• 제목/요약/키워드: fine particle components

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The Metallic Composition of PM2.5 and PM10 in a Northeast Region of Seoul During the Spring 2001 (2001년 봄철 서울시 북동부지점에서 관측한 중금속성분의 농도분포)

  • Choi, Gyoo-Hoon;Kang, Chang-Hee;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • 제23권6호
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    • pp.514-525
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    • 2002
  • The analysis of heavy metals associated with both PM2.5 and PM10 fraction of aerosols was made from a northeast region of Seoul during the spring period of 2001. The mean concentrations of fine (PM2.5), coarse (PM10-PM2.5), and PM10 fraction were observed as 49.3${\pm}$29.2, 50.5${\pm}$35.0, and 95.5${\pm}$46.1 ${\mu}g$/m$^3$, respectively during this study period. According to the results of enrichment factor (EF) analysis between different particle fractions, major elements (including Fe, Ca, Na, and K) were found to exhibit EF values of less than 10. However, heavy metal components (like Zn and Pb) showed very high EF values. Comparison of fine/coarse (F/C) concentration ratio showed that Zn, Cr, Pb, and Ni have higher ratio values than others. The metallic composition of particles was also compared on both absolute and relative terms. The results of our analysis showed an evidence that the increase in the total metallic contents is prominent during the spring period due mostly to the Asian Dust event.

Development of reference materials for mortar: Determination of the components and relation with mixing ratio

  • Lim, Dong Kyu;Choi, Myoung Sung
    • Advances in concrete construction
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    • 제10권5호
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    • pp.381-391
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    • 2020
  • This study aimed to develop reference materials (RMs) for mortar that can simulate the initial flow characteristics with constant quality over a long period. Through the previous research on the development of RMs for cement paste, the combination of limestone, glycerol, and water was used as the basic matrix for developing RMs for mortar in this study. In addition, glass beads of three particle sizes (0.5, 1.0, and 2.0 mm) and ISO standard sand were selected as tentative candidates to derive fine aggregate substitutes. The mixture of glass beads could simulate the initial flow characteristics of mortar, but under the same mixing ratio, replicates showed an unstable tendency to indicate inconsistent values due to the generation of electrostatic properties between materials and equipment. On the other hand, the mixture using ISO standard Sand not only simulates the constant flow characteristics for a long period of time, but also shows stable results with little error in replicates. Therefore, limestone, glycerol, ISO standard sand, and water were finally determined as components that met the required properties of RMs for mortar. The effect of each component on the flow characteristics of RMs was analyzed. It was found that glycerol increased the cohesion between the particles of standard sand, resulting in a constant increase both in the plastic viscosity and yield stress. Both limestone and standard sand had a dominant effect on the yield stress. The relationships between various mortar mixing ratios and the corresponding mixing ratios of RMs were established. In addition, the results of the verification experiment showed that the rheological properties of the RMs obtained through the relationships correlated with various water/cement ratios and the fine aggregate volume fractions of mortar obtained with same manner. In other words, the RMs for mortar developed in this study can be used as standard samples because they can simulate the initial flow characteristics of mortar of various mixing ratios for a long period without any chemical changes.

Engineering Characteristics of Ultra High Strength Concrete with 100 MPa depending on Fine Aggregate Kinds and Mixing Methods (잔골재 종류 및 혼합방법 변화에 따른 100 MPa 급 초고강도 콘크리트의 공학적 특성)

  • Han, Min-Cheol;Lee, Hong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • 제17권2호
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    • pp.536-544
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    • 2016
  • Recently, with the increase in the number of high rise and huge scaled buildings, ultra-high strength concrete with 80~100 MPa has been used increasingly to withstand excessive loads. Among the components of concrete, the effects of the kinds and properties of fine aggregates on the performance and economic advantages of ultra-high strength concrete need to be evaluated carefully. Therefore, this study examined the effects of the type of fine aggregates and mixing methods on the engineering properties of ultra-high strength concrete by varying the fine aggregates including limestone fine aggregate (LFA), electrical arc slag fine aggregate (EFA), washed sea sand (SFA), and granite fine aggregate (GFA) and their mixtures. Ultra-high strength concrete was fabricated with a 20 % water to binder ratio (W/B) and incorporated with 70 % of Ordinary Portland cement: 20 % of fly ash:10 % silica fume. The test results indicate that for a given superplasticizer dose, the use of LFA resulted in increases in slump flow and L-flow compared to the mixtures using other aggregates due to the improved particle shape and grading of LFA. In addition, the use of LFA and EFA led to enhanced compressive strength and a decrease in autogenous shrinkage due to the improved elastic properties of LFA and the presence of free-CaO in EFA, which resulted in the formation of C-S-H.

A Study on the Flow Characteristics of Supersonic Microjets (초음속 마이크로제트 유동특성에 관한 연구)

  • Shin, Choon-Sik;Kim, Heuy-Dong;Setoguchi, Toshiaki
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.492-495
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    • 2009
  • Supersonic microjets acquire considerable research interest from a fundamental fluid dynamics perspective, in part because the combination of highly compressible flow at low-to-moderate Reynolds number is not very common, and in part due to the complex nature of the flow itself. In addition, microjets have a great variety engineering applications such as micro-propulsion, MEMS (Micro-Electro Mechanical Systems) components, microjet actuators and fine particle deposition and removal. Numerical simulations have been carried out at moderate nozzle pressure ratios and for different nozzle exit diameters to investigate and to understand in-depth of aerodynamic characteristics of supersonic microjets.

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Strength Properties of Mortar Containg Metakaolin (메타카올린을 혼합한 모르타르의 강도특성)

  • Moon, Dae-Joong;Ju, Jae-Eok;Jo, Jeong-Hyun;Kang, Hyun-Jin;Choi, Yun-Wang
    • Proceedings of the Korea Concrete Institute Conference
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.639-642
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    • 2005
  • Main components of metakaolin(MK) were $SiO_2\;and\;Al_2O_3$. and specific surface was 2.2 times larger than that of ordinary portland cement(OPC). MK indicated the fine particle and fiber texture. Flow value of mortar with MK was decreased linearly each $13\%$ as the replacement ratio of MK was increased each $5\%$. Compressive strength of mortar with MK was increased more than that of mortar with OPC by 3days. Compressive strength of mortar with $10\%$ MK was about 83MPa at 28 days. When MK was replaced with $10\%$ of cement volume, flexural strength and modulus of elasticity of mortar was indicated the maximum value at 28 days.

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Numerical Visualization of Supersonic Microjet Flows (초음속 마이크로제트 유동의 수치해석적 가시화)

  • Shin, Choon-Sik;Lee, Jong-Sung;Kim, Heuy-Dong
    • Journal of the Korean Society of Visualization
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    • 제7권2호
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    • pp.35-41
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    • 2010
  • Supersonic microjets acquire considerable research interest from a fundamental fluid dynamics perspective, in part because the combination of highly compressible flow at low-to-moderate Reynolds number is not very common, and in part due to the complex nature of the flow itself. In addition, microjets have a great variety engineering applications such as micro-propulsion, MEMS(Micro-Electro Mechanical Systems) components, microjet actuators and fine particle deposition and removal. Numerical simulations have been carried out at moderate nozzle pressure ratios and for different nozzle exit diameters to investigate and to understand in-depth of aerodynamic characteristics of supersonic microjets.

A Modeling Study on Aerosol Property Changes due to Sea-Salts (해염성분에 의한 에어로솔 물성변화 모사연구)

  • 김용표
    • Journal of Korean Society for Atmospheric Environment
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    • 제16권2호
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    • pp.113-120
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    • 2000
  • Effects of sea-salts on the properties of aerosol collected in a coastal region were studied by applying a gas-particle equilibrium model SCAPE to the measurement data from Korea Cheju Island in summer 1994. It was found that the observed higher ammonium concentrations in fine particles (PM2.5) than in TSP were caused by forced evaporation of ammonium in coarse fraction of aerosol by sea-salts and the degree of evaporation was quantified through an application of SCAPE. By subtracting the sea-salt fraction from the measured concentra-tions the changes of aerosol property were also studied. The concentrations of nitrate at both TSP and PM2.5 decreased when alkaline sea-salt fraction was removed from the measured data. Estimates of aerosol acidity increased for most samples with sea salt loadings, However in some cases with high mass fractions of sea-salt components the aerosol acidity of PM2.5 decreased slightly. This is though to be related with the formation of solid salt with the removal of sea-salts.

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Review of PM-related Air Quality Improvement Policies of United States for PM-related Air Quality Improvement of Metropolitan Region in Korea (수도권 미세먼지 환경 개선을 위한 미국의 대기환경정책 사례 조사 연구)

  • Woo, Jung-Hun
    • Journal of Korean Society for Atmospheric Environment
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    • 제25권6호
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    • pp.579-593
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    • 2009
  • Several fine particle-related policies in Northeast United States were investigated in support of the execution of special measures to improve air quality of Seoul Metropolitan Area (SMA). The definition of particulate matter (PM) in the Clean Air Act (CAA), components and procedures of Regional Haze Rule (RHR), and Air Quality Management (AQM) were reviewed. Several State Implementation Plans (SIPs) were also reviewed as the way to attain required air quality under the Clean Air Act. $PM_{2.5}$ attainment SIP of Maryland, 8-hr Ozone attainment SIP of New Jersey, and Regional Haze Rule attainment SIP of MANE-VU were analyzed in detail as case studies. We realized that "Special Measures for Air Quality Improvement in the Seoul Metropolitan Area" has many similarities with its US counterparts in terms of purpose, components, procedures, and implementation methods. US policies, however, have more advanced features, such as standardized procedures and methods, transparent guidelines, and stable relationship among federal/state/local governments and stakeholders, which would be helpful to improve air quality in SMA.

Opto-Chemical Characteristics of Visibility Impairment Using Semi-Continuous Aerosol Monitoring in an Urban Area during Summertime (에어로졸의 준실시간 관측에 의한 여름철 도시지역 시정 감쇄 현상의 광ㆍ화학적인 특성 분석)

  • 김경원;김영준
    • Journal of Korean Society for Atmospheric Environment
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    • 제19권6호
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    • pp.647-661
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    • 2003
  • For continuous monitoring of atmospheric visibility in the city of Kwanaju, Korea, a transmissometer system consisting of a transmitter and a receiver was installed at a distance of 1.91 km across the downtown Kwanaju. At the transmitter site an integrating nephelometer and an aethalometer were also installed to measure the scattering and absorption coefficients of the atmosphere, respectively. At the receiver site. an URG PM$_{2.5}$ cyclone sampler and an URG-VAPS (Versatile Air Pollutant Sampler) with three filter packs and two denuders were used to collect both PM$_{2.5}$ and PM$_{10}$ samples at a 2-hour or 12-hour sampling interval for aerosol chemical analysis. Sulfate, organic mass by carbon (OMC), nitrate, elemental carbon (EC) components of fine aerosol were the major contributors to visibility impairment. Diurnal variation of visibility during best-case days showed rapid improvement in the morning hours, while it was delayed until afternoon during the worst-case days. Aerosol mass concentration of each aerosol component for the worst-case was calculated to be 11.2 times larger than the best-case for (NH$_4$)$_2$SO$_4$(NHSO), 19.0 times for NH$_4$NO$_3$ (NHNO), 2.2 times for OMC, respectively. Also result shows that elemental carbon and fine soil (FS) were 3.7 and 2.2 times more than those of best-case. respectively- Sum of total contributions of wet NHSO and NHNO to light extinction was calculated to be 301 Mm$^{-1}$ for the worst-case. However, sum of contributions by dry NHSO and NHNO was calculated to be 123 Mm$^{-1}$ for the best case. Mass extinction efficiencies of fine and coarse particles were calculated to be 5.8$\pm$0.3 $m^2$/g and 1.8$\pm$0.1 $m^2$/g, respectively.ely.

Mass Concentration and Ion Composition of Size-segregated Particulate Matter during the Non-Asian Dust Storm of Spring 2007 in Iksan (익산지역에서 봄철 비황사기간 중 입경별 대기먼지농도와 이온조성)

  • Kang, Gong-Unn;Kim, Nam-Song;Lee, Hyun-Ju
    • Journal of Environmental Health Sciences
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    • 제34권4호
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    • pp.300-310
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    • 2008
  • In order to further determine the mass concentration and ion composition of size-segregated particulate matter (PM) during the non-Asian dust storm of spring, $PM_{2.5}$ (fine particle), $PM_{10-2.5}$ (coarse particle), and $PM_{over-10}$ (PM with an aerodynamic diameter larger than $10{\mu}m$) were collected using a MCI (multi-nozzle cascade impactor) sampler of a three-stage filter pack in the spring season of 2007 in the Iksan area. During the sampling period from 5 April to 21 April, a total of 34 samples for size-segregated PM were collected, and then measured for PM mass concentrations by gravimetric measurements and for water-soluble inorganic ion species by using ion chromatography. Average mass concentrations of $PM_{2.5}$, $PM_{10-2.5}$, $PM_{over-10}$ were $35.4{\pm}11.5{\mu}g/m^3$, $13.3{\pm}5.5{\mu}g/m^3$ and $9.5{\pm}4.7{\mu}g/m^3$, respectively. On average, $PM_{2.5}$ accounted for 74% of $PM_{10}$. Compared with the literature from other areas in Korea, the measured concentration of $PM_{2.5}$ were relatively high. Water-soluble inorganic ion fractions in $PM_{2.5}$, $PM_{10-2.5}$, and $PM_{over-10}$ were found to be 47.8%, 28.5%, and 14.7%, respectively. Among the water-soluble inorganic ion species, $SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ were the main components in $PM_{2.5}$, while $NO_3^-$ dominantly existed in both $PM_{10-2.5}$ and $PM_{over-10}$. Non-seasalt $SO_4^{2-}$ (nss-$SO_4^{2-}$ and $NO_3^-$ were found to mainly exist as the neutralized chemical components of $(NH_4)_2SO_4$ and $NH_4NO_3$ in fine particles.