• Title/Summary/Keyword: formation behaviors

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Neural Network Models of Oxide Film Etch Process for Via Contact Formation (Via Contact 형성을 위한 산화막 식각공정의 신경망 모델)

  • 박종문;권성구;박건식;유성욱;배윤구;김병환;권광호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.1
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    • pp.7-14
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    • 2002
  • In this paper, neutral networks are used to build models of oxide film etched In CHF$_3$/CF$_4$ with a magnetically enhanced reactive ion etcher(MERIE). A statistical 2$\^$4-1/ experimental design plus one center point was used to characterize relationships between process factors and etch responses. The factors that were varied include radio frequence(rf) power, pressure, CHF$_3$ and CF$_4$ flow rates. Resultant 9 experiments were used to train neural networks and trained networks were subsequently tested on its appropriateness using additionally conducted 8 experiments. A total of 17 experiments were thus conducted for this modeling. The etch responses modeled are dc bias voltage, etch rate and etch uniformity A qualitative, good agreement was obtained between predicted and observed behaviors.

Effects of Oxygen on the Photochemical Behaviors of Methacrylic Homopolymer Containing Anthracene Groups

  • Kim, Yong-Woon;Chae, Kyu-Ho
    • Journal of Photoscience
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    • v.9 no.3
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    • pp.57-63
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    • 2002
  • A homopolymer containing anthracene groups, poly[6-(9-anthryloxy)hexyl methacrylate] (PAn) was prepared and the effect of oxygen on its photochemical reaction was studied by UV and IR absorption spectroscopy in order to understand its photochemical behavior. Photochemical reaction of the PAn in THF solution under an atmosphere of air resulted in the formation of endoperoxide at the beginning stage of reaction followed by photodimerization reaction after all the oxygen was consumed, whereas photodimerization and endoperoxide formation took place concomitantly in the film state. The photoreversible reaction of the anthracene photodimer groups in the polymer by photolysis with 254 nm UV light was not efficient. The IR absorption spectral changes of the PAn film upon irradiation indicate that various photooxidation products were produced in the atmosphere of air.

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Electrochemical and Spectrofluorometric Behaviors of Eu(III) Complexes in Aqueous Solution

  • Chae Won-Seok;Kim Kang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.15 no.12
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    • pp.1050-1054
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    • 1994
  • Eu(Ⅲ) exhibits one electron-transfer reduction at E$_{1/2}$ =-0.617 V vs. Ag/AgCl and the hypersensitive peak at 618 nm corresponding to $^5D_0$ ${\leftrightarro}$ $^7F_2$ transition in 0.10 M LiClO$_4$ aqueous solutions. Upon the addition of carboxylate or sulfonate anions to the Eu(Ⅲ) aqueous solutions, the reduction potential shifts negatively and the reduction current decreases because of the complex formation between Eu(Ⅲ) ions and the anions. However, for the case of carboxylate anion (acetate or propionate) the shift of reduction peak potential and the emission intensity at 618 nm are greater. The results are interpreted in terms of the differences in the formation constants and the hypersensitivity.

RUNNING-IN OF DLC COATED STEEL IN BOUNDARY LUBRICATION

  • Stavlid, N.;Wiklund, U.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.137-138
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    • 2002
  • The benefits of using DLC coatings on steel in dry sliding are well known. The present study has investigated the effects of using the same materials but in a boundary lubricated environment. Tribological tests were performed using a load-scanning device and a lubricant with an extreme-pressure (EP) additive. XPS and grazing incidence XRD are used for chemical analysis. The chemical composition of the resulting tribofilm is correlated to different friction behaviors and contact loads, and indicates that high loads are beneficial for formation of low friction tribofilm.

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A study on a collective behavior of interacting simple robots

  • Sugawara, Ken;Sano, Masaki;Watanabe, Toshinori
    • 제어로봇시스템학회:학술대회논문집
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    • 2002.10a
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    • pp.93.6-93
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    • 2002
  • Many livings form groups that we consider as collective systems. Their collective behaviors are good model for the development of useful distributed systems. In this paper, We discussed the group of motile elements that is described by simple model. The dynamics of each element is described by simple kinematics, but the group shows various types of motions. In addition, we found out the formation of the group changes by modifying rc which is an optimum distance between each element. This modification shows us to observe close-packed structure, face-centered lattice, sim pie lattice and double file.

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Biocompatibility and Mechanical Performance of Ni-Ti

  • Kim, J.H.;Choi, Y.C.;Kim, H.S.;Hong, S.I.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1257-1258
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    • 2006
  • Biomimetic apatite deposition behaviors and mechanical performance for as-rolled and annealed Ni-Ti plates were investigated . A good biomimetic apatite formation and excellent mechanical performance of Ni-Ti suggests that Ni-Ti can be an excellent candidate material as orthopedic implants.

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Freezing Behaviors of Frozen Foods Determined by $^1H$ NMR and DSC

  • Lee, Su-Yong;Moon, Se-Hun;Shim, Jae-Yong;Kim, Yong-Ro
    • Food Science and Biotechnology
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    • v.17 no.1
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    • pp.102-105
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    • 2008
  • The freezing patterns of commercial frozen foods were characterized by using proton nuclear magnetic resonance ($^1H$ NMR) relaxometry and differential scanning calorimetry (DSC). The liquid-like components like unfrozen water were investigated as a function of temperature (10 to $-40^{\circ}C$) and then compared with the unfrozen water content measured by DSC. The formation of ice crystals and the reduction of water in the foods during freezing were readily observed as a loss of the NMR signal intensity. The proton NMR relaxation measurement showed that the decreasing pattern of the liquid-like components varied depending on the samples even though they exhibited the same onset temperature of ice formation at around $0^{\circ}C$. When compared with the unfrozen water content obtained by the DSC, the NMR and DSC results could be closely correlated at the temperature above $-20^{\circ}C$. However, the distinct divergence in the values between 2 methods was observed with further decreasing temperatures probably due to the solid glass formation which was not detected by DSC.

Numerical Study on Flame Structure and Pollutant Formation for Syngas Turbulent Nonpremixed Swirl Burner (석탄가스 선회난류 연소기의 화염구조 및 공해물질 배출특성 해석)

  • Lee, Jeong-Won;Kang, Sung-Mo;Kim, Yong-Mo
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.449-452
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    • 2007
  • The present study numerically investigate the effects of the Syngas chemical kinetics on the basic flame properties and the structure of the Syngas diffusion flames. In order to realistically represent the turbulence-chemistry interact ion and the spatial inhomogeneity of scalar dissipation rate. the Eulerian Particle Flamelet Model(EPFM) with multiple flamelets has been applied to simulate the combustion processes and NOx formation in the syngas turbulent nonpremixed flames. Due to the ability for interactively describing the transient behaviors of local flame structures with CFD solver, the EPFM model can effectively account for the detailed mechanisms of NOx format ion including thermal NO path, prompt and nitrous NOx format ion, and reburning process by hydrocarbon radical without any ad-hoc procedure. validation cases include the Syngas turbulent nonpremixed jet and swirling flames. Based on numerical results, the detailed discussion has been made for the sensitivity of the Syngas chemical kinetics as well as the precise structure and NOx formation characteristics of the turbulent Syngas nonpremixed flames.

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PEO Film Formation Behavior of Al1050 Alloy Under Direct Current in an Alkaline Electrolyte

  • Moon, Sungmo;Kim, Yeajin
    • Journal of the Korean institute of surface engineering
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    • v.50 no.1
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    • pp.17-23
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    • 2017
  • This work demonstrates arc generation and anodic film formation behaviors on Al1050 alloy during PEO (plasma electrolytic oxidation) treatment under a constant direct current in an alkaline electrolyte containing silicate, carbonate and borate ions. Only one big arc more than 2 mm diameter was generated first at the edges and it was moving on the fresh surface or staying occasionally at the edges, resulting in the local burning due to generation of an extremely big orange colored arc at the edges. Central region of the flat surface was not fully covered with PEO films even after sufficiently long treatment time because of the local burning problem. The anodic oxides formed on the flat surface by arcing once were found to consist of a number of small oxide nodules with spherical shape of $3{\sim}6{\mu}m$ size and irregular shapes of about $5{\sim}10{\mu}m$ width and $10{\sim}20{\mu}m$ length. The anodic oxide nodules showed uniform thickness of about $3{\mu}m$ and rounded edges. These experimental results suggest that one big arc observed on the specimen surface under the application of a constant direct current is composed of a number of small micro-arcs less than $20{\mu}m$ size.