• Title/Summary/Keyword: foaming agent

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Synthesis and Surface Active Properties of Amphoteric Surfactant Derivatives(II);Surface Active Properties of N-Alkyl or Acyl Hydroxy sulfobetaines (양쪽성 이온 계면활성제의 유도체합성 및 계면성에 관한 연구(제2보);N-알킬 혹은 아실히드록시 술포베타인류의 계면성)

  • Lee, J.H.;Ha, J.W.;Park, H.J.;No, Y.C.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.1
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    • pp.79-85
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    • 1994
  • All the activities and physical properties including surface tension' foaming power, foam stability, emulsifying power, dispersion effect of 3-(N, N-dimethyl N-alkylammonio)-2-hydroxyY-1-propane sulfonate (HSB)류와 3-CN-alkylamidopropyl-N,N-dimethylamm-onjo)-2-hydroxy-1-propane sulfonate (APSB) aquous solution were measured and critical micelle concentration was evaluated. Their cmc of hydroxy sulfobetaine derivatives evaluated by the surface tension method was $1.0{\times}10^{-3}{\sim}1.0{\times}10^{-4}$ mol/l, and surface tension of the aquous solution was decreased to $27{\sim}38dyne/cm$. The experimental results for foaming power, foam stability, emulsifying power in liquid paraffin showed a good surface active properties, especially, dispersion effect in ferric oxide exhibited some efficient surface active properties, and then it would be expected to application as detergent and dispersion agent.

Fabrication of Mullite Short Fibers from Coal Fly Ash (석탄회로부터 뮬라이트 단섬유의 제조)

  • Kim, Byung-Moon;Park, Young-Min;Lyu, Seung-Woo;Yoon, Seog-Young;Park, Hong-Chae
    • Journal of the Korean Ceramic Society
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    • v.43 no.4 s.287
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    • pp.235-241
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    • 2006
  • Mullite short fibers have been fabricated by adapting the Kneading-Drying-Calcination (KDC) process and characterized. The effect of the addition of foaming agent and calcination temperature on the formation of mullite fibers from coal fly ash, was examined. In the present work, ammonium alum $NH_4Al(SO_4)_2\;12H_2O$ synthesized trom coal fly ash and sodium phosphate $Na_2HPO_4\;2H_2O$ were used as foaming agents. After calcination at $1300^{\circ}C$ for 10 h and then etching with 20% HF solution at $50^{\circ}C$ for 5 h using a microwave heating source, the alumina-deficient $(AI_2O_3/SiO_2$ = 1.13, molar ratio) orthorhombic mullite fibers with a width of ${\sim}0.8mm$ (aspect ratio >30), were prepared from the coal fly ash with $AI_2O_3/SiO_2$ = 0.32, molar ratio by the addition of $NH_4AI(SO_4)_2\;12H_2O$, and with further addition of 2 wt% sodium phosphate. The excessive addition of sodium phosphate rather decreased the formation of mullite fibers, possibly due to the large amount of liquid phase prior to mullitization reaction.

Study on the Characteristics of the dehumidification LDPE film (제습 LDPE 필름에 관한 특성 분석연구)

  • JO, Dong-Soo;Noh, Young-Tai;Park, Byung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.7917-7924
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    • 2015
  • In this study, based on CMA which is increasingly used for eco-friendly deicing materials, dehumidification MB made of sodium carbonate, $MgCl_2$/MgO (M/M), and SAP is to be produced. And its moisture absorption rate and dehumidification performance of the film are to be analyzed. And the data on the materials used for the dehumidification film are to be acquired. In case of the dehumidification MB, in which CMA and SAP are mixed, had poor film machinability due to foaming and moisture issues, but adding bentonite and calcium carbonate solved the problem. When a foaming agent was added to extend surface area between substances, CMA and M/M showed no remarkable difference, but SC showed large increase to 3.15 g/g. As the result of anti-corrosive test, CMA dehumidification film showed no corrosion while SC showed pitting corrosion and M/M showed corrosion.

Preparation of Polyethylene Foam Sheets Crosslinked by Gamma-ray Irradiation (감마선 조사에 의하여 가교된 폴리에틸렌 발포 시트의 제조)

  • Lee, Dong-Hoon;Choi, Jun-Ho;Shim, Ki-Hyung;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak
    • Journal of Radiation Industry
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    • v.6 no.3
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    • pp.211-215
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    • 2012
  • In this study, crosslinked polyethylene (PE) foam sheets were prepared through gamma-ray irradiation. PE foam sheets were prepared through a foaming process using sodium bicarbonate as a blowing and foaming agent. The prepared PE foam sheets were then crosslinked through gamma-ray irradiation. The crosslinking degree was increased to 86.0% with an increase in the absorption dose. The tensile strength of the crosslinked PE foam sheets was increased with an increase in the absorption dose. However, the elongation-at-break of the crosslinked PE foam sheets was decreased. The thermal decomposition temperature of the crosslinked PE foam sheets was increased to $421.2^{\circ}C$ with an increase in the absorption dose. The SEM analysis revealed that the morphology was not changed significantly after the crosslinking through gamma-ray irradiation.

Properties of Foamed Concrete According to Types and Concentrations of Foam Agent (기포제 종류 및 희석 농도에 따른 기포 콘크리트의 특성)

  • Kim, Jin-Man;Jeong, Ji-Yong;Hwang, Eui-Hwan;Shin, Sang-Chul
    • Journal of the Korea Concrete Institute
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    • v.24 no.1
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    • pp.61-70
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    • 2012
  • Recently, the government has been working feverously to save energy and reduce greenhouse gas emission by enacting Basic Act on Low Carbon Green Growth at the national level. Improving the insulation performance of building exterior and insulator can reduce the energy in the building sector. This study is about developing light-weight foamed concrete insulation panel that can be applied to buildings to save energy and to find the optimal condition for the development of insulation materials that can save energy by enhancing its physical, kinetic and thermal characteristics. Various experimental factors and conditions were considered in the study such as foam agent types (AES=Alcohol Ethoxy Sulfate, AOS=Alpha-Olefin Sulfonate, VS=Vegetable Soap, FP=Fe-Protein), foam agent dilution concentration (1, 3, 5%), and foam percentage (30, 50, 70%). Experiment results indicated that the surface tension of aqueous solution including foam agent, was lower when AOS was used over other foam agents. FP produced relatively stable foams in 3% or more, which produced unstable foams containing high water content and low surface tension when diluted at low concentration. Depending on foam agent types, compressive strength and thermal conductivity were similar at low density range but showed some differences at high concentration range. In addition, when concentrations of foam agent and foaming ratio increased, pore size increased and open pores are formed. In all types of foam agent, thermal conductivity were excellent, satisfying KS standards. The most outstanding performance for insulation panel was obtained when FP 3% was used.

Treatment Characteristics of Acid Mine Drainage by Porous Ceramics using Wood Flour as Pore-forming Agent (목분 기포제를 이용한 산업부산물 소재 다공성 세라믹에 의한 산성광산배수의 처리특성 연구)

  • Lee, Yeong-Nam;Yim, Soo-Bin
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.109-122
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    • 2018
  • This study was conducted to investigate the removal characteristics of heavy metals and sulfate ion from acid mine drainage by porous zeolite-slag ceramics (ZS ceramics) that was prepared by adding wood flour as pore-foaming agent while calcining the mixtures of natural zeolite and converter slag. The batch test showed that the removal efficiency of heavy metals by pellet-type porous ZS ceramics increased as the particle size of wood flour was decreased and as the weight mixing ratio of wood flour to ZS ceramics was increased. The optimal particle size and weight mixing ratio of wood flour were measured to be $75{\mu}m$ and 7~10%, respectively. The removal test with the porous ZS ceramics prepared in these optimal condition showed very high removal efficiencies: more than 98.4% for all heavy metals and 73.9% for sulfate ion. Relative to nonporous ZS ceramics, the increment of removal efficiency of heavy metals by porous ZS ceramics with $75{\mu}m$ and 10% wood flour was 5.8%, 60.5%, 36.9%, 87.7%, 10.3%, and 57.4% for Al, Cd, Cu, Mn, Pb, and Zn, respectively. The mechanism analysis of removal by the porous ZS ceramics suggested that the heavy metals and sulfate ion from acid mine drainage are eliminated by multiple reactions such as adsorption and/or ion exchange as well as precipitation and/or co-precipitation.

A Review of the Physical Performance of Lightweight Aerated Concrete for Use as an Interior Core Material in Fire Doors (방화문 내부 심재로 적용하기 위한 경량기포콘크리트의 물리적 성능 검토)

  • Hong, Sang-Hun;Kim, Bong-Joo;Jung, Ui-In;Kim, Hae-Nah;Park, Jun-Seo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.111-112
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    • 2023
  • With the development of cities, the density of the population is continuously increasing as buildings become larger and more high-rise, but since the Haeundae residential complex fire in Busan in 2010, there has been a growing need to meet the fire protection performance of buildings as large-scale fires continue to occur every year. On the other hand, fire doors, which are one of the fire protection performance of buildings, have been judged unqualified in 82% of cases when fire doors constructed on the actual site were inspected after completion. The reason for this is that paper honeycomb and glasswool, which are used as core materials for fire doors, absorb moisture, reducing thermal insulation performance, and sagging due to increased weight, leading to performance degradation due to warping in empty spaces. To overcome these problems, research is underway to apply lightweight aerated concrete, an inorganic material, as a core material. Therefore, in order to select a blowing agent that produces stable bubbles prior to the production of lightweight bubble concrete for application as a fire door inner core, this study examined the physical performance according to the type of blowing agent and dilution concentration, and the following conclusions were drawn. Compared to vegetable bubbles and independent bubbles, synthetic bubbles have 3~8% higher thermal conductivity than independent bubbles, but 3~6% lower slurry density than vegetable bubbles, and 2~13% higher compressive strength, which is thought to be an improvement of synthetic bubbles.

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Effect of Foaming Agent on the Continuous Voids in Lightweight Cellular Concrete (경량기포콘크리트의 연속공극 형성에 미치는 기포제의 영향)

  • 이승한
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.742-749
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    • 2002
  • This study was performed to clarify the formation procedure of continuous voids in cellular concrete, and to examine the effect of a foaming agent on the manufacture of cellular concrete with continuous voids. By the experiments, it was determined that cellular concrete to be formed with continuous voids is influenced by temperature, viscosity and flowability of cement paste, and stability of air voids, and is formed in accordance with cohesion of air voids. It was also found that separate voids are formed at an added amount of air voids corresponding to 2 % or less of the amount of cement, whereas an antifoaming phenomenon occurs when the added amount of air voids exceeds 9 % of the amount of cement. In products with respective cement fineness of 3,000, 6,000, and 8,000㎠/g, a higher compressive strength was exhibited at a higher cement fineness. The continuous void ratio depending on a variation in fineness was 38 %, 52 %, and 22 % in those products, respectively. That is, a highest continuous void ratio was exhibited at a cement fineness of 6,000㎠/g. When the water-cement ratio was reduced from 45% to 25%, the compressive strength of the cellular concrete was increased from 15 kgf/㎠ to 20 kgf/㎠ Thus, the reduction in water-cement ratio was effective in achieving an increase in strength without any variation in the specific gravity of the cellular concrete.

Effect of Foaming Agent Content on the Apparent Density and Compressive Strength of Lightweight Geopolymers (발포제 함량에 따른 경량 다공성 지오폴리머의 밀도와 강도 특성)

  • Lee, Sujeong;An, Eung-Mo;Cho, Young-Hoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.363-370
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    • 2016
  • Lightweight geopolymers are more readily produced and give higher fire resistant performance than foam cement concrete. Lowering the density of solid geopolymers can be achieved by inducing chemical reactions that entrain gases to foam the geopolymer structure. This paper reports on the effects of adding different concentrations of aluminum powder on the properties of cellular structured geopolymers. The apparent density of lightweight geopolymers has a range from 0.7 to $1.2g/m^3$ with 0.025, 0.05 and 0.10 wt% of a foaming agent concentration, which corresponds to about 37~60 % of the apparent density, $1.96g/cm^3$, of solid geopolymers. The compressive strength of cellular structured geopolymers decreased to 6~18 % of the compressive strength, 45 MPa of solid geopolymers. The microstructure of geopolymers gel was equivalent for both solid and cellular structured geopolymers. The workability of geopolymers with polyprophylene fibers needs to be improved as in fiber-reinforced cement concrete. The lightweight geopolymers could be used as indoor wall tile or board due to fire resistance and incombustibility of geopolymers.

Field Applicability and Manufacturing of Foam Concrete as Filler with the Low-strength and High-flow for Repair System of Ground Subsidence (지반 함몰 복구용 저강도·고유동 충전재로서 기포콘크리트 연구 및 현장적용)

  • Ma, Young;Kim, Beom-Seok;Woo, Yang-Yi;Jung, Kyung-Hun;Song, Hun-Young
    • Resources Recycling
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    • v.29 no.1
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    • pp.43-52
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    • 2020
  • The objectives of this study were to identify the optimal mix of foam concrete with the low-strength and high-flow for the repairing ground subsidence situation emergently by utilizing a large amount of industrial by-products and evaluate the possibility by applying it to the site. The factors of the experiment were the mixing ratio of mixing water and a foaming agent and the mixing ratio of foam over paste volume. The optimal mix identified by the experiment was applied to the field and basic properties were evaluated. The results of the experiment showed that the optimal mixing ratio of mixing water and the foaming agent was 10%. Moreover, when the mixing ratio of pre-foam over paste volume was 170%, it satisfied the target. However, to ensure stable quality when applying to the field, the foam mixing ratio was set 140% for the field application. The field application test of foam concrete with the low-strength and high-flow using an eco-friendly binder satisfied all target performances. Therefore, the possibility of using it as a mixture and construction method for a ground repair system is confirmed. However, there was a quality deviation between the upper part and the lower part due to the separation between foam and paste. Consequently, further studies are needed to improve it.