• Title/Summary/Keyword: flat sheet membrane

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On the Mass Transfer Behaviors in Hollcw-Fiber Membrane Modules for $CO_2$ Separation (이산화탄소 분리를 위한 중공사막 모듈에서의 물질전달 거동)

  • 전명석;김영목;이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.04a
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    • pp.51-52
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    • 1994
  • High permeability, selectivity and stability are the basic properties also required for membrane gas separations. The $CO_2$ separation by liquid membranes has been developed as a new technique to improve the permeability and selectivity of polymeric membranes. Sirkar et al.(1) have atlempted the hollow-fiber contained liquid membrane technique under four different operational modes, and permeation models have been proposed for all modes. Compared to a conventional liquid membrane, the diffusional resistance decreased by the work of Teramoto et al.(2), who referred to a moving liquid membrane. Recently, Shelekhin and Beckman (3) considered the possibility of combining absorption and membrane separation processes in one integrated system called a membrane absorber. Their analysis could be predicted effectively the performance of flat sheet membrane, however, there are restrictions for considering a flow effect. The gas absorption rate is determined by both an interfacial area and a mass transfer coefficient. It can be easily understood that although the mass transfer coefficients in hollow fiber modules are smaller than in conventional contactors, the substantial increase of the interfacial area can result in a more efficient absorber (4). In order to predict a performance in the general system of hollow-fiber membrane absorber, a gas-liquid mass transfor should be investigated inevitably. The influence of liquid velocity on both a mass transfer and a performance will be described, and then compared with experimental results. A present study is attempted to provide the fundamentals for understanding aspects of promising a hollow-fiber membrane absorber.

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Industrial dairy wastewater purification by shear-enhanced membrane filtration: The effects of vibration

  • Kertesz, Szabolcs
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.73-86
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    • 2014
  • Membrane fouling is a major challenge limiting the use of membrane applications. In this study high induced shear rates were utilized at the membrane surface in order to reduce the organic and inorganic scaling by using the torsional vibration of flat sheet membranes. The performances of a vibratory shear-enhanced processing (VSEP) system for the ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membrane filtration of industrial dairy wastewater were investigated. The vibration and non-vibration methods were compared with the same membrane and operational parameters during the purification of real dairy industrial process wastewater. In the initial experiments, short-term tests were carried out in which the effects of vibration amplitude, recirculation flow rate and transmembrane pressure were measured and compared. The permeate flux, turbidity, conductivity and chemical oxygen demand (COD) reduction of dairy wastewater were investigated by using UF, NF and RO membranes with vibration and non-vibration methods. In the subsequent experiments, concentration tests were also carried out. Finally, scanning electron microscopy (SEM) revealed that the vibration method gave a better performance, which can be attributed to the higher membrane shear rate, which reduces the concentration of solids at the membrane, and the transmission.

Prediction of Earings in the Deep Drawing Processes of a Cylindrical Cup (원통컵 디프드로잉 공정의 귀발생 예측)

  • 이승열;이승열;금영탁;정관수;박진무
    • Transactions of Materials Processing
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    • v.4 no.3
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    • pp.222-232
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    • 1995
  • The planar anisotripic FEM analysis for predicting earing profiles and draw-in amounts in the deep-drawing process is introduced. An implicit, incremental, updated Lagrangian formulation with a rigid-viscoplastic constitutive equation is employed. Contact and friction are considered through the mesh-based unit vector and normal contact pressure. The consistent full set of governing relations, which is comprising euilbrium and geometric constraint equations, is appropriately linearized. Barlat's strain-rate potential is employed, whose in-plane anisotropic properties are taken into account with anisotropic coefficients and potential parameters. The linear triangular membrane elements are used for depicting the formed sheet. In the numerical simulations of deep drawing processes of a flat-top cylindrical cup for 2090-T3 aluminum alloy sheet show good agreement with experiments, although some discrepancies were observed in the directional trend of cup height and thickness strains.

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Multi- effect air gap membrane distillation process for pesticide wastewater treatment

  • Pangarkar, Bhausaheb L.;Deshmukh, Samir K.;Thorat, Prashant V.
    • Membrane and Water Treatment
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    • v.8 no.6
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    • pp.529-541
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    • 2017
  • A multi-effect air gap membrane distillation (ME-AGMD) module for pesticide wastewater treatment is studied with internal heat recovery, sensible heat of brine recovery, number of stages and the use of fresh feed as cooling water in a single module is implemented in this study. A flat sheet polytetrafluroethylene (PTFE) membrane was used in the 4-stage ME-AGMD module. The maximum value of permeate flux could reach $38.62L/m^2h$ at feed -coolant water temperature difference about $52^{\circ}C$. The performance parameter of the module like, specific energy consumption and gain output ratio (GOR) was investigated for the module with and without heat recovery. Also, the module performance was characterized with respect to the separation efficiency of several important water quality parameters. The removal efficiency of the module was found to be >98.8% irrespective water quality parameters. During the experiment the membrane fouling was caused due to the deposition of the salt/crystal on the membrane surface. The membrane fouling was controlled by membrane module washing cycle 9 h and also by acidification of the feed water (pH=4) using 0.1M HCl solution.

Morphological study of synthesized PVDF membrane using different non-solvents for coagulation

  • Yadav, Meenakshi;Upadhyay, Sushant;Singh, Kailash;Chaturvedi, Tarun Kumar;Vashishtha, Manish
    • Membrane and Water Treatment
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    • v.13 no.4
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    • pp.173-181
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    • 2022
  • Polyvinylidene fluoride (PVDF) flat sheet hydrophobic membranes were prepared using 16 wt% PVDF in Dimethyl acetamide (DMAc) by phase inversion technique for desalination application using Membrane Distillation (MD). In this work, the effect of coagulation mediums such as ethanol and water as well their synergistic behavior on the fabricated PVDF membrane morphology was studied using SEM. Moreover, other characteristics required for the membrane distillation applications namely porosity, hydrophobicity and tensile strength were measured using the gravimetric method, sessile drop method and universal testing machine respectively. It was observed that the membrane morphology paradigm shifted from the finger-like structure to the sponge-like structure on increasing the ethanol concentration in coagulant. The porosity of the fabricated membrane was under the required MD range and found to be 57.3% at 16 weight % of PVDF in DMAc solvent under a pure ethanol coagulant bath. Moreover, the top surface contact angle ranges from 85° to 115° on increasing the bath concentration from CBC 0 to CBC 100 at 16 weight % of PVDF in DMAc solvent.

Preparation of PVdF/GO Composite Nanofibrous Flat Membrane and its Permeation Characteristics in Activated Sludge (PVdF/GO 복합 나노섬유 평막의 제조 및 활성슬러지 내 투과특성)

  • Won, In Hye;Jang, Wongi;Chung, Kun Yong;Byun, Hongsik
    • Membrane Journal
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    • v.25 no.1
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    • pp.67-74
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    • 2015
  • In this study the nanofiber was prepared by electrospinning method with polyvinylidene fluoride (PVdF) and a completely dispersed solution of graphene oxide (GO) in the mixed solvent of dimethylformamide (DMF) and acetone. The $0.4{\mu}m$ pore size microfiltration flat membrane was made by increasing layers of the PVdF/GO composite nanofiber. Also, transmembrane pressure (TMP) was measured in order to evaluate fouling of the PVdF/GO composite membrane which was introduced GO reducing biological fouling with the intrinsic antibacterial characteristics. The permeate experiments were carried out simultaneously for the PVdF/GO and commercialized CPVC (chlorinated polyvinyl chloride) flat membranes with $0.01m^2$ effective area in the activated sludge solution of MLSS 4,500 mg/L. TMP of PVdF/GO membrane decreased up to 79% lower than that of CPVC for $10L/m^2{\cdot}h$ permeate flux without air supply. Also, for the case of run/stop operational mode, TMP of PVdF/GO membrane decreased up to 69% lower than that of CPVC for $10L/m^2{\cdot}h$.

Forward Osmosis Based Seawater Desalination using Liquid Fertilizer as Draw Solution (액상 비료를 유도 용액으로 사용하는 정삼투 기반의 해수 담수화)

  • Park, Seong-Jik;An, Hee-Kyung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.2
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    • pp.21-27
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    • 2013
  • The present study explored the way to desalinate seawater for agricultural irrigation using forward osmosis (FO) process using liquid fertilizer as draw solution. FO experiments were performed in a cross flow mode using flat sheet FO membrane. The effect of membrane orientation, flow rate, and draw solution concentration on the performance of forward osmosis was investigated by measuring water flux of forward osmosis membrane. The water flux when the draw solution was placed against the membrane active layer was lower than the water flux when the feed solution was placed against the membrane active layer. This results indicated that the decrease of effective osmotic pressure by dilutive internal concentration polarization was less than that by concentrative internal concentration polarization. Increasing flow rate from 66.7 to 133.1 $cm^3$/min resulted in increase of the water flux when the membrane active layer orient to draw solution and feed solution, respectively. The reduction of resistance to water flow increased water flux at higher flow rate. The water flux of FO membrane increased with increasing draw solution concentration from 10000 to 30000 mg/L. The water flux for $KH_2PO_4$ draw solution was similar to that for commercial fertilizer. Optimization of FO process would contribute to economically desalinate brackish water for agricultural use.

Performance of a submerged membrane bioreactor for wastewater mimicking fish meal processing effluent

  • Lopez, Guadalupe;Almendariz, Francisco J.;Heran, Marc;Lesage, Geoffroy;Perez, Sergio
    • Membrane and Water Treatment
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    • v.9 no.4
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    • pp.263-271
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    • 2018
  • The objective of this work was to analyze organic matter removal, nitrification, biomass growth and membrane fouling in a submerged flat-sheet membrane bioreactor, fed with synthetic wastewater, of similar composition to the effluents generated in a fish meal industry. After biomass acclimatization with saline conditions of 12 gNaCl/L and COD/N ratio of 15 in the bioreactor, results showed that the organic matter removal was higher than 90%, for all organic loading rates (0.8, 1, 1.33 and $2gCOD/L{\cdot}d$) and nitrogen loading rates (0.053, 0.067, 0.089 and $0.133gN/L{\cdot}d$) tested during the study. However, nitrification was only carried out with the lowest OLR ($0.8gCOD/L{\cdot}d$) and NLR ($0.053gN/L{\cdot}d$). An excessive concentration of organic matter in the wastewater appears as a limiting factor to this process' operating conditions, where nitrification values of 65% were reached, including nitrogen assimilation to produce biomass. The analysis of membrane fouling showed that the bio-cake formation at the membrane surface is the most impacting mechanism responsible of this phenomenon and it was demonstrated that organic and nitrogen loading rates variations affected membrane fouling rate.

Removal of Silica and Humic Acid from Brackish Water with Calcite (Calcite를 이용한 brackish water 내의 실리카와 휴믹산의 제거에 관한 연구)

  • 박소희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.243-245
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    • 2002
  • Brackish water desalination using reverse osmosis(RO) membrane is more useful and economic than sea water to solve the shortage of fresh water supply because of its low total dissolved solid(TDS) contents. Silica and humic acid in brackish water make serious fouling problems and cause the decline of permeate flux and increase of operating pressure. In this study, the experiments for removal of silica and humic acid were conducted with calcite particles to prevent membrane fouling and investigated the effect of pH of feed water Adsorption of silica to calcite was higher at pH=7.5 than 9.5 and removal rate was increased according to increase of initial concentration of silica. The effect of pH on adsorption of humic acid was not significant but at low initial concentration the adsorption of humic acid was enhanced at pH 7.5. The result of this study expect to apply to brackish water desalination experiment of flat-sheet reverse osmosis membrane.

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Silk Fibroin Membrane as Guided Bone Regeneration in Rat Calvarial Defects

  • Kweon, Hae-Yong;Kim, Seong-Gon;An, Jin-Hee;Shim, Hye-Won;Yang, Byoung-Eun;Kim, Jwa-Young;Jo, You-Young;Yeo, Joo-Hong;Lee, Kwang-Gill
    • International Journal of Industrial Entomology and Biomaterials
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    • v.21 no.2
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    • pp.175-179
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    • 2010
  • Silk fibroin membrane was prepared and examined to know the feasibility of SF membrane as guided bone regeneration. The morphology of silk membrane was flat and smooth surface. The conformation of silk fibroin was $\beta$-sheet structure. When the silk membrane was applied on the rat calvarial defect model, it showed significantly higher new bone formation than uncovered control in histomorphometric analysis. The silk membrane was covered by thin fibrotic tissue and there was not observed any inflammatory cells infiltration. In conclusion, silk fibroin membrane could be useful materials for guided bone regeneration.