• Title/Summary/Keyword: fluctuation function

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Extracting Frequency-Frequency Correlation Function from Two-Dimensional Infrared Spectroscopy: Peak Shift Measurement

  • Kwak, Kyung-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3391-3396
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    • 2012
  • Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

Responses of Chloramphenicol Immunosensor to Analyte Types

  • PARK , IN-SEON;KIM, DONG-KYUNG;KIM, NAM-SOO
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1157-1162
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    • 2004
  • A well-holder type piezoelectric chloramphenicol (CAP) immunosensor which was prepared by binding an anti­CAP antibody to the chemisorbed monolayers of various thiol or sulfide compounds over the gold electrode surface of quartz crystals through a carboxyl-amine coupling procedure, using the activation with l-ethyl- 3-(3-dimethylarninopropyl)carbodiimide­HCl and N-hydroxysulfosuccinimide, was determined for its responses to CAP, CAP succinate, and water-soluble CAP. The reaction phase used in the well holder was 0.01 M phosphate buffer (pH 7.4), and the solvent for analyte dissolution varied according to the solubility of the individual analyte. The analyte detection which was indicated by a steady-state frequency shift was finished within 10 min, except for CAP dissolved in methanol. The responses of CAP succinate and water-soluble CAP in the reaction phase were very stable, while a minute fluctuation was found with CAP.

Novel steepest descent adaptive filters derived from new performance function (새로운 성능지수 함수에 대한 직강하 적응필터)

  • 전병을;박동조
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10a
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    • pp.823-828
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    • 1992
  • A novel steepest descent adaptive filter algorithm, which uses the instantaneous stochastic gradient for the steepest descent direction, is derived from a newly devised performance index function. The performance function for the new algorithm is improved from that for the LMS in consideration that the stochastic steepest descent method is utilized to minimize the performance index iterativly. Through mathematical analysis and computer simulations, it is verified that there are substantial improvements in convergence and misadjustments even though the computational simplicity and the robustness of the LMS algorithm are hardly sacrificed. On the other hand, the new algorithm can be interpreted as a variable step size adaptive filter, and in this respect a heuristic method is proposed in order to reduce the noise caused by the step size fluctuation.

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Cost Function Estimation of Regional Manufacturing Industries in Ko-rea (지역별 제조업의 비용함수 추정)

  • 김상호;손영엽
    • Journal of the Korean Regional Science Association
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    • v.11 no.2
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    • pp.1-17
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    • 1995
  • Regional production structres are investigated through an estimation of three-input(labor, capital and material) translog cost function. The estimation uses the pooled data in which time series data of 1970-1990 are combined with cross-sectional data corresponding to firm sizes. The empirical finding are the following: (1) the factors are Allen substitutes each otner in general except Pusan and a couple of regionss, and (2) estimates are very small in its absolute value irrespective of the regions. The low elasticity estimates of this study implies that substitytability among the three inputs are very weak in the regional manufacturing production compared to that in the national production. Seoul-Kyungki metropolitan area produces not only the smallest elasticities but relatively stable estimates without much fluctuation between the sub-regions of the area.

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Optimal Design of Acoustical Characteristics of Passenger Compartment (차실 음향 최적 설계에 관한 연구)

  • 김정수;강연준
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.11a
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    • pp.183-188
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    • 2003
  • This study is to make the fundamentals of sound quality evaluation in regard of acoustical characteristics of passenger compartment. The deviation of frequency response function level within audible frequency is evaluated at receiving point in the research of room acoustics. In this study, frequency response function is the one between speaker and driver's ear positions. The positions of driver and audio speakers are optimized by analysis of acoustic mode of acoustic cavity. The main reflection planes are determined by analysis sound ray path diffused at optimized speaker positions. Finally, designer selects acoustical material by analysis of absorption effect of acoustical materials on the main reflection planes in order to avoid to distortion and fluctuation of frequency response function..

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Flame Transfer Function Modeling in a Gas Turbine Partially-premixed Combustor with Equivalence Ratio Modulation (가스터빈 부분 예혼합 연소기에서 당량비 섭동에 대한 화염전달함수 모델링)

  • Kim, Jihwan;Kim, Daesik
    • Journal of ILASS-Korea
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    • v.22 no.2
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    • pp.55-61
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    • 2017
  • This study has investigated the relationship between heat release fluctuations and the flow perturbations in a partially premixed gas turbine combustor using a commercial CFD code. Special focus of the current work is placed on the effect of equivalence ratio on the flame dynamics in a partially-premixed system. As the first step for this combustion dynamics study in the non-perfectly premixed combustor, flame behaviors are modeled and then compared with measured results under both steady and unsteady conditions. The calculated results of the flame transfer function with equivalence ratio fluctuation are found to well capture the main qualitative characteristics of the combustion dynamics for the partially-premixed flames.

A novel time scale of dynamic heterogeneity in a supercooled liquid system

  • Mun, Seok-Jin;Park, Gye-Hyeon;Park, Sang-Won;Jeong, Yeon-Jun
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.138-146
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    • 2015
  • 액체 상태의 물질이 매우 급속하게 냉각되면 일반적으로 과냉각액체(supercooled liquid) 상태에 도달한다. 과냉각액체는 더 낮은 온도에서 유리상(glass phase)으로 상전이를 일으킨다고 알려져 있는데, 이때 나타나는 동역학적 불균일성(dynamic heterogeneity)은 상전이를 기술하는데 중요한 역할을 한다. 그러나 일반적인 액체의 상전이를 연구할 때 주로 사용되던 상관함수(correlation function)으로는 이러한 불균일성을 정량적으로 표현하기 어렵기 때문에 동역학적 민감도(dynamic susceptibility)나 multi-time correlation function 등 동역학적 성질(dynamic property)로부터 특징적인 시간 개념 및 거리 개념을 도출하려는 연구가 많이 진행되어 왔다. 본 논문에서는 일반적으로 특징적인 거리 개념을 도출해 내는데 사용되는 4점 밀도 상관함수(four-point density correlation function)인 dynamic susceptibility(${\chi}^4$)가 입자 밀도의 요동(fluctuation)의 상관관계(correlation)가 지속되는 특징적인 시간 개념에 대한 정보 또한 포함하고 있다는 점에 주목하였다. 이에 따라 ${\chi}^4$의 시간에 대한 적분인 ${\tau}_4$를 새롭게 도입하였으며 그 결과로 ${\tau}_4$는 three-time density correlation function으로부터 도출한 ${\tau}_{Dh}$와 같은 축척(scaling)을 가지는 것을 확인하였다. 과냉각액체에 대한 장난감 모형(toy model)의 일종인 "Lennard-Jones potential 하에서 운동하는 서로 다른 두 종류의 입자들"을 연구에 사용하였다.

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Decision of Producer's Specification Limits Considering Types of Loss Function (손실함수의 형태를 고려한 생산자 규격한계의 결정)

  • Kim, Dong-Hyuk;Chung, Young-Bae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.41 no.3
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    • pp.145-153
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    • 2018
  • Taguchi regarded the concept of quality as 'total loss to society due to fluctuations in quality characteristics from the time of supplied to the customer.' The loss function is a representative tool that can quantitatively convert the loss that occurs due to the deviation of the quality characteristic value from the target value. This has been utilized in various studies with the advantage that it can change the social loss caused by fluctuation of quality characteristics to economic cost. The loss function has also been used extensively in the study of producer specification limits. However, in previous studies, only the second order loss function of Taguchi is used. Therefore, various types of losses that can occur in the process can't be considered. In this study, we divide the types of losses that can occur in the process considering the first and second loss functions and the Spiring's reflected normal loss function, and perform total inspection before delivering the customer to determine the optimal producer specification limit that minimizes the total cost. Also, we will divide the quality policy for the products beyond the specification limits into two. In addition, we will show the illustration of expected loss cost change of each model according to the change of major condition such as customer specifications and maximum loss cost.

Reliability-based stochastic finite element using the explicit probability density function

  • Rezan Chobdarian;Azad Yazdani;Hooshang Dabbagh;Mohammad-Rashid Salimi
    • Structural Engineering and Mechanics
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    • v.86 no.3
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    • pp.349-359
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    • 2023
  • This paper presents a technique for determining the optimal number of elements in stochastic finite element analysis based on reliability analysis. Using the change-of-variable perturbation stochastic finite element approach, the probability density function of the dynamic responses of stochastic structures is explicitly determined. This method combines the perturbation stochastic finite element method with the change-of-variable technique into a united model. To further examine the relationships between the random fields, discretization of the random field parameters, such as the variance function and the scale of fluctuation, is also performed. Accordingly, the reliability index is calculated based on the explicit probability density function of responses with Gaussian or non-Gaussian random fields in any number of elements corresponding to the random field discretization. The numerical examples illustrate the effectiveness of the proposed method for a one-dimensional cantilever reinforced concrete column and a two-dimensional steel plate shear wall. The benefit of this method is that the probability density function of responses can be obtained explicitly without the use simulation techniques. Any type of random variable with any statistical distribution can be incorporated into the calculations, regardless of the restrictions imposed by the type of statistical distribution of random variables. Consequently, this method can be utilized as a suitable guideline for the efficient implementation of stochastic finite element analysis of structures, regardless of the statistical distribution of random variables.

A study on dual mass flywheel for a jeep vehicle with Diesel Engine (디젤엔진을 탑재한 짚차량의 2분할 플라이휠에 관한 연구)

  • 정종안;조찬기
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.17-22
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    • 1997
  • This paper reals with the structure and function of duel mass flywheel. Damping effects of engine rotational fluctuation are compared with those of pre-damper clutch and duel mass flywheel and driven- system behavior is estimated engine idle r.p.m. The reason of gear rattle noise is higher in summer than winter and driving longer period than initial driving is due to affection by drag torque changing. The above-contents can be used on the design of clutch system and transmission matching including engine and duel mass flywheel.

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