• Journal of Electrochemical Science and Technology
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• v.10 no.1
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• pp.14-21
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• 2019

Supported liquid membrane process usually is used for recovering or enrichment of valuable metals in the industrial wastewater. But, even if the metals in the wastewater was separated with high chemical selectivity, it cannot be enough concentrated since separation performance of supported liquid membrane (SLM) process is limited by concentration gradient between feed solution and stripping solution. If metal concentration in the stripping solution to be enough low, transport of metal through membrane can be accomplishment constantly. Therefore, Electrodialysis (ED) has been placed after SLM process and the stripping solution of SLM was used as the feed solution for the ED process. Transport of ions in the solutions is successfully performed by ED process. Thus, the metal concentration in the stripping solution does not rise as to stop ion transport. Besides, valuable metals easily are concentrated by ED process for re-use. In this study, effects of operation parameters like initial Cd(II) concentration, HCl concentration in the feed solution of SLM and applied voltage are investigated on separation efficiency, flux and permeability of the both processes. As the feed solution concentration increased, all performance values has increased. When initial concentration of 100 mg/L is used, separation performances (SP) are 55% and 70%, for SLM and consecutive process, respectively. The best HCl concentration in the feed solution of SLM has determined as 2 M, in this conditions SP are 64% and 72%, for SLM and consecutive process, respectively. With increased of applied voltage on ED process, SP of the consecutive process has been raised from 72% to 83%. According to the obtained experimental data, consecutive process has better separation performance than SLM. When the separation performances of both processes were compared for the same operating conditions, it was determined higher the separation efficiency, permeability and flux values of the consecutive process, 8%, 9% and %10.6, respectively. Consequently, the use of the consecutive process increases the performance efficiency of both processes. The consecutive process studied has quite a good chemical separation efficiency, and enrichment capability. Moreover, this process requires few water and energy.

• Journal of Pharmaceutical Investigation
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• v.38 no.1
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• pp.31-38
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• 2008

The objective of this work is to study transdermal delivery of levodopa using iontophoresis and evaluate various factors which affect the transdermal transport. Levodopa is unstable in aqueous solution, and, in order to establish a stable condition for levodopa for the duration of experiment, we investigated the stability of levodopa in aqueous solutions of different pHs with/without the addition of dextrose or the application of current. Using stable aqueous solution, we have studied the effect of pH, polarity and penetration enhancer (ethanol) on transdermal flux and compared the results. We also investigated the iontophoretic flux from hydroxypropyl cellulose (HPC) hydrogel. In vitro flux study was performed at $33^{\circ}C$, using side-by-side diffusion cell. Full thickness hairless mouse skin and rat skin were used for this work. Current densities applied were 0.4 or $0.6mA/cm^2$ and current was off after 6 hour application. Stability study showed that levodopa solution with a pH 2.5 or 4.5 maintained the initial concentration of levodopa for 24 hours with the addition of 5% dextrose. However, at pH 9.5, levodopa was unstable and 30 to 40% of levodopa degraded within 24 hours, even with the addition of 5% dextrose. Hydrogel swollen with dextrose added levodopa solution maintained about 97% of the initial concentration of levodopa for 13 days, when stored in $4^{\circ}C$. The application of current did not affect the stability of levodopa in hydrogel. Flux study from levodopa solution with pH 2.5 showed that cathodal delivery of levodopa was higher than passive or anodal delivery. When the pH of the donor solution was 4.5, anodal delivery of levodopa was higher than passive or cathodal delivery. These results seem to indicate that electroosmosis plays more dominant role than electrorepulsion in the flux of levodopa at pH 2.5, and the reverse situation applies for pH 4.5. The passive flux was unexpectedly high for the ionized levodopa. Similar to the results from aqueous solution, cumulative amount of levodopa transported trom HPC hydrogel by cathodal delivery was significantly higher than passive or anodal delivery. The treatment of 70% ethanol cotton ball by scrubbing increased passive, anodal and cathodal flux, with the largest increase for anodal flux. These results indicate that iontophoretic delivery of zwitterion such as levodopa is much complicated than that can be expected from small ionic molecules with single charge. The results also indicate that the balance between electroosmosis and electrorepulsion plays a very important role in the transport through skin.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.3
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• pp.71-76
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• 2003

A numerical simulation of selective catalytic reduction (SCR) for NO with $NH_3$ is conducted over the $V_2O_5/TiO_2$ and $WO_3-V_2O_5/TiO_2$ catalysts. The governing $NH_3$ and NO transport equations are considered by using the time-dependent FCT (Flux-Corrected Transport) algorithm. After a validating simulation for $NH_3$ step feed and shut-off experiments is analyzed, transient behavior of $NH_3$ and NO concentration in a SCR catalyst is investigated by changing such parameters as inflow $NH_3$ concentration, temperature of the catalyst, and $NH_3$/NOx ratios.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.5
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• pp.625-638
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• 1999

Air quality modeling for coastal urban region has been composed of a complex system including meteorological, chemical and physical processes and emission characteristics in complex terrain. In this study, we studied about an effect prediction for deposition phenomenon affecting on air quality in Pusan metopolitan metropolitan city. In air quality modeling including ship sources, a situation considered deposition process habe better result than not considered when compared with observed value. Air pollutants emitted into urban air during the daytime nearly removed through urban atmosphere polluted. Also these phenomena correlated concentration variation connent with sea/land breezes and terrain effect. Therefore we conclude that the concentration was low at daytime when deposition flux is high, and deposition effect on industrial complex and Dongrae region is considerable in particular.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.90-95
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• 2000

Condensation heat transfer experiments for R-22 and R-407C refrigerants mixed with mineral oil and POE oil respectively were performed in straight and U-bend sections of a microfin tube. Experimental parameters were an oil concentration from 0 to 5%, a mass flux from 100 to $400 kg/m^2s$ and an inlet quality from 0.5 to 0.9. The enhancement factors for R-22 and R-407C refrigerants at the first straight section decreased continuously as the oil concentration increased. They decreased rapidly as the mass flux decreased and inlet quality increased. The heat transfer coefficients in the U-bend were the maximum at the $90^{\circ}$ position. The heat transfer coefficients at the second straight section within the dimensionless length of 48 were larger by a maximum of 33% than the average heat transfer coefficients at the first straight section.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.337-339
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• 2012

This study investigates the combustion and heat transfer characteristics of a 100MWe pulverized coal boiler retrofitted for demonstration of oxy-coal combustion. By computational fluid dynamics (CFD), the flame temperature and wall heat flux were compared for air-fuel and oxy-fuel combustion with different $O_2$ concentration in the oxidizers. It was found that the oxy-fuel combustion requires an $O_2$ concentration higher than 27 vol.% for the boiler to achieve the similar value of wall heat flux with air-fuel combustion.

• Electrical & Electronic Materials
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• v.10 no.8
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• pp.807-811
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• 1997

In this paper we have investigated the removal characteristics of NOx by pulsed corona discharge with a multi-pointplane electrode where a magnetic field is applied in the discharge region. The efficiency of NOx removal was measured and analyzed as a function of pulse frequency gas flow rate NOx initial concentration magnetic flux density. In this result the highest removal efficiency of NOx was obtained at the following operating conditions; the frequency =400[Hz] gas flow =1[$\ell$/min] initial concentration= 400[ppm] and magnetic flux density=0.36[T].

• KIEAE Journal
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• v.2 no.3
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• pp.33-38
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• 2002

The intermediate range of temperatures($100{\sim}300^{\circ}C$) which can be achieved with CPCs(Compound Parabolic Concentrators) without tracking device provides both economic and thermal advantages for solar collector design. The present paper summarizes critical design considerations for CPC with cylindrical absorber and its optical performance using ray tracing program. Concentration ratios vary as acceptance half angle, ratio of reflector height to aperture width and ratio of reflector area to aperture area. This effects showed that the concentration ratio was increased as acceptance angle but optimum ratio of reflector height to aperture width existed at critical value. As a result of ray tracing, solar ray losses was maximized at acceptance half angle and this problem was solved by increasing absorber tube diameter. The concentrating flux distribution on the absorber surface was uniform but peak flux existed.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.5
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• pp.1011-1018
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• 1992

A series of experiment has been performed on the spray characteristics in a cylindrical confined space with the injection pressure taken as a parameter. By using a single-hole patternator and the Malvern particle sizer, the spray mass flux, drop size and volume concentration distributions along the radial and axial directions were obtained ; the line-of- sight data by Malvern particle sizer have been converted to the ring-of-sight data by using the tomographical transformation techniqe. The experimental results show that, due to the restriction on the ambient gas entrainment by the wall boundary, the effective spray angle is increasing. The spray drops were measured to be smaller in the confined space because of a large number of floating small drops by recirculation of the gas phase and the breakup of large drops by the wall collision. Also the details on the flow behavior of the confined spray are discussed.

• Membrane and Water Treatment
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• v.10 no.6
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• pp.417-429
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• 2019

Poly Sulfone nanofibers were electrospun to fabricate membranes of different characteristics. To fabricate the fiber mats, polymer concentration, flowrate, and current density were determined as the most influencing factors affecting the overall performance of the membranes and studied through Response Surface Methodology. The Box-Behnken Design method (three factors at three levels) was used to design, analyze, and optimize the parameters to achieve the best possible performance of the electrospun membranes in forward osmosis process. Also, internal concentration polarization that characterizes the efficiency of the forward osmosis membranes was determined to better assess the overall performance of the fabricated electrospun membranes. Water flux to reverse salt flux was considered as the main response to assess the performance of the membranes. As confirmed experimentally, best membrane performance with the minimal structural parameter value could be achieved when predicted optimal values were used to fabricate the membranes through electrospinning process.