• Title/Summary/Keyword: filler system

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Thermochemical Stability and Mechanical Properties of Ceramic-Filler Added BaO-ZnO-$B_2O_3$ Based Glass for Application to Barrier Rib in Plasma Display Panels

  • Kim, Sang-Gon;Shin, Hyun-Ho;Park, Jong-Sung;Hong, Kug-Sun;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.220-222
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    • 2004
  • Feasibility of BaO-ZnO-$B_2O_3$ (BZB) based glass system in the light of dielectric and thermal expansion properties are reported in the literature. Effects of addition of various types of ceramic fillers to the BZB-based glass on the thermochemical stability and mechanical properties were investigated in the present work. The studied filler-glass system demonstrated a capability to host various types of ceramic fillers to form thermochemically stable microcomposites at the processing temperature suitable for PDP systems. At the same time, mechanical strength of the filler-glass composites was much improved as compared to the glass itself These observations brighten the feasibility of the Pb-free BZB-based glass system as a host to employ various types of crystalline ceramic fillers so that it can be applied to barrier rib material in plasma display panels.

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Improvement of Paper Strength using Pretreated Precipitated Calcium Carbonate (PCC) (종이의 강도향상을 위한 경질탄산칼슘(PCC) 전처리에 대한 연구)

  • Kim, Chul-Hwan;Lee, Ji-Young;Gwak, Hye-Joeng;Chung, Ho-Kyung;Back, Kyung-Kil;Lee, Hui-Jin;Kim, Sung-Ho;Kang, Ha-Ryoun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.1
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    • pp.41-47
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    • 2010
  • Increasing ash content of the paper is one of the most effective methods for saving raw materials and steam consumption and improving optical properties and better print quality. However, the increase of filler loading or filler content using a conventional wet end system is limited due to severe loss in strength properties, affecting runnability and product quality. This is because the filler has no ability to make bonding with cellulosic fibers. Therefore, if the technology to give filler the bonding ability is developed, the ash content of the paper can be increased more than ever. This study was carried out to modify PCC by coating its surface with starch contributing to better bonding with fibers. To prepare the modified PCC, cationic starch was selected as a polymer and then pretreatment was done by mixing PCC and cationic starch. Consequently, the pretreated PCC contributed to higher tensile strength, stiffness and opacity than the conventional filler, such as GCC and untreated PCC. However, CIE whiteness and ISO brightness decreased slightly compared to conventional fillers.

Thermal Diffusivity of PEEK/SiC and PEEK/CF Composites (PEEK/SiC와 PEEK/CF 복합재료의 열확산도에 대한 연구)

  • Kim, Sung-Ryong;Yim, Seung-Won;Kim, Dae-Hoon;Lee, Sang-Hyup;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.9 no.3
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    • pp.7-13
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    • 2008
  • The particulate type silicon carbide (SiC) and fiber type carbon fiber (CF) filler, of similar thermal conductivities, were mixed with polyetheretherketone (PEEK) to investigate the filler effects on the thermal diffusivity. The SiC and CF fillers had a good and uniform dispersion in PEEK matrix. Thermal diffusivities of PEEK composites were measured from ambient temperature up to $200^{\circ}C$ by laser flash method. The diffusivities were decreased as increasing temperature due to the phonon scattering between PEEK-filler and filler-filler interfaces. Thermal diffusivity of PEEK composites was increased with increasing filler content and the thermal conductivities of two-phase system were compared to the experimental results and it gave ideas on the filler dispersion, orientation, aspect ratio, and filler-filler interactions. Nielson equation gave a good prediction to the experimental results of PEEK/SiC. The easy network formation by CF was found to be substantially more effective than SiC and it gave a higher thermal diffusivities of PEEK/CF than PEEK/SiC.

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The Effects of a Filler with a High Coefficient of Thermal Expansion on a Sealant for High-Temperature (750 ~ 850℃) SOFCs (고온 (750 ~ 850℃) SOFC용 밀봉재의 특성에 미치는 고열팽창계수를 갖는 필러의 영향)

  • Kim, Bit Nam;Lee, Mi Jai;Hwang, Jong Hee;Lim, Tae Young;Kim, Jin Ho;Hwang, Hae Jin;Kim, Il Won;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.470-475
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    • 2013
  • In this study, we report that effects of a filler with a high coefficient of thermal expansion on a sealant for high-temperature ($750{\sim}850^{\circ}C$) SOFC. We designed a $SiO_2-BaO-ZnO-B_2O_3-Al_2O_3$ glass system with a softening temperature higher than $750^{\circ}C$. The properties of the glass system show not only low volumetric shrinking but also low swelling. The glass system did not create a crystal phase during along-term heat treatment. We fabricated a seal gasket with 0, 10, 15, and 20 wt% cristobalite added as filler materials with glass powder. The coefficient of thermal expansion of the seal gasket increased according to cristobalite content. During along-term heat treatment, the leak rate decreased by about 5% after a heat treatment in an oxidizing atmosphere at $750^{\circ}C$ for 2000 h, also decreasing by about 6% after a heat treatment in a reducing atmosphere at $750^{\circ}C$ for 1000 h.

Prediction of Viscosity in Liquid Epoxy Resin Mixed with Micro/Nano Hybrid Silica (액상 에폭시 수지와 마이크로/나노 하이브리드 실리카 혼합물의 점도 예측)

  • Huang, Guang-Chun;Lee, Chung-Hee;Lee, Jong-Keun
    • Korean Journal of Materials Research
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    • v.21 no.2
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    • pp.100-105
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    • 2011
  • The relative viscosity was measured at different filler loadings for a cycloaliphatic epoxy resin and hexahydro-4-methylphthalic anhydride hardener system filled with micro/nano hybrid silica. Various empirical models were fitted to the experimental data and a fitting parameter such as critical filler fractions (${\phi}_{max}$) was estimated. Among the models, the Zhang-Evans model gave the best fit to the viscosity data. For all the silica loadings used, ln (relative viscosity) varied linearly with filler loadings. Using the Zhang-Evans model and the linearity characteristics of the viscosity change, simple methods to predict the relative viscosity below ${\phi}_{max}$ are presented in this work. The predicted viscosity values from the two methods at hybrid silica fractions of $\phi$ = 0.086 and 0.1506 were confirmed for a micro:nano = 1:1 hybrid filler. As a result, the difference between measured and predicted values was less than 11%, indicating that the proposed predicting methods are in good agreement with the experiment.

Effects of Strain Rate and Temperature on Fracture Strength of Ceramic/Metal Joint Brazed with Ti-Ag-Cu Alloy

  • Seo, Do-Won;Lim, Jae-Kyoo
    • Journal of Mechanical Science and Technology
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    • v.16 no.9
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    • pp.1078-1083
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    • 2002
  • Ceramics are significantly used in many industrial applications due to their excellent mechanical and thermal properties such as high temperature strength, low density, high hardness, low thermal expansion, and good corrosion resistive properties, while their disadvantages are brittleness, poor formability and high manufacturing cost. To combine advantages of ceramics with those of metals, they are often used together as one composite component, which necessiates reliable joining methods between metal and ceramic. Direct brazing using an active filler metal has been found to be a reliable and simple technique, producing strong and reliable joints. In this study, the fracture characteristics of Si$_3$N$_4$ ceramic joined to ANSI 304L stainless steel with a Ti-Ag-Cu filler and a Cu (0.25-0.3 mm) interlayer are investigated as a function of strain rate and temperature. In order to evaluate a local strain a couple of strain gages are pasted at the ceramic and metal sides near joint interface. As a result the 4-point bending strength and the deflection of interlayer increased at room temperature with increasing strain rate. However bending strength decreased with temperature while deflection of interlayer was almost same. The fracture shapes were classified into three groups ; cracks grow into the metal-brazing filler line, the ceramic-brazing filler line or the ceramic inside.

Development of Statistical Model and Neural Network Model for Tensile Strength Estimation in Laser Material Processing of Aluminum Alloy (알루미늄 합금의 레이저 가공에서 인장 강도 예측을 위한 회귀 모델 및 신경망 모델의 개발)

  • Park, Young-Whan;Rhee, Se-Hun
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.4 s.193
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    • pp.93-101
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    • 2007
  • Aluminum alloy which is one of the light materials has been tried to apply to light weight vehicle body. In order to do that, welding technology is very important. In case of the aluminum laser welding, the strength of welded part is reduced due to porosity, underfill, and magnesium loss. To overcome these problems, laser welding of aluminum with filler wire was suggested. In this study, experiment about laser welding of AA5182 aluminum alloy with AA5356 filler wire was performed according to process parameters such as laser power, welding speed and wire feed rate. The tensile strength was measured to find the weldability of laser welding with filler wire. The models to estimate tensile strength were suggested using three regression models and one neural network model. For regression models, one was the multiple linear regression model, another was the second order polynomial regression model, and the other was the multiple nonlinear regression model. Neural network model with 2 hidden layers which had 5 and 3 nodes respectively was investigated to find the most suitable model for the system. Estimation performance was evaluated for each model using the average error rate. Among the three regression models, the second order polynomial regression model had the best estimation performance. For all models, neural network model has the best estimation performance.

Electrical and Mechanical Strength Properties of Epoxy/Micro Silica and Alumina Composites for Power Equipment (전력기기용, 에폭시/마이크로 실리카 및 알루미나 복합제의 전기적·기계적 파괴 강도 특성)

  • Park, Joo-Eon;Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.7
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    • pp.496-501
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    • 2018
  • In this study, we prepared 40, 45, 50, 55, 60, 65, and 70 wt% content composites filled in epoxy matrix for two micro silica and three micro alumina types for use as a GIS heavy electric machine. As a filler type of epoxy composite, micro silica composites showed excellent AC breakdown strength properties compared to micro alumina composites in the case of electrical properties of micro silica and alumina. The electrical breakdown properties of micro silica composites increased with increasing filler content, whereas those of micro alumina decreased with increasing filler content. In the case of mechanical properties, the micro silica composite showed improved tensile strength and flexural strength compared with the micro alumina composite. In addition, mechanical properties such as tensile strength and flexural strength of micro silica and alumina composites decreased with increasing filler content. This is probably because O-H groups are present on the surface of silica in the case of micro silica but are not present on the surface of alumina in the case of micro alumina.

Characterization with Change of $R_2O_3$, RO in $SiO_2-R_2O_3-RO$ System for SOFC Sealnat (SOFC 밀봉재로서 $SiO_2-R_2O_3-RO$계에서 $R_2O_3$, RO 변화 따른 특성)

  • Yang, Sang-Jin;Choi, Byung-Hyun;Lee, Mi-Jai;Jee, Mi-Jung;Lee, Hong-Lim;Yoo, Yung-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.8-11
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    • 2007
  • SOFC 스택 밀봉재로서 $SiO_2-R_2O_3$계를 선정하여 $R_2O_3$와 RO를 변화 하였을 때 유리 전이 온도, 열팽창계수, 이종 물질간의 젖음성, 환원 가스에 반응성 등을 조사하였다. 또한 모유리에 filler를 넣었을 때 filler 첨가에 따른 특성을 조사한 결과 $B_2O_3/SiO_2$ 함량비 증가에 따라 열팽창계수는 증가하였고 전이점은 낮아졌으며 밀봉재를 이용한 SUS 와 SUS를 $800^{\circ}C$ 접합 후 산화 ${\cdot}$ 환원분위기에서 작동했을 때. 화학적 반응 및 확산 반응층은 관찰되지 않았다.

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The Thermal Properties of PVC-Ni Composite Materials

  • Moon, Tak-Jin;Kang Chang-Gyun
    • Bulletin of the Korean Chemical Society
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    • v.6 no.1
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    • pp.45-50
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    • 1985
  • The glass transition temperature, dynamic shear moduli, and bulk viscosities of PVC, filled with nickel particles, were investigated. The glass temperature of the composite increased with increasing filler concentration. The data were interpreted by assuming that the interaction between filler particles and the polymer matrix reduces molecular mobility and flexibility of the polymer chains in the vicinity of the interfaces. The relative modulus for the PVC/Ni composite system followed the Kerner equation. The relative viscosities were strongly temperature dependent and did not agree with the conventional viscosity predictions for suspensions. It is suggested that the filler has a twofold effect on the viscosity of the composite materials; one is due to its mechanical presence and the other is due to modification of part of the polymer matrix caused by interaction. This phenomenon is approximately bounded by Kerner's predictions for suspensions.