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Preparation and Characterization of Hybrid Membrane for Block Copolymer Containing Diphenyl Unit Increasing Cationic Conductivity for Fuel Cells (연료전지용 양이온 전도성이 증가된 디페닐 단위를 갖는 블록공중합체 혼성막 제조 및 특성)

  • KIM, AE RHAN
    • Journal of Hydrogen and New Energy
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    • v.28 no.5
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    • pp.465-470
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    • 2017
  • Sulfonated fluorinated block copolymers having diphenyl units were mixed with the sulfonated cationic conductive polymers at an optimum mixing ratio to form hybrid membranes for fuel cells and their characteristics were studied. 2D and 3D AFM topology analysis confirmed that the number of hydrophilic units in the hybrid membrane was improved. Through the FE-SEM, the microstructure of the hybrid membrane implied hydrogen bonding and pi-pi interactions, and EDAX confirmed carbon, oxygen, sulfur, and fluorine. The thermogravimetric analysis showed that the hybrid membrane was thermally stable and the hydrophilicity of the hybrid membrane was increased by the contact angle of water droplets. As a result, it was confirmed that the cation conductivity increased by a factor of 1.8 times as the number of acidic domains in the hybrid film increased.

Performance of SC-FDE System in UWB Communications with Imperfect Channel Estimation

  • Wang, Yue;Dong, Xiaodai
    • Journal of Communications and Networks
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    • v.9 no.4
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    • pp.466-472
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    • 2007
  • Single carrier block transmission with frequency domain equalization(SC-FDE) has been shown to be a promising candidate in ultra-wideband(UWB) communications. In this paper, we analyze the performance of SC-FDE over UWB communications with channel estimation error. The probability density functions of the frequency domain minimum mean-squared error(MMSE) equalizer taps are derived in closed form. The error probabilities of single carrier block transmission with frequency domain MMSE equalization under imperfect channel estimation are presented and evaluated numerically. Compared with the simulation results, our semi-analytical analysis yields fairly accurate bit error rate performance, thus validating the use of the Gaussian approximation method in the performance analysis of the SC-FDE system with channel estimation error.

Prototype Production of Retaining Wall Block using Liquefied Red Mud (액상화 레드머드를 적용한 보강토 블록의 시제품 생산)

  • Kang, Hye Ju;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.179-180
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    • 2018
  • Color concrete is produced by adding white portland cement and coloring agent. In Korea, colorant added to color concrete is expensive, durability evaluation in external environment is not verified and there is a tendency to avoid color concrete pouring. Red mud with a water content of 50% was prepared in liquid form using appropriate mixing water and additives for recycling as a coloring agent, the liquefied red mud manufactured was intended to show the possibility of using color concrete. In this paper, the application of red mud as an industrial by - product as a coloring agent for color concrete was investigated for the practical use of liquefied red mud by liquefying red mud and producing retaining wall block. As a result, it was found that all of the specifications stipulated in SPS-KCIC0001-0703 are satisfied.

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A Study on the Upgrading Program of HDB in Singapore (싱가포르 주택개발청(HDB)의 업그레이딩 프로그램에 관한 연구)

  • 김주현;박선경;하재명;이재윤
    • Journal of the Korean housing association
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    • v.15 no.2
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    • pp.97-105
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    • 2004
  • This research is about Apartment Remodeling Upgrading Programme by Singapore Housing Development Board(HDB). For this study, we visited HDB and made field survey of the projects. There are basically three types of upgrading, namely, Precinct Upgrading, Apartment Block Upgrading and Flat Upgrading. Precint Upgrading refers the upgrading of services and facilities of the precinct. It involves the extention of open space, car-park, commercial space and additional covered linkways. These afford the residents greater convenience and comfort and generally enhance the environment of the community. Apartment Upgrading refers the upgrading of the block facade, improvements to the elevator, lift lobbies, letter boxes, trash chute and rain chute. The upgrading improves the quality of life of the residents. Flat Upgrading Involves the addition of space which may be in the form of a new Utility-room, replacement of old services, piping and equipment within an apartment unit. These provide the residents with a bigger and more comfortable living space.

Performance Analysis of Space-Time Block Coded Cooperative Wireless Transmission in Rayleigh Fading Channels

  • Kong Hyung-Yun;Khuong Ho-Van
    • Journal of Communications and Networks
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    • v.8 no.3
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    • pp.306-312
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    • 2006
  • This paper studies theoretically the bit error rate (BER) performance of cooperative transmission using space-time block code (STBC) in a fully distributed manner. Specifically, we first propose a STBC-based cooperative signaling structure to make the cooperation of three single-antenna terminals possible. Then, we derive the closed-form BER expressions for both cooperation and noncooperation schemes under flat Rayleigh fading channel plus additive white Gaussian noise (AWGN). The validity of these expressions is verified by Monte-Carlo simulations. A variety of numerical and simulation results reveal that the cooperative transmission achieves higher diversity gain and better performance than the direct transmission for the same total transmit power.

Block-triangular Decomposition of a Linear Discrete Large-Scale Systems via the Generalized Matrix Sign Function (행렬부호 함수에 의한 선형 이산치 대규모 계통의 블럭 삼각화 분해)

  • Park, Gwi-Tae;Lee, Chang-Hoon;Yim, In-sung
    • Proceedings of the KIEE Conference
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    • 1987.07a
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    • pp.185-189
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    • 1987
  • An analysis and design of large-scale linear multivariable systems often requires to be block triangularized form for good sensitivity of the systems when their poles and zeros are varied. But the decomposition algorithms presented up to now need a procedure of permutation, rescaling and a solution of nonlinear algebraic equations, which are usually burden. To avoid these problem, in this paper we develop a newly alternative block triangular decomposition algorithm which used the generalized matrix sign function on the Z-plane. Also, the decomposition algorithm demonstrated using the fifth order linear model of a distillation tower system.

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Polymeric Micelle Formation of Multiblock Copolymer Composed of Poly( $\gamma$-benzyl L-glutamate) and Poly(ethylene oxide)

  • Na, Jae Un;Jeong, Yeong Il;Jo, Jong Su
    • Bulletin of the Korean Chemical Society
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    • v.21 no.4
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    • pp.383-388
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    • 2000
  • Multiblock copolymers consisting of poly( g-benzyl L-glutamate) (PBLG) as the hydrophobic part and poly(ethylene oxide) (PEO) as the hydrophilic part (GEG) were synthesized and characterized. GEG polymeric micelles were prepared by the dialysis technique. Particle size distributions based on intensity,volume, and number-average were 22.6 $\pm$ 11.9 nm, 23.5 $\pm$ 4.6 nm, and 23.7 $\pm$ 37 nm, respectively. It was observed that par-ticle size and size distribution of GEG polymeric micelles changed significantly with the choice of initial sol-vent. Transmission electron micrographs (TEM) showed the polymeric micelles to be spherically shaped, with sizes ranging from 20 nm to 40 nm in diameter. Fluorescence spectroscopy measurements suggested that GEG block copolymers wereassociated in water to form polymeric micelles, and the critical micelle concentrations (CMC) value of the block copolymers was 0.0094 g/L. Further evidenceof micelle formation of GEG block copolymers and limited mobility of the PBLG chain in the core ohe micelle was obtained with 1 H NMR in D2O.

Collapse behaviour of three-dimensional brick-block systems using non-linear programming

  • Baggio, Carlo;Trovalusci, Patrizia
    • Structural Engineering and Mechanics
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    • v.10 no.2
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    • pp.181-195
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    • 2000
  • A two-step procedure for the application of non linear constrained programming to the limit analysis of rigid brick-block systems with no-tension and frictional interface is implemented and applied to various masonry structures. In the first step, a linear problem of programming, obtained by applying the upper bound theorem of limit analysis to systems of blocks interacting through no-tension and dilatant interfaces, is solved. The solution of this linear program is then employed as initial guess for a non linear and non convex problem of programming, obtained applying both the 'mechanism' and the 'equilibrium' approaches to the same block system with no-tension and frictional interfaces. The optimiser used is based on the sequential quadratic programming. The gradients of the constraints required are provided directly in symbolic form. In this way the program easily converges to the optimal solution even for systems with many degrees of freedom. Various numerical analyses showed that the procedure allows a reliable investigation of the ultimate behaviour of jointed structures, such as stone masonry structures, under statical load conditions.

Selective Encryption of Canonical Huffman code (정규 허프만 코드의 선택적 암호화)

  • Park, Sang-ho
    • Journal of IKEEE
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    • v.22 no.4
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    • pp.1163-1167
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    • 2018
  • The selective encryption scheme for canonical Huffman codes using the inversion of bit values is proposed. The symbols are divided into blocks of a certain size, and each symbol in the block is compressed by canonical Huffman coding. Blocks are determined to be sent in the original code or encrypted form. The encryption block inverts the values of the whole bits, and bits of block that do not encrypt are not inverted. Those compressed data are transmitted with the encryption information. It is possible to decrypt the compressed data on the receiving side using the encryption information and compressed data.

A manufacturing process and characteristic observation of alloy blocks for dental CAD/CAM system (치과 CAD/CAM 가공용 합금블럭 제조 및 특성 관찰)

  • Kim, Chi-young
    • Journal of Technologic Dentistry
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    • v.40 no.3
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    • pp.125-131
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    • 2018
  • Purpose: Automatic dental prosthesis manufacturing process was accelerated by the spread of dental CAD / CAM system. The CAD / CAM system with milling alloys were needed supplement. So, sintered alloy blocks were introduced. In this study, we want to study sintered alloy block. And to evaluate the alloy block manufacture and alloy properties. Methods: The alloy powders were prepared by high pressure water dispersion method. The sintered alloy blocks were prepared by low temperature pressing method. Their components observation were EDX, and the alloy structure was observed by XRD. Results: Co-Cr alloy powders were observed to have a circle shape with an average diameter of about $100{\mu}m$ and a Ni-Cr alloy powder had a circle shape with an average diameter of about $50{\mu}m$. The Co-Cr alloy block is composed of Co (34.62 wt%), Cr (17.33 wt%), Mo (2.98 wt%), Si (0.36 wt%) and C (44.17 wt%). The Ni-Cr alloy powder was composed of Ni (40.29 wt%), Cr (19.37 wt%), Mo (3.53 wt%), Si (0.52 wt%) and C (33.18 wt%). The peak of the Co and CoCr peaks were observed in the CoCr alloy body by the means of XRD study. Cr2Ni3 of the peak was observed in the Ni-Cr alloy material. Conclusion : As a result, the following conclusions were obtained. 1. Prepared by high-pressure water-law Co-Cr alloy powder has an average diameter $100{\mu}m$, Ni-Cr alloy powder was found to have the form of sphere having an average diameter $50{\mu}m$. 2. Co-Cr alloy and Ni-Cr alloy block produced by low-temperature processing showed a certain ratio. 3. In the XRD study, Co phase appeared in Co-Cr alloy block after sintering. and Cr2Ni3 phase appeared in Ni-Cr alloy block after sintering.