• Journal of the Korean Chemical Society
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• v.55 no.1
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• pp.92-97
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• 2011

The effect of Group I alkali acetate promoters on vinyl acetate (VA) synthesis was evaluated. Catalyst product selectivity and ethylene conversion are compared to the unpromoted catalyst in the fixed-bed reactor with oxidation reaction of ethylene and acetic acid in gaseous phase over Pd-Au/$SiO_2$ catalyst. It was found that: a) the promoters were stabilized on the catalyst surface, b) common effect for the alkali promoted Pd-Au catalysts increaseed in product selectivity and ethylene conversion compared to unpromoted catalyst (these effects increase from top to the bottom of Group I). These promoting effect is due to the common-ion effect of acetate, present in the reaction, resulting in an increase in the activity of the catalyst. In addition a complementary theory for the effect of Au in the structure of the catalyst is proposed the imposition of distribution of palladium particles through decreasing the particle's diameter.

• Aerospace Engineering and Technology
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• v.12 no.1
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• pp.87-93
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• 2013

The conceptual design lunar lander demonstrator has been developed to use as a test bed for advanced spacecraft technologies and to test a prototype planetary lander capable of vertical takeoff and landing. Size of the lunar lander demonstrator is the same as that of lunar lander conceptually designed, however, the weight of lunar lander demonstrator is designed in 1/6 scale in consideration of gravity difference between moon and earth. The thruster clustering and virtual flight test were performed in the demonstrator fixed on the ground. The demonstrator ground test has been conducted for two months in the test site for the solid motor combustion of the Goheung Flight Center. The purposes of ground test of demonstrator are to demonstrate and verify essential electronics, propulsion system, control algorithm, embedded software, structure and system operation technologies before developing the flight model lander. This paper is described about the virtual flight test including test configuration, test aims and test facilities

• Journal of Hydrogen and New Energy
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• v.23 no.5
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• pp.559-571
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• 2012

Dimethyl ether (DME) is a new clean fuel as an environmentally-benign energy resource. DME can be manufactured from various energy sources including natural gas, coal, and biomass. In addition to its environmentally friendly properties, DME has similar characteristics to those of LPG. The aim of this article is to represent the development of new DME process with KOGAS's own technologies. KOGAS has investigated and developed new innovative DME synthesis process from synthesis gas in gaseous phase fixed bed reactor. DME has been traditionally produced by the dehydration of methanol which is produced from syngas, a product of natural gas reforming. This traditional process is thus called the two-step method of preparing DME. However, DME can also be manufactured directly from syngas (single-step). The single-step method needs only one reactor for the synthesis of DME, instead of two for the two-step process. It can also alleviate the thermodynamic limitations associated with the synthesis of methanol, by converting the produced methanol into DME, thereby potentially enhancing the overall conversion of syngas into DME. KOGAS had launched the 10 ton/day DME demonstration plant project in 2004 at Incheon KOGAS LNG terminal. In the mid of 2008, KOGAS had finished the construction of this plant and has successively finished the demonstration plant operation. And since 2008, we have established the basic design of commercial plant which can produce 3,000 ton/day DME.

• Korean Chemical Engineering Research
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• v.45 no.3
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• pp.277-285
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• 2007

The adsorption characteristics of multi-component solvent vapors including poorly-adsorbable chemicals such as toluene-xylene-MEK and toluene-MEK-IPA on the activated carbonaceous adsorbents were investigated in a stainless steel fixed bed of 10.2 cm ID and 50 cm in height in order to identify those carbons for eliminating and recovering solvent vapors from industrial emission sources. The used activated carbonaceous adsorbents were pelletized commercial activated carbons and activated carbon fiber. Breakthrough curves and adsorption capacity at atmospheric pressures were obtained. It has been found that non-polar and larger molecules have been adsorbed better than polar and smaller molecules. In special, alcohols and ketones were poorly adsorbed caused by competitive adsorbability in multi-component mixture system. However, it could be overcome by profitable employment of organization of cooperative system which was composed of different porosity activated carbonaceous adsorbents appropriately.

• Journal of Korean Orthopaedic Sports Medicine
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• v.1 no.1
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• pp.61-64
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• 2002

The authors report one case of isolated avulsion fracture of the tibial attachment of the posterior cruciate ligament. A 13 years old boy was admitted for right knee pain and swelling after the soccer injury on his knee. Hemarthrosis and posterior instability were present. Simple roentgenographic examination showed an isolated avulsion fracture of the tibial attachment of the posterior cruciate ligament. Open approach through the popliteal fossa was used and bony fragment was fixed into its bed using pull-out sutures. Postoperatively, a long leg cast was applied for 4 weeks. The patient was followed for 6 months. He returned to his previous activity levels. There was no residual laxity. Isolated avulsion of the posterior cruciate ligament from the tibia before the epiphyseal fusion is very rare in children. We reported one case of our experience and its result.

• KSBB Journal
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• v.8 no.3
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• pp.256-265
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• 1993

In this study, it was observed that hydrogen productivity varied with changes of input g1ucose concentration and dilution rate in FBR( Fixed Bed Reactor), and CSTR(Continuous Stirred Tank Reactor). We evaluated and compared reaction rate Parameters and internal external and overall mass transfer resistances of immobilized carrier in both reactors. Apparent $K_m$ decreased with increasing dilution rate in FBR but showed a constant value above $0.4h^{-1}$ of dilution rate in CSTR. The experimental results in FBR showed nearly analogous to those in CSTR, however, the performance of FBR resulted in lower hydrogen productivity and an external effectiveness factor but a higher internal effectiveness factor than in CSTR. The overall effectiveness factor obtained with various input 91ucose concentrations showed similar values in both reactors.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.624-628
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• 1998

The aromatic organic solvents(BTX) were decomposed in the fixed bed reactor packed with a 0.5% $Pt/{\gamma}-Al_2O_3$ catalyst, then, supercritical carbon dioxide(SC-$CO_2$) was used as the reaction media. And the conversion was dependent on the inlet concentration of BTX and the molar density of SC-$CO_2$. The conversion of BTX was decreased with increasing of inlet concentration, and was increased with temperature and pressure. The maximum conversion of benzene was 98.5% at $300^{\circ}C$ and 204.1 atm, and that of toluene and xylene were 82.0 and 76.5%, respectively, at $350^{\circ}C$ and 204.1 atm. The intermediate products of partial oxidation were identified as benzaldehyde, phenol, benzenemethanol, and so on. The BTX can be effectively converted into harmless $CO_2$ and $H_2O$ at appropriate operating condition. Thus, the nontoxic recovery process was suggested as the removal method of BTX.

• Journal of the Korean Applied Science and Technology
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• v.34 no.4
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• pp.892-898
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• 2017

In this study, the basic properties of recoverable gaseous and solid materials were investigated from heavy oil contained in the resources. The basic characteristics of pyrolysis reaction for the conversion of bituminous oil to pyrolysis various temperature were investigated. The characteristics of gas and solid phase byproducts were also investigated with a laboratory scale fixed bed reactor according to various reaction temperature. As a result, it was confirmed that the oil yield was about 17% at $550^{\circ}C$ and $CH_4$, $CaCO_3$ and CaO could be recovered as by-products.

• Journal of Environmental Science International
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• v.15 no.1
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• pp.21-31
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• 2006

Aquatic plants grow in water with photosynthesis and purify water quality as taking organic and inorganic matter in water. Polluted water in stagnant stream channel where nutritive salts load is great can be purified by activities of aquatic plants. Aquatic plants should be fixed to bed easily to plant and sustainable environment is needed. So in this study, Mattress/Filter system is suggested to plant aquatic plant in stagnant stream channel. In the result of study, coverage of Phragmites australis, Zizania latifolia and Typha angustifolia which planted in mattress was $78\%,\;62\%\;and\;82\%$ and numbers of species in each mattress system were 7, 11, 3. The evenness index of each mattress system was 0.86, 0.91 and 0.79 and diversity index of each mattress system was 1.67. 2.18 and 0.87. Removal rates of phosphorus at Phragmites australis, Zizania latifolia and Typha angustifolia which planted in mattress were $68.7\%,\;62.7\%,\;55.3\%$ and removal rates of nitrogen of them were $79.8\%,\;74.7\%,\;64.9\%$. The removal rate of nitrogen was greater than phosphorus at all system and both removal rates were greater at Phragmites australis than at Zirania latifolia and at Typha angustifolia the rate was the least. Removal rates of $PO_4^{-3},\;NH_4-N,\;NO_{3-}N$ at Phragmites australis were $57.4\%,\;52.8\%,\;47.8\%$ and at Zizania latifolia were $82.6\%,\;77.2\%,\;67.5\%$ and at Typha angustifolia were $80.6\%,\;73.7\%,\;64.3\%$. It seems that removal effect is great by the planted mattress system.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2384-2393
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• 2018

Porous alginate-based hydrogel beads (porous ABH) have been prepared through a facile and sustainable template-assisted method using nano-calcium carbonate and nano-$CaCO_3$ as pore-directing agent for the efficient capture of methylene blue (MB). The materials were characterized by various techniques. The sorption capacities of ABH towards MB were compared with pure sodium alginate (ABH-1:0) in batch and fixed-bed column adsorption studies. The obtained adsorbent (ABH-1:3) has a higher BET surface area and a smaller average pore diameter. The maximum adsorption capacity of ABH-1:3 obtained from Langmuir model was as high as $1,426.0mg\;g^{-1}$. The kinetics strictly followed pseudo-second order rate equation and the adsorption reaction was effectively facilitated, approximately 50 minutes to achieve adsorption equilibrium, which was significantly shorter than that of ABH-1:0. The thermodynamic parameters revealed that the adsorption was spontaneous and exothermic. Thomas model fitted well with the breakthrough curves and could describe the dynamic behavior of the column. More significantly, the uptake capacity of ABH-1:3 was still higher than 75% of the maximum adsorption capacity even after ten cycles, indicating that this novel adsorbent can be a promising adsorptive material for removal of MB from aqueous solution under batch and continuous systems.