• 한국가스학회지
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• 제22권6호
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• pp.52-58
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• 2018

신뢰도 기반 접근법(RBDA)에서, 신뢰도 목표는 설계 및 유지관리 단계에서 관계되는 한계상태를 충족할 수 있는 정도의 안전 수준을 가지는 지 확인하기 위해서 사용된다. 우리나라의 경우 가연성 가스 배관에 대한 신뢰도 목표는 아직 개발되거나 활용되지 못하고 있다. 다만 신뢰도 목표 대신에 사회적 위험과 개인적 위험과 같은 위험 측정지표에 대한 허용가능(tolerable) 판단기준이 배관의 위험관리에 적용되어 왔다. 본 논문에서는 고압천연가스 배관에 대한 정량적 위험평가 시 판단기준으로 삼는 사회적, 개인적 위험 판단기준을 사용하여 신뢰도 기반 접근법의 핵심요소인 목표 신뢰도를 개발하는 절차를 소개하고 자 한다. 또한 소개된 절차를 통해 천연가스와 수소가스 수송배관에 대한 신뢰도 목표를 제안한다.

• 대한안전경영과학회지
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• 제26권1호
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• pp.99-106
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• 2024

In the event of an emergency such as facility shutdown during process operation, the by-product gas must be urgently discharged to the vent stack to prevent leakage, fire, and explosion. At this time, the explosion drop value of the released by-product gas is calculated using ISO 10156 formula, which is 27.7 vol%. Therefore, it does not correspond to flammable gas because it is less than 13% of the explosion drop value, which is the standard for flammable gas defined by the Occupational Safety and Health Act, and since the explosion drop value is high, it can be seen that the risk of fire explosion is low even if it is discharged urgently with the vent stock. As a result of calculating the range of explosion hazard sites for hydrogen gas discharged to the Bent Stack according to KS C IEC 60079-10-1, 23 meters were calculated. Since hydrogen is lighter than air, electromechanical devices should not be installed within 23 meters of the upper portion of the Bent Stack, and if it is not possible, an explosion-proof electromechanical device suitable for type 1 of dangerous place should be installed. In addition, the height of the stack should be at least 5 meters so that the diffusion of by-product gas is facilitated in case of emergency discharge, and it should be installed so that there are no obstacles around it.

• 한국재난정보학회 논문집
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• 제18권1호
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• pp.182-193
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• 2022

연구목적: 바이오디젤의 위험성을 ASTM 시험규격에 의해 특정한 온도에서 열잔분측정과 발화점 및 폭발한계 측정을 통해 측정 평가함으로써 화학화재의 원인물질의 위험성을 확인하고, 보편적인 평가방법 도출 그리고 그에 따른 물질의 위험성 관련 데이터를 확보함으로써 화재원인 감식과 감정에 활용할 수 있을 것이고, 다른 화학물질에 위험성평가에 적용할 수 있을 것이다. 연구방법: 바이오디젤의 위험성을 측정하기 위해서 특정한 온도에서 얼마나 많은 가연성 액체를 발생하는가를 측정하는 가열잔분 측정법을 사용해서 측정해 보았다. 가열은 KS M 5000 : 2009 시험방법 4111을 적용해서 실험을 해보았다. 또한 발화점 측정은 ASTM E659-782005서 규정하는 방법으로, 에너지 공급방식은 정온법을 이용하여 측정하였다. 아울러 폭발한계 측정은 ASTM E 681-04 「Standard test method for concentration limits of flammability of chemicals(Vapors and gases)」 시험규격에 의해 실험을 진행하였다. 연구결과: 가열잔분법으로 가연성액체량의 확인결과 105±2℃에서 3시간 방치했을 때의 일반디젤의 가열잔분은 약 30%정도(휘발분 70%), 바이오디젤의 경우 약 4%정도로 측정되었다. 또한 가열온도 150±2℃, 3시간과 200±2℃ 1시간의 가열잔분의 값은 유사한 결과를 얻었고, 200℃이상에서는 흰색연기를 발생시켰다. 아울러 일반디젤, 20%의 바이오디젤 함유된 일반디젤, 그리고 100% 바이오디젤의 폭발(연소)한계를 실험적으로 확인해 본 결과 유사한 값을 얻었다. 따라서 인화위험성이 폭발위험성에 영향을 크게 미치지 못하는 경향을 확인하였다. 결론: 본 연구에서의 결과는 기존의 위험물안전관리법에서의 위험물 판정 기준에 대한 세부 내용의 실효성 및 신뢰성 그리고 재현성 확보를 목적으로 인화성 혼합물에 대한 실험적 연구를 통해서 혼합물에 대한 위험성 판단 기준을 제시하였고, 향후 소방현장에서 단속되는 인화성 액체 대한 판정 기준에 대한 참고적인 자료를 제공할 수 있을 것이다. 또한 본 연구로 시험방법별 실험에 대한 노하우를 축적한다면 위험물의 위험성 평가 연구에 있어 기초 자료이자 위험물 판정 관한 연구의 기반으로 활용될 수 있기를 기대한다.

• International Journal of Automotive Technology
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• 제4권1호
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• pp.1-8
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• 2003

Wastes such as shredder dust of disposed vehicles can be decomposed into low calorific flammable gases by Pyrolysis gasification. A stationary electric Power generation using an internal combustion engine fuelled with the waste-pyrolysis gas is an effective way to ease both waste management and energy saving issues. The waste-pyrolysis gas mainly consists of H$_2$, CO, $CO_2$ and $N_2$. The composition and heating value of the gas generated depend on the conversion process and the property of the initial waste. This research analyzed the characteristics of the combustion and the exhaust emissions in a premixed charge spark ignition engine fuelled with several kinds of model gases, which were selected to simulate the pyrolysis-gases of automobile shredder dusts. The influences of the heating value and composition of the fuel were analyzed parametrically. Furthermore, optical analyses of the combustion flame were made to study the influence of the fuel's inert gas on the flame propagation.

• 한국안전학회지
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• 제22권4호
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• pp.37-42
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• 2007

Flash points for the flammable binary systems, n-propanol+acetic acid and n-propanol+n-propionic acid, were measured by Cleveland open cup tester. The Raoult's law, the van Laar equation and the UNIQUAC equation were used for predicting flash points and were compared with experimentally-derived data. The calculated values based on the van Laar and UNIQUAC equations were found to be better than those based on the Raoult's law. And the predictive curve of the flash point prediction model based on the UNIQUAC equation described the experimentally-derived data more effectively than was the case when the prediction model was based upon the the van Laar equation.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2008년도 추계학술논문발표회 논문집
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• pp.262-269
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• 2008

Chemical products have had an favorable influence on our everyday life, and contributed very much to the development of human culture. According to the rapid change of industry and the development of scientific technique the using chemical products are increasing more and more. Chemical products can have any hazardous property such as flammability or explosiveness. There are occurring many accidents in the international trade due to the different classification and labelling of chemicals produced in various countries. The main purpose of this work is the development of global standard test methods for the chemicals, and the classification and labelling in building block approach by means of the basic technical data. Oxidizing solids, combustible solids, spontaneously combustible materials, water-prohibitive materials, flammable liquids, self-reactive materials and oxidizing liquids have been tested. The results have been classified according to the hazard material safety regulation and the UN regulation, and summarized in a data-base.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2354-2359
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• 2007

Influence of changing combustor pressure on flame stabilization and emission index in the swirl-stabilized flame was investigated. The combustor pressure was controlled by suction fan at combustor exit. Pressure index ($P^{\ast}$=Pabs/Patm), where Pabs and Patm indicated the absolute pressure and atmosphere pressure, respectively, was controlled in the range of 0.7${\sim}$1.3 for each equivalence ratio conditions. The flammable limits of swirl flames were largely influenced by changing combustor pressure and they showed similar tendency with laminar flames. NOx emission index decreased with decreasing pressure index for overall equivalence ratio conditions. R.m.s. of pressure fluctuations is increased with decreasing combustor pressure. This flame fluctuation caused incomplete combustion, hence CO emission index increased. These oscillating flames were measured by simultaneous $CH^{\ast}$ chemiluminescence time-series visualization and pressure fluctuation measurement.

• 한국화재소방학회논문지
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• 제22권3호
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• pp.246-251
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• 2008

일반적으로 유류화재의 경우 상온 상압 하에서 그 물리적 성질과 에너지 특성이 유사한 양상을 나타내나 식용유에 의한 화재발생은 그 특성이 매우 특이하여 취급자의 무지로 인한 화재가 자주 발생하고 있다. 따라서 본 연구에서는 식용유에 대한 에너지 특성과 그 물적 성질을 고찰한 연후 실제 연소실험을 통하여 식용유에 대한 물리적 성질을 검증하였다. 뿐만 아니라 실제 화재사례를 통하여 식용유에 의한 화재원인을 감식하였고 식용유화재 방지를 위한 대응방안을 고찰하여 제시 하였다.

• 한국전산유체공학회지
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• 제15권2호
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• pp.47-54
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• 2010

In the present study, a numerical simulation for the diffusion of hydrogen leakage of FCV(Fuel Cell Vehicle) in a tunnel was performed to aid the assessment of risk in case of leakage accident. The temporal and spatial distributions of the hydrogen concentration around FCV are predicted from the present numerical analyses. Flammable region of 4-74% and explosive region of 18-59% hydrogen by volume was identified from the present results. Factors influencing the diffusion of the hydrogen jet were examined to evaluate the effectiveness of tunnel ventilation system for relieving the accumulation of the leaked hydrogen gas. The distribution of the concentration of the leaked hydrogen for various cases can be used as a database in various applications for the hydrogen safety.

• 한국안전학회지
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• 제28권2호
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• pp.49-54
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• 2013

The autoignition temperature(AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-Decane and Acetic acid system by using ASTM E659 apparatus. The AITs of n-Decane and Acetic acid which constituted binary system were $212^{\circ}C$ and $512^{\circ}C$, respectively. The experimental AITs of n-Decane and Acetic acid system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation). And n-Decane and Acetic acid system was shown the minimum autoignition temperature behavior(MAITB).