• 한국주조공학회지
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• 제8권4호
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• pp.407-411
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• 1988

• 한국주조공학회지
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• 제9권5호
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• pp.377-385
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• 1989

• 한국주조공학회지
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• 제12권1호
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• pp.10-20
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• 1992

• Current Research on Agriculture and Life Sciences
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• 제31권1호
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• pp.25-29
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• 2013

As a specialty oil, furan fatty acids have gained special attentions since they are known to play important roles in biological systems including human. Although several studies reported chemical synthesis of furan fatty acids, their synthesis consisted of complicated chemical multistep with chemical catalysts. Recently, a simple one-step heat treatment method was developed to produce a novel furan fatty acid, 7,10-epoxy-octadeca-7,9-dienoic acid (7,10-EODA) from a dihydroxyl fatty acid 7,10-dihydroxy-8(E)-octadecenoic acid (DOD). In this report we studied about optimization of environmental conditions for the maximum production of 7,10-EODA from DOD by heat treatment. Production of 7,10-EODA was maximized at over $85^{\circ}C$ for at least over 48 hour in hexane. Solvent volume for maximum production should be over 300 mL per 10 mg DOD.

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3600-3604
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• 2010

Rhodium(III)-$Cp^*$ complexes containing labile ligands, $[Cp^*RhCl_2]_2$, [$Cp^*Rh({\eta}^2-NO_3)$(OTf)], and $[Cp^*Rh(OH_2)_3](OTf)_2$, reacted with potential linking ligands [$L^1$ = (2-thiophene)-CH=N-N=CH-(2-thiophene); $L^2$ = (2-furan)-CH=N-N=CH-(2-furan)] to give two molecular compounds, [$Cp^*Rh(L^1)Cl_2$] (1) and [$Cp^*Rh({\eta}^2-NO_3)(L^1)$]$(OTf){\cdot}CH_2Cl_2$ ($2{\cdot}CH_2Cl_2$), and one 1-dimensioanl coordination polymer, $\{[Rh(L^2)]{\cdot}(OTf)}_{\infty}$ (3). Whereas one imine nitrogen atom within the ligand is coordinated to the Rh metal in compounds 1 and 2, both nitrogen atoms are bound to two neighboring Rh metals in compound 3 to lead to a 1-D chain polymer.

• Archives of Pharmacal Research
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• 제29권11호
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• pp.984-989
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• 2006

1-Furan-2-yl-3-pyridin-2-yl-propenone (FPP-3) has been characterized to have an anti-inflammatory activity through the inhibition of the production of nitric oxide and tumor necrosis $factor-{\alpha}$. In the present studies, the phase 1 metabolism of FPP-3 was investigated in rat liver microsomes and cytosols. When FPP-3 was incubated with rat liver microsomes and cytosols in the presence of NADPH. 2 major peaks were detected on a liquid chromatography/electrospray ionization-mass spectrometry. Two metabolites (i.e., M1 and M2) were characterized as reduced forms on propenone: M1 (1-furan-2-yl-3-pyridin-2-yl-propan-1-one) was the initial metabolite and M2 (1-furan-2-yl-3-pyridin-2-yl-propan-1-ol) was a secondary alcohol believed to be formed from M1.

• 한국주조공학회지
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• 제12권6호
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• pp.471-479
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• 1992

For the last 2 decades, the bonding materials for the foundry sand and the foundry equipments with high performance have been developed and employed in the foundry shops. In those periods, the furan resins hardened in higher temperature have been replaced with the self-hardened ones in the room temperature. Simultaneously the various reclamation methods of the self-hardened furan resin sand have been developed in order to get the clean working environments, the reduction of solid wastes and the lower of production cost in the foundry. In this experimental study, the combustion reclamation method using the fluidized bed among the various methods was studied in order to reduce the L.O.I. and /or $N_2$ gas due to the deposition of the furan resins and the hardeners. Comparing the results of this experimental combustion reclamation method with those of the employed pneumatic method, the Surface Stability Index of the specimen made by combustion method is 30% higher than that of the latter one and L.O.I. decreases about 30%. The reclamation temperature of 650$^{\circ}C$ in this experimental fluidized bed would be recommended in the viewpoints of the reclamation period, the fuel consumption and the residual quantity of the furan resin. The formula determining the minimum fluidizing velocities according to the temperatures in the fluidized bed has been obtained.

• Bulletin of the Korean Chemical Society
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• 제31권3호
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• pp.577-581
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• 2010

Spiro[fluorene-9,4'-[4H]indeno[1,2-b]furan] was synthesized, and its $\pi$-conjugation was efficiently elongated using palladium-catalyzed C-H arylation of a furan moiety. The resulting $\pi$-conjugated compounds showed intense fluorescence and extremely high thermal stability.

• Bulletin of the Korean Chemical Society
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• 제29권5호
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• pp.1065-1068
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• 2008

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.90-94
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• 2012

The furan-2-ylidene acetates (3a-d), obtained from the furan-2,3-diones (1a-b) and methyl/ethyl (triphenylphosphoranylidene)-acetates (2a-b), were converted via the Michael type reactions with 2,3-diaminopyridine and its derivatives (4a-c) into the corresponding pyrrol-2-ylidene-acetates (5a-j) in moderate yields (45-94%). Structures of these compounds were determined by the IR, NMR, elemental analysis, and X-ray diffraction method.