circ}C$ for 1 h and than at 40$0^{\circ}C$ for 1 h. A cubic crystalline phase consisting of the nano-crysatls transforms into a stable phase at temperature above 47$0^{\circ}C$ for 1 h.

Dielectric properties of the $Pb(Fe_{1/2}Nb_{1/2})O_3-Pb(Fe_{2/3}W_{1/3})O_3- Pb(Mg_{1/3}Nb_{2/3})O_3$ ceramics ($Pb(Fe_{1/2}Nb_{1/2})O_3-Pb(Fe_{2/3}W_{1/3})O_3- Pb(Mg_{1/3}Nb_{2/3})O_3$ 세라믹의 유전특성)

  • 박인길;류기원;이성갑;이영희
    • Electrical & Electronic Materials
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    • v.6 no.2
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    • pp.122-128
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    • 1993
  • 본 연구에서는 0.45Pb(Fe$_{1}$2/Nb$_{1}$2/)O$_{3}$- (0.55-xPb(Fe$_{2}$3/W$_{1}$3/)O$_{3}$ (x=0.20, 0.25, 0.30) 세라믹을 950~990[.deg.C]에서 2시간 유지시켜 일반소성법으로 제작하였다. 제작된 시편에 대해 적층 세라믹 캐패시터로의 응용가능성을 고찰하기 위해 조성비와 소결온도에 따른 구조적, 유전적 특성을 조사하였다. PMN의 첨가량이 증가할수록 결정립 크기는 감소하였으며 상전이 온도는 증가하였다. 소결밀도는 970[.deg.C]에서 소결된 0.45PFN-0.30PFW-0.25PMN 시편에서 7.86[g/cm$_{3}$]의 최대값을 나타내었다. 유전상수는 990[.deg.C]에서 소결된 0.45PFN-0.25PFW-0.30PMN 시편에서 20,751의 최대값을 나타내었으며 유전손실은 모든 조성에서 5[%]이상을 나타내었다.

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Permeability of CoZrNb film with thickness (CoZrNb막의 두께에 따른 투자율의 변화)

  • Hoe, J.;Kim, Y.H.;Shin, K.H.;Sa-Gong, G.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.443-446
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    • 2001
  • MI(Magneto-Impedance) sensor which is made by thin films has significantly high detecting sensitivity in weak magnetic field. It also has a merit to be able to build in low power system. Its structure is simple, which makes it easier to prepare a miniature. In this study, its magnetic permeability and anisotropy field(H$\sub$k/) as a function of a thickness of sputtered amorphous CoZrNb thin film with high saturation magnetostriction and excellent soft magnetic property are investigated. In order to make a uniaxial anisotropy, thin film was subjected to post annealing with a static magnetic field with 1KOe intensity at 250, 300, and 320$^{\circ}C$ for 2 hour. Anisotropy field(H$\sub$k/)of thin film is measured by using MH loop tracer. Its magnetic permeability of thin film is measured over the frequency range from 1 MHz to 750MHz. It has shown that the magnetic permeability of amorphous CoZrNb thin film is decreased due to the skin effect with increasing a thickness of CoZrNb thin film, and hence its driving frequency is lowered.

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Dielectric and Piezoelectric Characteristics of (Na,K)NbO3 Ceramics System According to Sintering Time (소결시간변화에 따른 (Na,K)NbO3계 세라믹스의 유전 및 압전특성)

  • Kim, Do-Hyung;Yoo, Ju-Hyun;Kim, In-Sung;Song, Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.10
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    • pp.901-905
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    • 2008
  • In this study, $0.95(K_{0.5}Na_{0.5})NbO_{3}-0.05Li(Sb_{0.8}Nb_{0.2})O_{3}+0.2\;wt%Ag_{2}O$ were investigated as a variations of sintering times in order to improve dielectric and piezoelectric properties of lead-free piezoelectric ceramics. $Ag_{2}O$ were used as sintering aids and the specimens were sintered during 3, 5, 7, 9 and 11 hours, respectively. At the specimen sintered during 7 hour, Electromechanical coupling factor ($k_p$), density, dielectric constant (${\epsilon}_{\gamma}$), piezoelectric constant ($d_{33}$) and curie temperature ($T_c$) of composition ceramics showed the optimal value of 0.450, 4.274 $[g/cm^3]$, 1007, 257 [pC/N] and $396^{\circ}C$, respectively.

Fabrication and Properties of MFISFET Using $LiNbO_3$ Ferroelectric Films ($LiNbO_3$ 강유전체를 이용한 MFISFET의 제작 및 특성)

  • Jung, Soon-Won;Koo, Kyung-Wan
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.57 no.2
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    • pp.135-139
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    • 2008
  • MFISFETs with platinum electrode on the $LiNbO_3$/aluminum nitride/Si(100) structures were successfully fabricated and the properties of the FETs have been discussed. $I_D-V_G$ characteristics of MFISFETs for linear region (that is, 0.1 V of the drain voltage) showed hysteresis loop with a counter-clockwise trace due to the ferroelectric nature of $LiNbO_3$ films. A memory window (i.e., threshold voltage shift) of the fabricated device was about 2[V] for a sweep from -4 to +4[V]. The estimated field-effect electron mobility and transconductance on a linear region were 530[$cm^2/V{\cdot}s$] and 0.16[mS/mm], respectively. The drain current of 27[${\mu}A$] on the "on" state was more than 3 orders of magnitude larger than that of 30[nA] on the "off" state at the same "read" gate voltage of l.5[V], which means the memory operation of the MFISFET.