• 제목/요약/키워드: film crystallinity

검색결과 643건 처리시간 0.031초

SBN 세라믹 박막의 유전특성에 관한 연구

  • 김진사;최영일;김형곤;오용철;신철기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 춘계학술대회 논문집
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    • pp.7-7
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    • 2010
  • The SBN thin films were deposited at substrate temperature of 300[$^{\circ}C$] on Pt-coated electrode (Pt/Ti/$SiO_2$/Si(100)) using RF sputtering method. The grain and crystallinity of SBN thin films were increased with the increase of annealing temperature. The dielectric constant(150) of SBN thin film was obtained by annealing temperature above 750[$^{\circ}C$]. The frequency dependence of dielectric loss showed a value within 0.03 in frequency ranges of 1~1000[kHz].

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RF 스퍼터링법에 의한 SBN 박막의 표면형상 및 유전특성 (Surface Morphology and Dielectric Properties of SBN Thin Film by RF Sputtering Method)

  • 김진사;김충혁
    • 한국전기전자재료학회논문지
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    • 제22권8호
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    • pp.671-676
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    • 2009
  • The $Sr_{0.7}Bi_{2.3}Nb_2O_9$(SBN) thin films are deposited on Pt-coated electrode(Pt/Ti/$SiO_2$/Si) using RF sputtering method at various deposition conditions. We investigated the effect of deposition condition on the surface morphology and dielectric properties of SBN thin films. The optimum of the rougness showed about 4.33 nm in 70/30 of Ar/$O_2$ ratio. The crystallinity and rougness of SBN thin films were increased with the increase of rf power. Also, Deposition rate of SBN thin films was about 4.17 nm/min in 70 W of rf power. The capacitance of SBN thin films were increased with the increase of Ar/$O_2$ ratio, rf power and deposition temperature respectively.

SBN 세라믹 박막의 기판온도에 따른 영향 (Influence of Substrate Temperature of SBN Ceramic Thin Film)

  • 김진사;오용철;신철기;김응권;소병문;송민종;김충혁
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.213-214
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    • 2008
  • The $Sr_{0.7}Bi_{2.3}Nb_2O_9$(SBN) thin films are deposited on Pt-coated electrode(Pt/Ti/SiO2/Si) using RF sputtering method at various substrate temperature. The optimum conditions of RF power and Ar/O2 ratio were 60[W] and 70/30, respectively. The crystallinity of SBN thin films were increased with increase of substrate temperature in the temperature range of 100~400[$^{\circ}C$]. The capacitance of SBN thin films were increased with the increase of substrate temperature.

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Physicochemical Changes in UV-Exposed Low-Density Polyethylene Films

  • Salem, M.A.;Farouk, H.;Kashif, I.
    • Macromolecular Research
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    • 제10권3호
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    • pp.168-173
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    • 2002
  • Unstabilized low-density polyethylene (LDPE) films and films formulated with hindered amine light stabilizer (HALS) were exposed to UV-radiation; and the physicochemical changes during photooxidation processes have been investigated using tensile, FTIR spectre-photometric and thermal analytical (DSC) techniques. The dependence of tensile properties (elongation- and stress-at-break), carboxyl index and heat of fusion on UV-irradiation time have been discussed. The use of HALS is found to be effective in maintaining the UV-mechanical properties of the LDPE films. The experimental results showed that there exists no correlation between mechanical properties and carbonyl index, whereas crystallinity correlates well with carbonyl index in unstabilized and stabilized films for irradiation times greater than 100 h. The rate of formation of carbonyl groups is found to be dependent on UV exposure time. Crystallinity of the film samples is strongly influenced by both exposure time and presence of HALS.

RF 스퍼터링법에 의한 (SrCa)Ti $O_3$ 세라믹 박막의 제초 및 미세구조 (Fabrication and microstructure of (Sr .Ca)Ti $O_3$ Ceramic Thin Films by RF Sputtering Method-)

  • 김진사;정일형;백봉현;김충혁;최운식;오재한;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.189-193
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    • 1997
  • (S $r_{0.85}$/C $a_{0.15}$)Ti $O_3$(SCT) thin films at various deposition temperature and rf power were grown by rf magnetron sputtering method on optimized Pt-based electrodes (Pt/TiN/ $SiO_2$/Si). The crystallinity of the films increases with increasing deposition temperature. SCT thin film is depend on the surface morphology and crystallinity of Pt films for bottom electrode. Dielectric constant of (S $r_{0.85}$C $a_{0.15}$)Ti $O_3$ thin films deposited on Si wafer substrate are larger with the increase of deposition temperature and gain size.in size.

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PET film의 알칼리 분해에 의한 구조변화에 관한 연구 (A Study on the Crystal Structure of PET films by the Alkali Treatment)

  • Myung Soo, Park;Man Woo, Huh
    • 한국염색가공학회지
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    • 제8권3호
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    • pp.16-23
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    • 1996
  • In order to know the change of weight loss, crystallinity, crystallite size(010) plane, and thermal properties of PET films which had before drawn and annealed at various temperature. It were treated in sodium triethylene glycolate-triethylene glycol(STEG-TEG) were prepared. The following results were abtain. The weight loss of PET films were increasing with increaing treated time in STEG-TEG solution and It showed a linear rlationship to the treated time. The crystallinity and crystallite size(010) plane of PET films decreased with increasing decomposition ratio when PET films were treated with before annealed under 16$0^{\circ}C$. The crystalline region on the surface of samples were decompose to thermal unstable crystalline structure

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전력 케이블용 폴리에틸렌의 열처리 효과(I) (Effects of Heat Treatment on Polyethylene Film for Power Cable Insulation(I))

  • 홍진웅;영치보웅;수곡조길
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1993년도 하계학술대회 논문집 B
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    • pp.1174-1176
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    • 1993
  • Morphology of low density polyethylene(LDPE) such as the degree of crystallinity changes with thermal history etc. In order to clarify the effects of morphological changes on electrical breakdown, we studied direct current and impulse breakdown phenomena of LDPE films heat-treated at 100[$^{\circ}C$] for 1[H] in silicone oil and subsequently cooling to various ways. The degree of crystallinity was estimated by the infra red absorption and X-ray diffraction measurements for the specimens of slowly cooled, cooled in water, original, and cooled in liquid nitrogen gas. As the result, we obtained that the first, second, third, and fourth was slowly cooled of 70.23[%], cooled in water of 61.6[%], original specimen of 56.75[%], and cooled in liquid nitrogen gas of 34.7[%] respectively. The crystalline size and distribution of specimens were researched by Differential scanning calolimeter measurements.

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Interfaces of Stacking $TiO_2$ Thin Layers Affected on Photocatalytic Activities

  • 주동우;부진효
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.189.1-189.1
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    • 2013
  • Titanium dioxide (TiO2) is a wide bandgap semiconductor possessing photochemical stability and thus widely used for photocatalysis. However, enhancing photocatalytic efficiency is still a challenging issue. In general, the efficiency is affected by physio-chemical properties such as crystalline phase, crystallinity, exposed crystal facets, crystallite size, porosity, and surface/bulk defects. Here we propose an alternative approach to enhance the efficiency by studying interfaces between thin TiO2 layers to be stacked; that is, the interfacial phenomena influencing on the formation of porous structures, controlling crystallite sizes and crystallinity. To do so, multi-layered TiO2 thin films were fabricated by using a sol-gel method. Specifically, a single TiO2 thin layer with a thickness range of 20~40 nm was deposited on a silicon wafer and annealed at $600^{\circ}C$. The processing step was repeated up to 6 times. The resulting structures were characterized by conventional electron microscopes, and followed by carrying out photocatalytic performances. The multi-layered TiO2 thin films with enhancing photocatalytic efficiency can be readily applied for bio- and gas sensing devices.

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DMAB첨가량에 따른 연성회로기판을 위한 무전해 Ni 도금박막에 관한 연구 (DMAB Effects in Electroless Ni Plating for Flexible Printed Circuit Board)

  • 김형철;나사균;이연승
    • 한국재료학회지
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    • 제24권11호
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    • pp.632-638
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    • 2014
  • We investigated the effects of DMAB (Borane dimethylamine complex, C2H10BN) in electroless Ni-B film with addition of DMAB as reducing agent for electroless Ni plating. The electroless Ni-B films were formed by electroless plating of near neutral pH (pH 6.5 and pH 7) at $50^{\circ}C$. The electroless plated Ni-B films were coated on screen printed Ag pattern/PET (polyethylene terephthalate). According to the increase of DMAB (from 0 to 1 mole), the deposition rate and the grain size of electroless Ni-B film increased and the boron (B) content also increased. In crystallinity of electroless Ni-B films, an amorphization reaction was enhanced in the formation of Ni-B film with an increasing content of DMAB; the Ni-B film with < 1 B at.% had a weak fcc structure with a nano crystalline size, and the Ni-B films with > 5 B at.% had an amorphous structure. In addition, the Ni-B film was selectively grown on the printed Ag paste layer without damage to the PET surface. From this result, we concluded that formation of electroless Ni-B film is possible by a neutral process (~green process) at a low temperature of $50^{\circ}C$.

Reaction Gas 변화에 따라 스퍼터된 Ga Doped ZnO 박막의 특성 (Properties of Sputtered Ga Doped ZnO Thin Film Under Various Reaction Gas Ratio)

  • 김종욱;김홍배
    • 한국전기전자재료학회논문지
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    • 제26권4호
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    • pp.289-293
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    • 2013
  • We have studied structural, optical, and electrical properties of the Ga-doped ZnO (GZO) thin films being usable in transparent conducting oxides. The GZO thin films were deposited on the corning 1737 glass plate by the RF magnetron sputtering system. To find optimal properties of GZO for transparent conducting oxides, the Ar gas in sputtering process was varied as 40, 60, 80 and 100 sccm, respectively. As reaction gas decreased, the crystallinity of GZO thin film was increased, the optical bandgap of GZO thin film increased. The transmittance of the film was over 80% in the visible light range regardless of the changes in reaction gas. The measurement of Hall effect characterizes the whole thin film as n-type, and the electrical property was improved with decreasing reaction gas. The structural, optical, and electrical properties of the GZO thin films were affected by Ga dopant content in GZO thin film.