• Title/Summary/Keyword: flammable limit

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Fire Identification based on Physical Properties of Bean Oil (대두유의 물리적 특성에 따른 화재감식)

  • Jin, Bog-Kwon;Jung, Soo-Il
    • Fire Science and Engineering
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    • v.22 no.3
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    • pp.246-251
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    • 2008
  • Oil Fire easily generates fire in the pressure of the atmosphere and below the normal temperature. Because these discharge flammable gas and ignite within the combustibles limit in conditioning to be assisted air and an invariable density. But Kitchen Fire shows very specific properties of matter and energy Qualification in most cases even though the same oil fires occured. In this Paper, around these specific character that Kitchen Fire have Properties of matter or energy Qualification studied on the genetic mechanism and counter measure scheme.

On the Extinction Characteristics of the Interacting Lean-Lean Premixed Flames (상호작용을 하는 희박-희박 예혼합화염의 소화특성에 관한 연구)

  • 정석호;김종수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.2
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    • pp.232-240
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    • 1986
  • Extinction characteristics of the two interacting premixed flames are analyzed for the effects of flame stretch and preferential diffusion using large activation energy asymptotic analysis by adopting counterflow system as a model problem. Results show that the flammable limit of the thermally interacting premixed flames is extended compared to the single flame, and the extinction mechanism is classified into weak and strong interactions. As the lewis number of the deficient species increases, the region of strong interaction diminishes which can explain the different characteristics of the extinction boundaries of the lean (rich) methane/air and butane/air flames. The influence of the flame stretch to the interaction boundaries is also studied.

Calculation of the TNT Equivalent Mass of the Possible Explosion of CO, CH4, and C2H4 (CO와 CH4, C2H4 혼합 가스 폭발에 대한 TNT 등가량 계산)

  • Kim, Minju;Kwon, Sangki
    • Explosives and Blasting
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    • v.38 no.1
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    • pp.1-13
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    • 2020
  • Gas explosion accidents are steadily being issued due to increased gas consumption in Korea and foreign countries. To analyze the effects of these gas explosions, a TNT equivalent method is used. In this study, the TNT equivalent was calculated in the event of an explosion due to the volume content in the air of CO, CH4 and C2H4, the typical flammable gases emitted by coal. Also, the peak overpressure and impulse variation with the distance from explosion point were compared and analyzed by gas using the calculated equivalent value of TNT. The upper limit of the TNT equivalent for the three mixed gases is up to five times larger than the other gases mixture. In addition, the peak overpressure and impulse, which are factors of the TNT characteristic curve, are also increasing as the number of gases increases.

A Study on Establishing Target Reliability Levels for Flammable Gas Transmission Pipelines (가연성가스 수송배관에 대한 목표 신뢰도 수준 설정에 관한 연구)

  • Lee, Jin-Han;Jo, Young-Do;Moon, Jong-Sam
    • Journal of the Korean Institute of Gas
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    • v.22 no.6
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    • pp.52-58
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    • 2018
  • In reliability based design and assessment (RBDA) methodology, reliability targets are used to ensure that safety levels are met relevant limit states in the stage of design and maintenance. The target reliability for flammable gas pipelines have not been developed yet in Korea. Instead of the reliability targets, the tolerable criteria for risk measures such as societal and individual risk have been applied in pipeline risk management. This paper introduces the procedures to develop the target reliability using tolerable risk criteria for societal and individual risk which can be enforced for high pressure natural gas pipelines in quantitative risk assessment. In addition, we propose the target reliability for natural gas and hydrogen gas transmission pipelines by the procedures.

A Study on the Safety of Carbon Manufacturing By-product Gas Emissions (카본제조 부생가스 배출 안전성에 관한 연구)

  • Joo, Jong-Yul;Jeong Phil-Hoon;Kim, Sang-Gil;Sung-Eun, Lee
    • Journal of the Korea Safety Management & Science
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    • v.26 no.1
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    • pp.99-106
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    • 2024
  • In the event of an emergency such as facility shutdown during process operation, the by-product gas must be urgently discharged to the vent stack to prevent leakage, fire, and explosion. At this time, the explosion drop value of the released by-product gas is calculated using ISO 10156 formula, which is 27.7 vol%. Therefore, it does not correspond to flammable gas because it is less than 13% of the explosion drop value, which is the standard for flammable gas defined by the Occupational Safety and Health Act, and since the explosion drop value is high, it can be seen that the risk of fire explosion is low even if it is discharged urgently with the vent stock. As a result of calculating the range of explosion hazard sites for hydrogen gas discharged to the Bent Stack according to KS C IEC 60079-10-1, 23 meters were calculated. Since hydrogen is lighter than air, electromechanical devices should not be installed within 23 meters of the upper portion of the Bent Stack, and if it is not possible, an explosion-proof electromechanical device suitable for type 1 of dangerous place should be installed. In addition, the height of the stack should be at least 5 meters so that the diffusion of by-product gas is facilitated in case of emergency discharge, and it should be installed so that there are no obstacles around it.

A Study on the Prevention Measures against Fire and Explosion Accidents during Splash Filling in Batch Process (회분식 공정에서 스플래쉬 필링(Splash Filling) 작업으로 인한 화재·폭발 사고 예방대책에 관한 연구)

  • Kim, Sang Ryung;Lee, Dae Jun;Kim, Jung Duk;Kim, Sang Gil;Yang, Won Baek;Rhim, Jong Guk
    • Journal of the Korean Institute of Gas
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    • v.24 no.3
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    • pp.33-39
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    • 2020
  • In general, in a batch reaction process in which products are made using flammable liquids, splash filling is used to clean the walls of the reactor by spraying flammable liquids, which are raw materials used for product, during cleaning of the reactor after work. During this process, mist of flammable liquid is generated, the lower limit of explosion is lowered, and fire·explosion may occur due to discharges caused by various types of complex charges, such as flow charge, collision charge, and ejection charge. Therefore, based on the recent accident case, to identify the risk when working in the form of splash filling with toluene in a batch process and perform an explosion impact analysis using the TNT equivalent method After that, we will analyze the accident results and suggest preventive measures such as constant purge system, improvement of cleaning method, and use of tantalum to prevent such accident.

Dispersion Characteristics of Hydrogen Gas by the Effect of Leakage Hole Size in Enclosure Space (누출공 크기에 따른 밀폐공간 내 수소 가스의 확산 특성)

  • Choi, Jinwook;Li, Longnan;Park, Chul-Woo;Lee, Seong Hyuk;Kim, Daejoong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.5
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    • pp.26-35
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    • 2016
  • As a potential clean energy resource, the production and consumption of hydrogen gas are expected to gradually increase, so that hydrogen related studies are also increasing. The thermal and chemical properties of hydrogen result in its high flammability; in particular, there is a high risk if leaks occur within an enclosed space. In this study, we applied the computational fluid dynamics method to conduct a numerical study on the leakage behavior of hydrogen gas and compared these numerical study results with an experimental study. The leakage hole diameter was selected as an important parameter and the hydrogen gas dispersion behavior in an enclosed space was investigated through various analytical methods. Moreover, the flammable regions were investigated as a function of the leakage time and leakage hole size. We found that the growth rate of the flammable region increases rapidly with increasing leakage hole size. We also investigated the relation between the mass flow rate and the critical time when the hydrogen gas reaches the ceiling. The analysis of the monitoring points showed that the hydrogen gas dispersion behavior is isotropic and independent of the geometry. We found that the concentration of gas in an enclosed space is affected by both the leakage flow rate and amount of gas accumulated in the enclosure.

Measurement and Prediction of Fire and Explosion Properties of n-Ethylanilne (노말에틸아닐린의 화재 및 폭발 특성치의 측정 및 예측)

  • Ha, Dong-Myeong
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.474-478
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    • 2018
  • For process safety, fire and explosion characteristics of combustible materials handled at industrial fields must be available. The combustion properties for the prevention of the accidents in the work place are flash point, fire point, explosion limit, and autoignition temperature (AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. In the chemical industries, n-ethylaniline which is widely used as a raw material of intermediate products and rubber chemicals was selected. For safe handling of n-ethyl aniline, the flash point, the fire point and the AIT were measured. The lower explosion limit (LEL)of n-ethylaniline was calculated using the lower flash point obtained in the experiment. The flash points of n- ethylaniline by using the Setaflash and Pensky-Martens closed-cup testers measured $77^{\circ}C$ and $82^{\circ}C$, respectively. The flash points of n-ethylaniline using the Tag and Cleveland open cup testers are measured $85^{\circ}C$ and $92^{\circ}C$, respectively. The AIT of the measured n-ethyl aniline by the ASTM E659 apparatus was measured at $396^{\circ}C$. The LEL of n-ethylaniline measured by Setaflash closed-cup tester at $77^{\circ}C$ was calculated to be 1.02 vol%. In this study, it was possible to predict the LEL by using the lower flash point of n-ethylaniline measured by closed-cup tester. The relationship between the ignition temperature and the ignition delay time of the n-ethylaniline proposed in this study makes it possible to predict the ignition delay time at different ignition temperatures.

Numerical Analysis of Gas Leakage and Diffusion Behavior in Underground Combined Cycle Power Plant (지하 복합발전 플랜트 내에서의 가스 누출 및 확산 거동에 관한 수치해석 연구)

  • Bang, Joo Won;Lee, Seong Hyuk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.118-124
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    • 2017
  • In this study, a numerical simulation was performed using commercial code Fluent(v.17.1). The underground Combined Cycle Power Plant (CCPP) was simplified to analyze the methane gas leakage with the crack size and position. In addition, extensive numerical simulations were carried out for different crack sizes from 10 mm to 20 mm. The crack position is the gas leakage, which is assumed to be near the pipe elbow and the gas turbine. A total of 4 cases were compared and analyzed. To analyze the gas leakage, the concept of the Lower Flammable Limit (LFL) was applied. The leakage distance was defined in the longitudinal direction, and the transverse direction was estimated and quantitatively analyzed. As a result, the leakage distance in the longitudinal direction varies by 52.3 % depending on the crack size at the same crack position. Moreover, the maximum difference was 34.8 % according to the crack position when the crack sizes are identical. As jet flow impacts on the obstacle and changes its direction, the recirculation flows are formed. These results are expected to provide useful data to optimize the location and number of gas detections in confined spaces, such as underground CCPP.

The Measurement of Lower Flash Point for tert-Pentanol+n-Decane System Using Tag Open-Cup Tester (Tag 개방식 장치를 이용한 tert-Pentanol+n-Decane 계의 하부인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.16 no.5
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    • pp.41-46
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    • 2012
  • The flash point the lowest temperature at which the concentration of vapor of the substance in the air reaches the lower flammability limit(LFL), and is one of the most important physical properties used to determine the potential for fire and explosion hazards of industrial materials. The most published flash point data was for pure components and the flash points of the binary solutions that have flammable components, appear to be scarce in the literature. In the present study, the flash points of tert-pentanol+n-decane system were measured by Tag open-cup tester. The measured data were compared with the values calculated by the Raoult's law and the optimization methods based on the Wilson and NRTL equations. The calculated values by optimization methods were found to be better than those based on the Raoult's law.