• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.141-145
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• 2007

Due to their excellent catalytic activity with respect to methanol oxidation on platinum at low temperature, platinum nanosized catalysts have been a topic of great interest for use in direct methanol fuel cells (DMFCs). Since pure platinum is readily poisoned by CO, a by-product of methanol electrooxidation, and is extremely expensive, a number of efforts to design and characterize Pt-based alloy nanosized catalysts or Pt nanophase-support composites have been attempted in order to reduce or relieve the CO poisoning effect. In this review paper, we summarize these efforts based upon our recent research results. The Pt-based nanocatalysts were designed by chemical synthesis and thin-film technology, and were characterized by a variety of analyses. According to bifunctional mechanism, it was concluded that good alloy formation with $2^{nd}$ metal (e.g., Ru) as well as the metallic state and optimum portion of Ru element in the anode catalyst contribute to an enhanced catalytic activity for methanol electrooxidation. In addition, we found that the modified electronic properties of platinum in Pt alloy electrodes as well as the surface and bulk structure of Pt alloys with a proper composition could be attributed to a higher catalytic activity for methanol electooxdation. Proton conducting contribution of nanosized electrocatalysts should also be considered to be excellent in methanol electrooxidation (Spillover effect). Finally, we confirmed the ensemble effect, which combined all above effects, in Pt-based nanocatalsyts especially, such as PtRuRhNi and $PtRuWO_{3}$, contribute to an enhanced catalytic activity.

• 환경영향평가
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• 제18권6호
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• pp.453-460
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• 2009

In order to provide fundamental data for developing high-grade(high-quality and low-pollution) Refuse Derived Fuel(RDF), we analyzed caloric value and HCl content by Municipal Solid Waste(MSW) type. The caloric value was analyzed using calorimeter and HCl content was analyzed using mercury(II) thiocyanate method. In case of paper type the caloric value was 3,060~3,608kcal/kg and the HCl content was 239~6,135ppm. In case of vinyl-plastics the caloric value was 5,946~9,888kcal/kg and the HCl content was 429~455,771ppm. According to the result of quality assessment by MSW type, the calroric value of vinyl-plastics type was showed higher than that of paper type and in case of HCl content the paper type was showed lower than vinyl-plastics type. So, We mixed paper and plastic wastes. The caloric value of mixed MSW(paper and plastics) was 5,046~9,125kcal/kg and the HCl content was 239~6,135ppm. Also, The caloric value of packaging waste(film-plastics) was 5,982~8,045kcal/kg. Therefore It is possible to develop high-grade Refuse Derived Fuel through suitable mixing of paper and plastic in municipal solid waste.

• 전기화학회지
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• 제4권4호
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• pp.172-175
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• 2001

마그네트론 스퍼터링 방법에 의하여 Nanophase 촉매층을 형성하여 Direct Methanol Fuel Cell(DMFC)에 적용하였다. 일반적인 박막 증착 방법보다 높은 압력 (Ar/He혼합기체)에서 금속 Target과 탄소 Target을 동시에 스퍼터링하여 내피온막 위에 직접 코팅함으로써 기공성 있는 PtRu혹은 Pt및 탄소입자를 포함한 새로운 구조의 촉매층을 형성하였다. 본 방법에 의하여 $1.5mg/cm^2$의 PtRu(Anode) 및 $1mg/cm^2$ Pt(Cathode) 로딩으로 2M Methanol, 1 Bar공기, $80^{\circ}C$조건에서 $45mW/cm^2$의 출력을 얻을 수 있었으며, 이는 기존의 상용방법에 의하여 제조된 전극보다 같은 조건에서 $30\%$의 성능향상을 제시한 것이다. 이는 Nanophase촉매층 구조로 인하여 초미세 분말을 적용하였고, 많은 량의 원자들이 입계에 배열하게 됨으로써 촉매반응을 원활하게 하고,연료의 공급을 효율적으로 해준 것에 기안한 것으로 판단된다. 그러므로, 본 연구의 결과를 응용할 경우 DMFC를 휴대용 전자기기에 적용함에 있어서 성능향상 및 가격경쟁력 확보에 도움을 줄 것으로 기대된다.

• Nuclear Engineering and Technology
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• 제27권6호
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• pp.811-824
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• 1995

CANDU 핵연료봉의 휨 열적 휨 멘트와 수력학적 견인력 및 기계적 하중에 기인하는 휨 모멘트에 의하여 일어난다. 여기서, 연료봉 휨은 연료봉 축방향 중심선으로부터의 측면 처짐으로 정의한다. 본 논문에서는 연료봉 축방향 중심선에 대한 비대칭 온도불포에 의해 핵연료 피복관 자체와 피복관과 소결체의 상호작용 부위에서 발생하는 열적 휨만을 취급한다. 이를 위해 1).소결체와 피복관사이의 기계적 상호작용을 무시한 조건에서의 핵연료 피복관의 휨과 2) 소결체와 피복관의 온도 변화에 기인하여 발생하는 소결체와 피복관 사이의 기계적 상호작용을 고려한 조건에서의 연료봉 휨을 혼합 고려하고, 각각에서 피복관의 비대칭 온도분포가 (i) 냉각재의 불완전한 혼합에 따른 비균질 냉각재 온도, (ii) 핵연료 피복관과 냉각재 사이의 비균질한 열전달 계수, (iii) 핵연료내 반경 방향으로의 중성자속 감쇄에 의한 비대칭 열 발생 등의 복합적효과에 의해 발생되는 것으로 고려하여 피복관의 대칭온도 분포까지 포함 할 수 있는 열적 휨의 일반적 해석 공식을 제시하였다. 본 휨 공식에 사용되는 모든 변수에 대한 민감도 분석을 통해, 핵연료봉 길이, 피복관 내경, 냉각재 평균 온도 및 변화 인자, 소결체 -피복관 기계적 상호 작용 인자, 중성자속 감쇄 인자, 핵연료 열팽창 계수, 피복관-냉각재 열전도 계수 등의 변화가 피복관 두께, 피복관-냉각재 열전달 계수, 피복관 열팽창 계수, 핵연료-피복관 열전달 계수 등의 변화보다 핵연료봉의 열적 휨에 상대적으로 더욱 영향을 미치는 것으로 밝혀졌다.

• Journal of Advanced Marine Engineering and Technology
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• 제27권5호
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• pp.624-632
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• 2003

In the gasoline engine industry. there has been a trend towards the development of high performance engines with improved fuel efficiency, reduced weight and smaller sizes. These trends help to solved engine problems related to thermal load and abnormal combustion. In order to investigate these Problems, a thin film-type probe for instantaneously measuring temperatures has been suggested. A method for manufacturing such a probe was established in this study. The instantaneous surface temperature of a constant volume combustion chamber was measured by this probe and the heat flux was obtained through Fourier analysis. A peak instantaneous temperature was obtained after 55∼60 ms from ignition and the temperature increased according to an equivalence ratio and varied differently according to the position of the probe. Total heat loss during combustion period was affected by the equivalence ratio and differed widely in accordance to the position of the probe.

• 대한기계학회논문집B
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• 제22권8호
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• pp.1132-1140
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• 1998

The disintegration process of initial spray from high-pressure swirl injector was investigated at different injection pressures. The transient breakup phenomena that were difficult to observe at high injection pressure were easily observed at the low injection pressure of 0.4MPa. The effect of fuel remained inside a nozzle hole volume on the penetration of initial spray was also investigated. The disintegration process of initial spray could be classified four regions: the formation of mushroom shape, the first collision, the second collision, and the development of spray, The liquid film of cup shape was particularly found in the second collision region, and the growth ratio of its length and width at low and high injection pressures were compared.

• Journal of Advanced Marine Engineering and Technology
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• 제19권3호
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• pp.9-23
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• 1995

To analyze the spray and flame in D.I. diesel engine, the visualizing methods by schlieren photograph and diffused background illumination photograph with high speed camera are applied to optically accessible D.I.diesel engine. Wcaporating spray, spray droplets and brightness flame are taken with high speed camera by visuallizing method in accordance with various suction air temperature and injection time. The spray and flame image on the film was analyzed by image analyzer. The optically accessible D.I. diesel engine had the similar pressure characteristic to the real D.I. diesel engine. Experimental results showed that shadow areas of the evaporating spray were extended at higher suction air temperature, spray droplets had a max. Penetration length and their penetrating patterns were dependent on the surrounding gas temperature, and flame size after ignition was largely governed by the evaporated fuel quantity at ignition point and by the surrounding gas condition due to piston motion.

• Tribology and Lubricants
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• 제20권2호
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• pp.84-90
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• 2004

It is very important to improve the durability and reliability of crankshaft because of conflicting demands for lower fuel consumption and higher power output. In this study, for the crankshaft bearing design, analyses were conducted to determine the lubrication characteristics such as oil flow rate, minimum oil film thickness, friction force and increase of oil temperature at main bearing and connecting rod bearing. Additionally, supplied oil pressure and temperature effects on the bearings were simulated to figure out lubrication characteristics on the bearings. Finally the effects of increasing the bearing width and clearance were introduced on the lubrication characteristics.

• 한국세라믹학회지
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• 제31권5호
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• pp.477-484
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• 1994

The yttria stabilized zirconia(YSZ) thin films for solid oxide fuel cell (SOFC) were fabricated by an electrochemical vapor deposition(EVD) technique using YCl3+ZrCl4+H2O gas system. The YSZ films were deposited under reduced pressure at the temperature of 1000~120$0^{\circ}C$ on the porous alumina substrates. The deposition rate, chemical composition and growth morphology were investigated by SEM, XRD, EDS. The growth rates of the films obeyed a parabolic rate law, representing that the growing process is controlled by an electrochemical transport through the YSZ film. The Y2O3 content of the films was about 10 mol%, equal to the composition of metal chloride reactant gases, approximately. The YSZ films were highly dense, the growing features showed columnar structure and surface morphologies were changed with the EVD conditions.

• 한국세라믹학회지
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• 제45권12호
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• pp.782-787
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• 2008

Ni-ceria cermets have been extensively investigated as candidates for the anode in intermediate-temperature solid oxide fuel cells. We have used the citric method to synthesize nanocomposite powders consisting of NiO (Ni metal content: $40{\sim}60%$ by volume) highly dispersed in $Ce_{0.9}Gd_{0.1}O_{1.95}$ (CGO). The microstructure characteristics and sintering behaviors of the nanocomposites were investigated. No impurity phases were observed and the shrinkage of these substrates matched well with that of a CGO electrolyte with a specific surface area of $11\;m^2/g$. Densification of the CGO electrolyte layer to $<5\;{\mu}m$ thickness was achieved by co-firing the laminated electrolyte with the porous NiO-CGO substrate at $1400^{\circ}C$ for 6 h.