• 제목/요약/키워드: flammability

검색결과 247건 처리시간 0.025초

재활용(再活用) 폴리프로필렌과 무기계(無機界) 폐기물(廢棄物)을 이용(利用)한 난연성(難燃性) 소재(素材) 개발(開發) (Development of flame retardant materials utilizing recycled polypropylene and inorganic waste)

  • 전병철;조태근;박현규;최형준;정용찬;전호석
    • 자원리싸이클링
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    • 제16권4호
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    • pp.17-26
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    • 2007
  • 재활용한 폴리프로필렌(재활용 COPP, 이하 COPP)에 무기계 폐기물인 패각을 도입하여 함량 변화에 따른 기계적 물성 및 난연성을 조사하였다. 상기 복합소재의 기계적 물성 향상을 위하여 상용화제(Polytail H)를 첨가하였고, 난연성 향상을 위하여 다양한 종류의 난연제($Al_2O_3$, DBDPO, $Sb_2O_3$)를 첨가하여 이에 따른 기계적 물성 및 난연성을 종합적으로 평가하였다. 측정 결과 재활용 COPP에 패각만 혼합하는 것보다는 추가적으로 상용화제를 혼합하는 것이 매트릭스인 폴리프로필렌과 패각과의 계면 결합력이 증대되어 패각만을 혼합하였을 때 보다 물성저하가 감소하였고, 충격강도의 경우는 100 wt% 재활용 폴리프로필렌(COPP)과 유사한 값을 나타내었다. 한편, 난연제 첨가에 따른 기계적 물성의 저하는 관찰되지 않았다. 제조된 재활용 COPP 복합소재의 UL-94규격에 의한 난연 테스트 결과 패각만을 혼합한 경우 패각 40 wt% 함유된 경우가 pure COPP보다 불이 붙을 때까지 걸리는 시간과 타는 시간이 지연됨을 확인할 수 있었지만, 난연 효과는 나타나지 않았다. 그러나, 패각을 난연제와 함께 복합화하여 제조한 소재에서는 뚜렷한 난연 효과를 관찰할 수 있었으며, 난연 효과는 $Sb_2O_3>Al_2O_3>DBDPO$의 순으로 효과가 있음을 확인하였다. UL-94 V-0 등급은 $Al_2O_3$를 첨가한 그레이드 중 상용화제를 넣은 그레이드와 패각 40 wt%가 함유된 그레이드에서, 그리고 $Sb_2O_3$를 난연제로 사용한 모든 그레이드에서 관찰되었다.

3성분계 유기용제의 인화특성에 관한 연구 (A Study on the Characteristics of Flammability for Organic Solvents of Three Component Systems)

  • 임우섭;목연수;최재욱;최일곤;하동명;조태제
    • 한국안전학회지
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    • 제14권3호
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    • pp.120-126
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    • 1999
  • This study was accomplished by measuring the lower and upper flash point with air blowing method and grasping the characteristics of flammability for the three component systems, which are made up of the Benzene-Toluene-o-Xylene and Methylethylketone-Toluene-o-Xylene. These three component systems are widely used in the various industrial fields together with the development of industry. The results are as follows ; 1 ) Isothermal line is plotted on the triangular diagram for flash points determined in each solutions. From this line, the mixed compositions which indicated the same lower and upper flash points in each different composition could be read on this diagram, if the composition of mixtures are known. 2) Lower and upper explosion limits obtained from the flash points determined for the three component solution are compared with the value calculated from Le Chatelier's law. Especially the lower explosion limits are in a good agreement with the calculated values.

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음향가진과 보염기형상이 확산화염의 특성에 미치는 영향 (Effect of Acoustical Excitation and Flame Stabilizer on a Diffusion Flame Characteristics)

  • 전충환;장영준
    • 한국연소학회지
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    • 제3권1호
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    • pp.1-10
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    • 1998
  • Lots of techniques are adopted for a flame stabilization and a high-load combustion. But the techniques being used were passive control method which have to change combustor shape like pilot flame, flame stabilizer, pressure profile, etc. Active control method which is not necessary to transform its shape is employed. Acoustical excitation is broadly used for its convenience in changing frequency and intensity. Both acoustical excitation and flame stabilizers were adopted to study their relationship. So, we investigated flammability limits. Flame visualization. And mean temperature in the condition of various frequencies, intensities, and flame stabilizers. As a consequence, flammability limit were advanced in acoustically excited flame at some frequencies. Coherent structure was extended to the downstream region through acoustical excitation and a size of vortice was curtailed. Also width of recirculation zone was magnified. In addition, Effects of acoustical excitation was stood out at 25mm flame stabilizer rather than another ones.

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인계화합물을 포함한 재활용 폴리우레탄폼의 난연성 (Fire Retardancy of Recycled Polyurethane Foam Containing Phosphorus Compounds)

  • 정영진
    • 한국응용과학기술학회지
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    • 제24권2호
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    • pp.182-189
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    • 2007
  • Used polyurethane was chemically degraded by treatments with flame retardants such as tris(3-chloropropyl) phosphate (TCPP), triethyl phosphate (TEP), and trimethyl phosphate (TMP). The structure of degraded products (DEP) was analyzed by FT-IR and P-NMR and it turned out to be phosphorus containing oligourethanes. Rigid polyurethane foam was produced by using the degraded products (DEP) as flame retardants. The flammability of recycled rigid polyurethane was investigated. The recycled polyurethane shows a reduced flammability over virgin polyurethane. In order to evaluate flame retardant properties of the recycled polyurethane foams with various amounts of DEP, the combustion parameters of the foam was measured by a cone calorimeter. Scanning electron micrograph of recycled PU shows the same uniform cell morphology as virgin PU.

LPG 가연성 혼합물에 대한 고형 금지제의 억제 효과 (Inhibitory Effect of Solid Inhibitors on LPG Combustible Mixtures)

  • Hamdan, M. A.;Yamin, J. A.;Dabbas, R. K.
    • 대한화학회지
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    • 제54권3호
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    • pp.295-299
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    • 2010
  • 액화석유가스-공기 불꽃에 대한 2가지 열적 금지제(즉, 돌가루, 탄산칼슘)의 억제효과를 연구하였다. 이를 위해 이들 금지제를 가하기 전과 후 가연성 혼합물의 가연성 한도를 측정하여 조사하였다. 그 결과, 탄산칼슘이 돌가루에 비해 억제 효과가 우수하였다.

고온시에서의 폴리머 시멘트 모르타르의 연소특성에 관한 연구 (Burn-up Characteristics of Polymer-Modified Cement Mortar Used for Building Repair)

  • 김형준;노구치 타카후미
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2012년도 춘계 학술논문 발표대회
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    • pp.295-298
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    • 2012
  • Repair and strengthening is necessary to extend the service life of existing buildings. Polymer-modified cement mortar (PCM) has been extensively used as a high performance material particularly for finishing and repairing works in concrete building because of itsexcellent adhesion, waterproofing, resistance to chemical attack, and workability. As PCM contains organic polymer, it is necessary to clarify its properties at high temperature under fire, on which sufficient data are not available. This paper evaluated the burn-up characteristics of polymer-modified cement mortar with cone calorimeter test, non-combustibility test and flammability test with experimental parameters such as the types of polymer, unit-polymer content, polymer-cement ratio and thickness of the specimen.

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유증기 연소처리를 위한 난류 부분예혼합화염의 활용 및 유동장 가시화 (Utilization and Visualization of Turbulent Partially-premixed Flame for Combustion of Inert-gas-diluted VOC)

  • 안태국;남연우;박선호
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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    • pp.193-196
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    • 2015
  • Combustion of low concentration VOC in inert gas around the flammability limit has been experimentally studied. Streams of nitrogen and propane mixture with various compositions and flow conditions were treated by a turbulent partially-premixed pilot flame. HC and CO contents in exhaust gas measured and the flow patterns were visualized. The results suggested that there exists an optimal mixture velocity range for efficient combustion treatment for each flow condition and composition of the mixture.

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교류 전기장 인가에 따른 프로판 예혼합 화염의 유동 특성 (Flow Characteristics of Propane Premixed Flame on AC Electric Field)

  • 김보윤;김민석;김태훈;권일송;김혜민
    • 한국분무공학회지
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    • 제29권1호
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    • pp.38-44
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    • 2024
  • This study investigates the flow characteristics of propane-air premixed flames on AC electric field using the Schlieren method. A voltage was applied to the ring electrode and the burner was grounded to form an electric field, and the applied voltage was fixed at 16 kV (Vpp). Results show that under the application of AC electric fields, flow around the flame oscillated only at frequencies below 50 Hz, and no oscillation was observed above this frequency range. Flame height oscillated with frequency in the range of 25 to 300 Hz, with frequency doubling observed in the range of 25 to 150 Hz. The flammability limit increased with frequency up to 250 Hz, but in the high-frequency range above 250 Hz, the flammability limit did not increased and converged.