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Synthesis of Alternating Head-to-Head Copolymer of Methyl $\alpha$-cyanoacrylate and 2,3-Dihydrofuran. Ring-Opening Polymerization of 3-Methoxy-4-cyano-2,9-dioxabicyclo[4.3.0]non-3-ene

  • Lee, Ju-Yeon;Cho, I-Whan
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.176-179
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    • 1988
  • 3-Methoxy-4-cyano-2,9-dioxabicyclo[4.3.0]non-3-e ne (1) was prepared by (4 + 2) cycloaddition reaction of methyl ${\alpha}$-cyanoacrylate with 2,3-dihydrofuran. Compound 1 was ring-open polymerized by cationic catalyst such as boron trifluoride etherate to obtain alternating head-to-head (H-H) copolymer (2) of methyl $\alpha$ -cyanoacrylate and 2,3-dihydrofuran. For comparison, head-to-tail (H-T) copolymer (3) was also prepared by free radical copolymerization of the corresponding monomers. The H-H copolymer exhibited minor differences in its $^1H$-NMR and IR spectra, but in the $^{13}C$-NMR spectra significant differences were observed between the H-H and H-T copolymers. All of the H-H and H-T copolymers were soluble in common solvents and the inherent viscosities were in the range 0.2-0.3 dl/g.

CLASSIFICATION OF CLIFFORD ALGEBRAS OF FREE QUADRATIC SPACES OVER FULL RINGS

  • Kim, Jae-Gyeom
    • Bulletin of the Korean Mathematical Society
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    • v.22 no.1
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    • pp.11-15
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    • 1985
  • Manddelberg [9] has shown that a Clifford algebra of a free quadratic space over an arbitrary semi-local ring R in Brawer-Wall group BW(R) is determined by its rank, determinant, and Hasse invariant. In this paper, we prove a corresponding result when R is a full ring.Throughout this paper, unless otherwise specified, we assume that R is a commutative ring having 2 a unit. A quadratic space (V, B, .phi.) over R is a finitely generated projective R-module V with a symmetric bilinear mapping B: V*V.rarw.R which is non-degenerate (i.e., the natural mapping V.rarw.Ho $m_{R}$(V,R) induced by B is an isomorphism), and with a quadratic mapping .phi.: V.rarw.R such that B(x,y)=1/2(.phi.(x+y)-.phi.(x)-.phi.(y)) and .phi.(rx) = $r^{2}$.phi.(x) for all x, y in V and r in R. We denote the group of multiplicative units of R by U9R). If (V, B, .phi.) is a free rank n quadratic space over R with an orthogonal basis { $x_{1}$,.., $x_{n}$}, we will write < $a_{1}$,.., $a_{n}$> for (V, B, .phi.) where the $a_{i}$=.phi.( $x_{i}$) are in U(R), and denote the space by the table [ $a_{ij}$ ] where $a_{ij}$ =B( $x_{i}$, $x_{j}$). In the case n=2 and B( $x_{1}$, $x_{2}$)=1/2 we reserve the notation [a $a_{11}$, $a_{22}$] for the space. A commutative ring R having 2 a unit is called full [10] if for every triple $a_{1}$, $a_{2}$, $a_{3}$ of elements in R with ( $a_{1}$, $a_{2}$, $a_{3}$)=R, there is an element w in R such that $a_{1}$+ $a_{2}$w+ $a_{3}$ $w^{2}$=unit.TEX>=unit.t.t.t.

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Content Analysis and Job Satisfaction of the Nurse in the Free Elderly Home and Nursing Home (무료 양로.요양시설 간호사의 업무내용과 직무만족정도)

  • Sung, Ki-Wol
    • Research in Community and Public Health Nursing
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    • v.16 no.3
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    • pp.329-340
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    • 2005
  • Purpose: The study was performed to compare the contents of jobs and job satisfaction of resident nurses at free elderly homes with nursing homes in Korea. Method: The subjects consisted of 138 resident nurses at free elderly homes and nursing homes. Data were collected from the 1st of January to the 22nd of February in 2005 using a structured questionnaire containing questions on general characteristics. contents of the nurses' daily tasks, health program. job satisfaction and pay satisfaction. Collected data were analyzed using SPSS (version 11.5) through descriptive statistics, $X^2-test$, t-test and ANOVA. Result: For nurses at free elderly homes and nursing homes. their daily tasks consisted of health assessment. medication care and eating care. The general job satisfaction of the nurses was similar between those at free elderly homes and those at nursing homes, but working conditions and pay were significantly different according to the sub content of job satisfaction. Job satisfaction was significantly different according to marital status in resident nurses at the free elderly home, and according to the experience of living with the elderly and the experience of receiving special training or lectures in elderly nursing in resident nurses at free nursing homes. Conclusion: Resident nurses at free elderly homes and nursing homes had various types of tasks, and it is necessary to differentiate tasks and payment systems for them according to their job.

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Free Amino Acids in Meats of Cattle, Swine, Goats and Rabbits by Thin Layer Chromatography and Automatic Amino Acid Analyzer (Thin Layer Chromatography 및 Automatic Amino Acid Analyzer에 의한 소, 돼지, 산양(山羊) 및 토끼 고기 중의 유리(遊離)아미노산 분포(分布))

  • Cho, Jong Hoo;Cho, T.H.;Han, Su Nam
    • Korean Journal of Veterinary Research
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    • v.13 no.1
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    • pp.17-21
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    • 1973
  • Free amino acid extracts of musculus brachiocephalicus and musculus glutaeus of cattle, swine, goats and rabbits are analyzed to see the composition and the contents of free amino acids by thin layer chromatography and automatic amino acid analyzer. The results obtained are summarized as follows: 1. Meats of cattle, swine, goats and rabbits analyzed by thin layer chromatography have 6 kinds of free amino acids such as glycine, histidine, methionine, lysine, alanine and leucine, and the spots of glycine in chromatogram of meats of cattle, swine and goats and the ones of methionine in chromatogram of meats of rabbits are the largest and the most denes of all other ones. 2. Distribution curves of free amino acids in meats of cattle, swine, goats and rabbits showed significant differences, but differences on distribution curves of free amino acids between musculus-brachiocephalicus and musculus glutaeus of the same tested animal are not significant. 3. Contents of free amino acids in meats of cattle, swine, goats and rabbits showed significant differences, but differences on contents of free amino acids between musculus brachiocephalicus and musculus glutaeus of the same tested animal are not significant.

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ON THE CONSTRUCTION AND THE EXISTENCE OF PARAMETRIC CUBIC$g^2$ B-SPLINE

  • Kimn, Ha-Jine
    • Communications of the Korean Mathematical Society
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    • v.10 no.2
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    • pp.483-490
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    • 1995
  • A parametric cubic spline interpolating at fixed number of nodes is constructed by formulating a parametric cubic $g^2$ B-splines $S_3(t)$ with not equally spaced parametric knots. Since the fact that each component is in $C^2$ class is not enough to provide the geometric smoothness of parametric curves, the existence of $S_3(t)$ oriented toward the modified second-order geometric continuity is focalized in our work.

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Comparison of Seasonal Nitrogen Removal by Free-Water Surface Wetlands Planted with Iris pseudacorus L. (노랑꽃창포 자유수면습지의 계절에 따른 질소제거 비교)

  • Yang, Hongmo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.14 no.1
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    • pp.121-132
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    • 2011
  • Removal rates of $NO_3$-N and TN in the free-water surface wetland system during winter; December, January, February and March, spring and fall; April, May, October and November, and summer; Jun, July, August and September were investigated. The system was established on floodplain in the downstream reach of the Gwangju Stream in 2008. It measures 50 meters in length and 5.5 meters in width. Iris pseudacorus L. grown in pots for about two years were planted in the system. The water stream was funneled in by gravity and its effluent was discharged back in. Volumes and water quality of inflow and outflow were analyzed from December 2008 to November 2010. The inflow was averaged approximately 350 $m^3/day$ and hydraulic residence time was about 3 hours. Average influent and effluent $NO_3$-N concentration was 3.75 and 3.35 mg/L, respectively and $NO_3$-N retention was amounted to 10.6%. Influent and effluent TN concentration were averaged 4.93 and 4.30 mg/L, respectively and TN abatement reached to 12.9%. One-way ANOVA statistics claimed that the average removal rates of $NO_3$-N and TN during winter, spring and fall, and summer were not always the same (p<0.001). The t-Tests of three pairs among $NO_3$-N removal rates of winter, spring and fall, and summer illustrated that the removal rates of winter ($5.04{\pm}1.94$), spring and fall ($10.53{\pm}2.24$), and summer ($18.61{\pm}2.26$) were significantly different each others (p<0.001). Among TN removal rates, the three pairs of t-Tests of three seasons showed that the removal rates of winter ($5.21{\pm}2.51$), spring and fall ($11.71{\pm}3.12$), and summer ($21.53{\pm}4.86$) were significantly different from each others (p<0.001).

Computation of Free Surface Displacement for Water Waves by Asymptotic Approximations (점근 근사법에 의한 파랑변위 계산)

  • 서승남
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.6 no.1
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    • pp.12-22
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    • 1994
  • Time evolution of linear water waves on a constant depth generated by a disturbance is analyzed by asymptotic methods; stationary phase, steepest descents and leading wave approximation. In order to verify the derived formulae of surface displacements for 1-D and 2-D waves. surface displacements are calculated and plotted from both the formulae and a numerical integration. The existing results for surface displacements are verified in which the leading amplitude of 1-D waves during the evolution decays as f- T/B, the rest of the wavetrain as t$^{-1}$ 2/ and the rest of the wavetrain of 2-D waves as t-1. But it is shown that the leading amplitude of 2-D waves decays as t 5/6 which is different from Kajiura's result t$^{-4}$ 3/.

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Effect of an 8-week Closed Kinetic Chain Styled Pilates Exercise on Lower Limb Alignment (8주간 닫힌 사슬형 필라테스 운동이 하지 정렬에 미치는 영향)

  • Ga Ram Jeon;Sukhoon Yoon
    • Korean Journal of Applied Biomechanics
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    • v.33 no.4
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    • pp.128-136
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    • 2023
  • Objective: The aim of this study was to investigate the effect of an 8-week closed kinetic chain typed Reformer and Chair Pilates exercise on static and dynamic lower limb alignment for healthy female adults. Method: Ten healthy young female adults without musculoskeletal injury history in last 6 months (Age: 29.3 ± 3.5 yrs., Height: 165 ± 3.4 cm, Body mass: 58.2 ± 5.4 kg) participated in this study. All participants asked to join the 8-week closed kinetic chain typed Reformer and Chair Pilates exercise, and the program was conducted for 60 minutes twice a week. Participants were asked to be measure a static Q-angle and performed free squat one week before and after the program. A 3-D motion analysis with 8 infrared cameras and 5 channels of EMG was executed in this study. The effectiveness of the training was evaluated by paired t-test, and the significance level was set at .05. Results: A significantly decreased in internal rotation angles was found at hip joint during free squat after the training. Also, significantly decreased in lateral rotation angles were found at knee and ankle joint during free squat after training. Finally, significantly decreased in muscle activations were found at adductor longus and peroneus longus during free squat after training. Conclusion: From results of our study, it is concluded that an 8-week closed kinetic chain typed Pilates exercise positively effect on lower limb alignment during dynamic movement.

Hydrolysis Mechanisms of Fish Oil by Lipolase-100T

  • HUR, BYUNG-KI;DONG-JIN WOO;CHONG-BO KIM
    • Journal of Microbiology and Biotechnology
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    • v.9 no.5
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    • pp.624-630
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    • 1999
  • In order to investigate the position of various fatty acids attached to glycerol and the specificity of Lipolase-100T, hydrolysis of fish oil was carried out with Lipolase-100T derived from Aspergillus oryzae. The amounts of free fatty acids produced from triglyceride, 1,2(2,3)-diglyceride, 1,3-diglyceride, and 2-monoglyceride and conversion rates of 1,2(2,3)-diglyceride to 1,3-diglyceride and 2-monoglyceride to 1(3)-monoglyceride were also calculated. The ratio of 1,2-diglyceride content to 1,3-diglyceride was higher than 70 in the early period of hydrolysis. The fatty acid content of the glyceride mixture after 72 h of hydrolysis was compared with that of fish oil, and it was found that polyunsaturated fatty acids such as C16:4, C20:4 n-3, C20:5 n-3, C21:5 n-3, C22:5 n-3 and C22:6 n-3 were located in the 2-position of glycerol. Material balance of each component in the hydrolysis system was written to obtain a set of simultaneous linear equations. The theoretical quantity of free fatty acids produced from triglyceride, 1,2-diglyceride, 1,3-diglyceride, and monoglyceride, respectively, were calculated by solving the linear equation system. The conversion rate of 1,2(2,3)-diglyceride to 1,3-diglyceride and that of 2-monoglyceride to 1(3)-monoglyceride were also obtained. The results showed that the migration rate of 1,2(2,3)-diglyceride to 1,3-diglyceride was higher than the hydrolysis rate of 1,2(2,3)-diglyceride to 2-monoglyceride and the conversion rate of 2-monoglyceride to 1(3)-monoglyceride was extremely low.

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Syntheses of Alternating Head-to-Head Copolymers of Vinyl Ketones and Vinyl Ethers, and Their Properties. Ring-Opening Polymerization of 2,3,6-Trisubstituted-3,4-dihydro-2H-pyrans

  • Lee, Ju-Yeon;Cho, I-Whan
    • Bulletin of the Korean Chemical Society
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    • v.8 no.2
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    • pp.102-105
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    • 1987
  • 2-Methoxy-6-methyl-3,4-dihydro-2H-pyran ($1_a$), 2-ethoxy-3,6-dimethyl-3,4-dihydro-2H-pyran ($1_b$), and 2-ethoxy-3-methyl-6-ethyl-3,4-dihydro-2H-pyran ($1_c$) were prepared by (4 + 2) cycloaddition reaction from the corresponding vinyl ketones and alkyl vinyl ethers. Compounds $1_{a-c}$ were ring-open polymerized by cationic catalyst to obtain alternating head-to-head (H-H) copolymers. For comparison, copolymer of head-to-tail (H-T) was also prepared by free radical copolymerization of the mixture of the corresponding monomers. The H-H copolymer exhibited some differences in its $^1H$ NMR and IR spectra. However, significant differences were showed between the H-H and H-T copolymers in the $^{13}C$ NMR spectra. Also noteworthy was that$T_g$ value of H-H copolymer was higher than that of the corresponding H-T structure. Decomposition temperature of the H-H copolymer was lower than that of the H-T copolymer. All the H-H and H-T copolymers were soluble in common solvents.