• Title/Summary/Keyword: flammable

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Development and Selection of Accident Scenarios for Risk Assessment in HF Charging Process (HF 충진 공정의 위험성 평가를 위한 가상사고 시나리오 발굴 및 선정)

  • Jang, Chang-Bong
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.26-32
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    • 2013
  • The best way to prevent major occupational accidents is prohibiting use of hazardous substances such as flammable gas, toxic gas whereas using alternative substances that ensured safety. but if there are no economic efficiency and substituting technologies of alternative substances, the best way is preparing to prevent accidents thoroughly. Therefore, this study has developed and selected release scenarios to use and apply for consequence analysis and emergency action plan for HF charging process of chemical plants that have HF release accidents and high probability of release accidents.

A Study on the Risk of Organic Solvents for Underground Area under Construction Site through a Fire Accident Case (화재사고사례를 통해서 본 건설현장 지하공간에서의 유기용제의 위험성에 대한 연구)

  • Ahn, Byung-Joon;Jung, Ki-Hyuk;Lee, Jung-Suk;Rhim, Jong-Kuk
    • Journal of the Korean Institute of Gas
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    • v.22 no.1
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    • pp.9-17
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    • 2018
  • In the consideration of the working conditions, which have several kinds of works operating at the same time, at construction sites, it is difficult to prevent industrial accidents. There are a number of works to employ flammable materials and hot works simultaneously operated without fire protection systems. It causes a huge fire and casualties. In this research to analyze an accident case, the reasonable prevention methods are suggested throughout the property tests for the organic solvents and the analysis of the behavior for vapour cloud in the underground area of the construction site.

Measurement of Lower Flash Point for Ternary Mixture, n-Nonane+n-Decane+n-Dodecane System (삼성분계 혼합물인 n-Nonane+n-Decane+n-Dodecane 계의 하부인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.31-36
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    • 2016
  • The flash point is one of the most important indicators of the flammability of liquid solutions. The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. In this study the flash points of ternary liquid solutions, n-nonane+n-decane+n-dodecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and empirical equation. The calculated data by empirical equation described the measured values more effectively than those calculated by Raoult's law.

A Study on Minimum Ignition Energy by Controlled Discharge Energy (방전에너지 제어에 의한 최소점화에너지의 고찰)

  • Choi, Sang-Won;Ohsawa, Atsushi
    • Journal of the Korean Society of Safety
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    • v.22 no.1 s.79
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    • pp.36-39
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    • 2007
  • It is important to know Minimum Ignition Energy(MIE) of flammable materials for ignition hazard of chemical processes etc.. Currently a capacitor discharge is used mainly to measure the MIE. Then, it is impossible to control actively discharge energies and discharge time because the MIE measurement uses a high voltage capacitor and fixed capacitor. However, the control of discharge energy and discharge time will be convenient if self-sustain discharge is used. In this paper, we measured the MIE by self-sustain discharge of a pulse shape to propose the new measuring method of the MIE. AS a result, ignition energies are increased gradually as discharge duration time gets longer, and discharge current grows larger. Also, an arc discharge and a glow discharge occurred during the experimental period, and the ignition by glow discharges happened when discharge duration time was $90{\mu}s$, discharge current was 8A and 1A Especially, the MIE occurred the 0.05mm and 0.08mm of the gap distance between discharge electrode in the same discharge duration time.

Recommended Evacuation Distance for Offsite Risk Assessment of Ammonia Release Scenarios (냉동, 냉장 시스템에서 NH3 누출 사고 시 장외영향평가를 위한 피해범위 및 대피거리 산정에 관한 연구)

  • Park, Sangwook;Jung, Seungho
    • Journal of the Korean Society of Safety
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    • v.31 no.3
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    • pp.156-161
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    • 2016
  • An accident of an ammonia tank pipeline at a storage plant resulted in one death and three injuries in 2014. Many accidents including toxic gas releases and explosions occur in the freezing and refrigerating systems using ammonia. Especially, the consequence can be substantial due to that the large amount of ammonia is usually being used in the refrigeration systems. In this study, offsite consequence analysis has been investigated when ammonia leaks outdoors from large storages. Both flammable and toxic effects are under consideration to calculate the affected area using simulation programs for consequence analysis. ERPG-2 concentration (150 ppm) has been selected to calculate the evacuation distance out of various release scenarios for their dispersions in day or night. For offsite residential, the impact area by flammability is much smaller than that by toxicity. The methodology consists of two steps as followings; 1. Calculation for discharge rates of accidental release scenarios. 2. Dispersion simulation using the discharge rate for different conditions. This proactive prediction for accidental releases of ammonia would help emergency teams act as quick as they can.

A study of the hazard of fire and explosion due to electric charge by Gas-Solids flow in pipeline

  • Chung Jae Hee;Seo Dae Won;Koo Ja Hyeuk;Kim Sung Jun;An Heau Seak;Kim Joon Ho;Hong Sung Kyung;YAMAGUMA Mizuki;KODAMA Tsutomu
    • Journal of the Korean Institute of Gas
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    • v.4 no.3 s.11
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    • pp.33-38
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    • 2000
  • When fire and explosion accidents have occurred due to a leak of the flammable gas involving the LNG & LPG in an industrialized society, it is a very important problem. Accordingly, in this paper, we have compared and analyzed the occurrence transition and the electrostatic energy according to dust supplies and pressure variations for the electric charge due to the gas-solids of pipe flow. As the experimental results, if dust amounts and the initial pressure increased, electric charge in the pipe and the exit increased. The Specific charge of $Fe_2O_3$ increased proportionally if the initial pressure increased but if the quantity of dust increased, the specific charge decreased. Energy increased significantly as the dust amounts and the initial pressure increased. The possibility of fire and explosion exist in the measuring point(M 1) and the Faraday cage if natural gas and LPG were used.

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Effect of Noble Metals on Hydrogen Sensing Properties of Metal Oxide-based Gas Sensors

  • Mirzaei, Ali;Bang, Jae Hoon;Kim, Sang Sub;Kim, Hyoun Woo
    • Journal of Sensor Science and Technology
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    • v.29 no.6
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    • pp.365-368
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    • 2020
  • As a green and abundant source of energy, H2 has attracted the attention of researchers for use in different applications. Nevertheless, it is highly flammable, and because of its significantly small size, extreme attention is needed to detect its leakage. In this review, we discuss different effects of noble metals on the H2 gas response and performance of metal oxide-based gas sensors. In this regard, we discuss the effects of noble metals, in combination with metal oxides, on H2 gas detection. The catalytic activity towards H2 gas and the formation of heterojunctions with metal oxides are the main contributions of noble metals to the sensing improvement of H2 gas sensors. Furthermore, in the special case of Pd and somewhat Pt, the formation of PdHx and PtHx also affects the H2 sensing performance. This review paper provides useful information for researchers working in the field of H2 gas detection.

Combustion Characteristics of the SOFC Products for SOFC/Gas Turbine Hybrid Power Generation System (SOFC/가스터빈 혼합발전을 위한 SOFC 생성물의 연소특성)

  • Lee, Byeong Jun;Bae, Chul Han
    • Journal of the Korean Society of Combustion
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    • v.19 no.3
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    • pp.44-52
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    • 2014
  • Solid oxide fuel cell(SOFC) makes electric power using hydrogen or reformed from methane and emits high temperature products that contain flammable species like hydrogen, carbon monoxide and methane which varies with operation condition. SOFC/gas turbine integrated system which uses thermal and chemical energy of the discharges is more efficient than SOFC itself. Burning character of the SOFC products will affect the efficiency and stability of the system. Experiments were conducted to know the characteristics of the flame for two typical composition of SOFC products, i.e. start-up and steady state composition. When coflowing air temperature was higher than $600^{\circ}C$, auto-ignitin occurred for both fuels. Though start-up fuel has higher contents of hydrogen, it makes longer flame than steady state composition. It was inferred that the amount of oxidizer necessary to burn makes this phenomenon. Steady state composition fuel was unstable since it contains lots of water. Nozzle that had 6 holes, distance between each hole was 16.7 times of hole diameter, improved the stability of the flame.

Prediction of Explosion Limits of Aldehydes Using Chemical Stoichiometric Coefficients and Heats of Combustion (연소열 및 화학양론계수를 이용한 알데히드류의 폭발한계의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.19 no.2
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    • pp.5-11
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    • 2015
  • The explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. The explosion limit of aldehydes have been shown to be correlated the heat of combustion and the chemical stoichiometric coefficients. In this study, the lower explosion and upper explosion limits of aldehydes were predicted by using the heat of combustion and chemical stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data above determination coefficient 0.99. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the aldehydes.

Prediction of Lower Explosion Limits of Binary Liquid Mixtures by Means of Solution Thermodynamics (용액열역학에 의한 2성분계 혼합물의 폭발하한계 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Journal of the Korean Institute of Gas
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    • v.13 no.5
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    • pp.20-25
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    • 2009
  • Low explosion limits of flammable liquid mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this paper, Raoult's law, van Laar equation and Wilson equation are shown to be applicable for the prediction of the lower explosion limits for ethylacetate+ethanol and ethanol+toluene systems. The calculated values based on Raoult's law were found to be better than those based on van Laar and Wilson equations.

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