• International Journal of Advanced Culture Technology
• /
• v.11 no.3
• /
• pp.346-357
• /
• 2023

The purpose of this study is to suggest improvement plans for prevention regulations by reflecting the toxicity, fire and explosion effects of hazardous materials factories and surrounding areas using an off-site consequence assessment program. Regarding the effects of the hydrogen cyanide leak accident, which is the 1st petroleum of the 4th class flammable liquid, Areal Locations of Hazardous Atmospheres (ALOHA) program was used to compare and analyze the extent of damage effects for toxicity, overpressure, and radiation. As a result, the toxicity was analyzed to exceed 5km in the area with Acute exposure guideline level (AEGL)-2 concentration or higher, the overpressure was 103m in the range of 1 psi or more, and the radiant heat was analyzed to be 724m in the range of 2kw/m² or more. Toxicity and radiation affected the area outside the hazardous material storage area, but the overpressure was limited to the inside of the hazardous material storage area. Therefore, we propose to improve the safety management of hazardous materials by conducting a risk assessment for hazardous materials and reflecting the results in internal and external emergency response plans to prepare prevention regulations.

• Korean Chemical Engineering Research
• /
• v.61 no.1
• /
• pp.74-79
• /
• 2023

As the demand for hydrogen increases, the facilities for storing hydrogen has been important, and a few laws for hydrogen facilities should be complied. According to the Occupational Safety and Health Act in Korea, in case liquid hydrogen with a storage capacity of 5 tons or more is handled, a Process Safety Management (PSM) system should be complied. However, there are some standards which are not proper for flammable low-temperature liquefied substances on the current Occupational Safety and Health Act. In this study, 7 key points in process safey information and safety operation procedures among PSM components are suggested and how these key points should be improved is derived based on scientific analysis.

• Nuclear Engineering and Technology
• /
• v.54 no.12
• /
• pp.4534-4550
• /
• 2022

Integrated severe accident codes should be capable of simulating not only specific physical phenomena but also entire plant behaviors, and in a sufficiently fast time. However, significant uncertainty may exist owing to the numerous parametric models and interactions among the various phenomena. The primary objectives of this study are to present best-practice uncertainty and sensitivity analysis results regarding the evolutions of severe accidents (SAs) and fission product source terms and to determine the effects of mitigation measures on them, as expected during a short-term station blackout (STSBO) of a reference pressurized water reactor (optimized power reactor (OPR)1000). Three reference scenarios related to the STSBO accident are considered: one base and two mitigation scenarios, and the impacts of dedicated severe accident mitigation (SAM) actions on the results of interest are analyzed (such as flammable gas generation). The uncertainties are quantified based on a random set of Monte Carlo samples per case scenario. The relative importance values of the uncertain input parameters to the results of interest are quantitatively evaluated through a relevant sensitivity/importance analysis.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.37 no.4
• /
• pp.347-357
• /
• 2024

Oxide semiconductor gas sensors are widely used for detecting toxic, explosive, and flammable gases due to their simple structure, cost-effectiveness, and potential integration into compact devices. However, their reliable gas detection is hindered by a longstanding issue known as humidity dependence, wherein the sensor resistance and gas response change significantly in the presence of moisture. This problem has persisted since the inception of oxide semiconductor gas sensors in the 1960s. This paper explores the root causes of humidity dependence in oxide semiconductor gas sensors and presents strategies to address this challenge. Mitigation strategies include functionalizing the gas-sensing material with noble metal/transition metal oxides and rare-earth/rare-earth oxides, as well as implementing a moisture barrier layer to prevent moisture diffusion into the gas-sensing film. Developing oxide semiconductor gas sensors immune to humidity dependence is expected to yield substantial socioeconomic benefits by enabling medical diagnosis, food quality assessment, environmental monitoring, and sensor network establishment.

• Journal of the Korean Society of Safety
• /
• v.38 no.6
• /
• pp.9-15
• /
• 2023

Hydrogen is gaining attention as a sustainable and renewable energy source, potentially replacing fossil fuels. Its high diffusivity, wide flammable range, and low ignition energy make it prone to ignition even with minimal friction, potentially leading to fire and explosion risks. Workplaces manage ignition risks by classifying areas with explosive atmospheres. However, the effective installation of a blast wall can significantly limit the spread of hydrogen, thereby enhancing workplace safety. To optimize the wall installation of this barrier, we employed the response surface methodology (RSM), considering variables such as wall distance, height, and width. We performed 17 simulations using the Box-Behnken design, conducted using FLACS software. This process yielded two objective functions: explosion likelihood near the barrier and explosion overpressure affecting the blast wall. We successfully achieved the optimal solution using multi-objective optimization for these two functions. We validated the optimal solution through verification simulations to ensure reliability, maintaining a margin of error of 5%. We anticipated that this method would efficiently determine the most effective installation of a blast wall while enhancing workplace safety.

• Fire Science and Engineering
• /
• v.15 no.4
• /
• pp.41-48
• /
• 2001

Halogen-based fire suppressing agents have been the most effective fire suppressants and widely used for flammable liquid and electric fire. However they have environmental problems causing stratospheric ozone depletion and globe warming. As a substitution of halon, fire suppression system using fine water mist is one of an effective fire suppressant. Suffocating and cooling effects of water mist are increased by the evaporation characteristics because it has droplet size less than 1,000 $\mu{m}$ and very large surface area. In this study, the extinguishing characteristics of fire was measured with changing of water mist droplet size, flow density; discharge pressure, and fire size. As a result, the extinguishing time of pool fire was shortened with the increase of flow density and in case of low flow density less than 0.5$\pm$0.05 ml/$\textrm{cm}^2$ . min, the extinguishing time was shortened with the increase of droplet size. The cycling discharge was effective for $\eta$-heptane pool fire, and total amount of water mist required to extinguish fire was reduced to a quarter compare with continuous discharge.

• Korean Chemical Engineering Research
• /
• v.55 no.5
• /
• pp.618-622
• /
• 2017

Gasoline is a widely used product as a source for energy in homes, the automotive industry, and for industrial power generation, and it is also a product with a high risk of fire and explosion. In this study, to examine the risk for explosion for gasoline, PG, MG and RG, which are categorized according to octane number, were used as test specimens to measure their explosion limit according changes in oxygen concentration. The explosion limit for 21% oxygen concentration in air were confirmed to be 1.5~10.9%, 1.4~8.1%, and 1.3~7.6%, respectively, and the MOC for each of the test sample were confirmed to be 10.9%. The explosion limit measured in the test performed in this study confirmed between a 1.2%~7.6% wider explosion limit for the currently accepted MSDS for gasoline, and therefore it is considered that the results of this study can provide significant reference for preventing fires and explosions for process used gasoline.

• Journal of Korean Society of Disaster and Security
• /
• v.9 no.2
• /
• pp.33-42
• /
• 2016

Domestic harbor yard storage facilities are a place specifically located in a container terminal for import and export of packaged dangerous goods, and due to the recent relaxed criteria for the secured open area, concerns for the extended damage upon accidents are increasing. In this study, the impact of damages by radiant heat was analyzed through a simulation of a pool fire caused by the leakage of flammable liquids from a tank container. As a result, it was analyzed that the distance of radiant heat according to threshold damage levels was beyond the current criteria of the secured open area, and the structural damage of adjacent containers could happen within a very short time if they were exposed to the early pool fire continuously. It is considered that this study will be helpful in preparing the proper criteria for the secured open area between yard storage facilities in a container terminal.

• Fire Science and Engineering
• /
• v.31 no.3
• /
• pp.54-62
• /
• 2017

The aim of this study is to find out the water spray features of in-rack sprinklers for rack storage. This study conducted cold water flow test, measurement of spray angle and densities by angles for sprinkler head manufactured by a Korean company and a U.S. company. Korean sprinkler head had a wide angle of water spary. The water spray angle of a U.S. sprinkler head was narrow compared to the Korean sprinkler. In comparison of the Korean head with U.S. head of the same K80, the Korean head can send water to parts that are difficult to directly spray, but the spraying density by angle was low. U.S. head can send more water than Korean head at a narrow angle. In conclusion, for flammable materials placed in two or more rows in a rack storage, a zigzag arrangement with face sprinklers will be effective.

• Korean Chemical Engineering Research
• /
• v.52 no.6
• /
• pp.755-767
• /
• 2014

Chlorine is one of the most produced and most used non-flammable chemical substances in the world even though its toxicity and high reactivity cause the ozone layer depletion. However, in modern life, it is impossible to live a good life without using Chlorine and its derivatives since they are being used as an typical ingredient in more than 40 percent of the manufactured goods including medicines, detergents, deodorant, fungicides, herbicides, insecticides, and plastic, etc. Even if Chlorine has been handled and distributed in various business (small and medium-sized businesses, water purification plants, distribution company, etc.), there have been few researches about its possible health hazard and transportation risks. Accordingly, the purpose of this paper is to make a detailed assessment of Chlorine-related risks and to model an index of chemicals transportation risks that is adequate for domestic circumstances. The assessment of possible health hazard and transportation risks was made on 13 kinds of hazardous chemicals, including liquid chlorine. This research may be contributed to standardizing the risk assessment of Chlorine and other hazardous chemicals by using an index of transportation risks.