• Title/Summary/Keyword: filler system

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Flow Properties of Liquid Epoxy Compounds as a Function of Filler Fraction for the Underfill (Underfill용 액상 Epoxy Compound의 Filler 충진에 따른 Flow특성 연구)

  • 김원호;황영훈;배종우;정혜욱
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.2
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    • pp.21-27
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    • 2000
  • To develop the underfill materials which are required for the new process of semi-conductor industry, the properties of epoxy/anhydride/cobalt(II) catalyst system with two types of fused silica(1 $\mu\textrm{m}$, 8 $\mu\textrm{m}$) are studied as a function of filler fraction. According to the curing profile, the optimum catalyst amount was 1.0 wt% for full curing at the conditions of $160^{\circ}C$/l5 min., and we could conclude that the viscosity has superior effect on the real flaw through the relationship between surface tension and viscosity data. The underfills which were filled with 1 $\mu\textrm{m}$ fused silica did not show good flowability, but they should be useful by improving the viscosity for a future process which has small gaps. The underfills which were filled with 8 $\mu\textrm{m}$ fused silica showed good flowability when the filler contents were 55~60 vol%. The model which was referred by Matthew can predict the real flow length only when the underfill has high viscosity and low surface tension.

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The Efficacy of New Hyaluronic Acid Filler (HyaFilia) (새롭게 개발된 히알루론산 필러(히아필리아)의 유용성)

  • Jang, Joon-Chul;Shin, Soo-Hye;Han, Seung-Kyu;Kim, Woo-Kyung
    • Archives of Plastic Surgery
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    • v.38 no.1
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    • pp.1-6
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    • 2011
  • Purpose: Currently, soft tissue filler products based on hyaluronic acid are widely used. They are safe, effective, and convenient to use compared with bovine collagens. However, all commercially available hyaluronic acid based fillers in Korea are imported ones. The purpose of this study is to evaluate efficacy of a new hyaluronic acid filler (HyaFilia; CHA bio&Diostech Co., Seoul), which has been recently developed in Korea. Methods: Three kinds of soft tissue fillers, including Restylane (Q-Med, Uppsala, Sweden), HyaFilia (CHA bio & Diostech Co., Seoul), Juvederm (Allergan, CA, USA), were injected subdermally into the back of hairless mice at six sites. The 2 cephalic sites composed Restylane groups, the 2 middle sites HyaFilia groups, and the 2 caudal sites Juvederm groups. Six hairless mice were included in the study, therefore, a total of 12 injections per group were performed. After 16 weeks after injection, the nodular swellings that resulted from the injections were excised wide enough to include skin beyond the swelling points down to the panniculus carnosus layer using 8mm punches. Volumes and weights were measured using a stereoimage optical topometer system and a weighting machine. Histologic comparisons were also carried out. Results: The mean volumes of the Restylane, HyaFilia and Juvederm groups were $3698{\times}103$, $4820{\times}103$, and $1435{\times}103$ PI, respectively. The mean weights of the Restylane, HyaFilia and Juvederm groups were 36.08, 37.83, and 24.66 mg, respectively. Histologic examination between the 3 groups showed no significant difference in tissue compositions and inflammatory reactions. Conclusion: The results of this study shows that HyaFilia is superior to Restylane and Juvederm in longavity of filling effect. Therefore, HyaFilia may be an effective replacement for the imported materials including Restylane and Juvederm.

Electrical and the Mechanical Properties of Graphite particle/carbon fiber hybrid Conductive Polymer Composites (흑연입자/탄소섬유 혼합 보강 전도성 고분자 복합재료의 전기적, 기계적 특성 연구)

  • Heo Seong-Il;Yun Jin-Cheol;Oh Kyung-Seok;Han Kyung-Seop
    • Composites Research
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    • v.19 no.2
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    • pp.7-12
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    • 2006
  • Graphite particle/carbon fiber hybrid conductive polymer composites were fabricated by the compression molding technique. Graphite particles were mixed with an epoxy resin to impart the electrical conductivity in the composite materials. In this study, graphite reinforced conductive polymer composites with high filler loadings were manufactured to accomplish high electrical conductivity above 100S/cm. Graphite particles were the main filler to increase the electrical conductivity of composites by direct contact between graphite particles. While high filler loadings are needed to attain good electrical conductivity, the composites becomes brittle. So carbon fiber was added to compensate weakened mechanical property. With increasing the carbon fiber loading ratio, the electrical conductivity gradually decreased because non-conducting regions were generated in the carbon fiber cluster among carbon fibers, while the flexural strength increased. In the case of carbon fiber 20wt.% of the total system, the electrical conductivity decreased 27%, whereas the flexural strength increased 12%.

Recovery Behaviors of Natural Rubber Composites Thermally Aged in Altering Medium Systems of Air and Water (공기와 물의 교매질 시스템에서 열노화된 천연고무 복합체의 회복 거동)

  • Choi, Sung-Seen;Kim, Ok-Bae
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.181-189
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    • 2013
  • Unfilled, carbon black-filled, and silica-filled natural rubber (NR) composites were aged with a circular deformation at $60-90^{\circ}C$ and the recovery behaviors were investigated. The samples were aged under the altering aging medium systems of air and distilled water every day for 10 days. The order of the recoveries according to the filler systems was unfilled > silica > carbon black. The recoveries of the samples aged in the air to water altering system were greater than those of the samples aged in the water to air altering system. The initial aging medium dominantly influenced the deformation level.

SBR/Organoclay Nanocomposites for the Application on Tire Tread Compounds

  • Kim, Wook-Soo;Lee, Dong-Hyun;Kim, Il-Jin;Son, Min-Jin;Kim, Won-Ho;Cho, Seong-Gyu
    • Macromolecular Research
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    • v.17 no.10
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    • pp.776-784
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    • 2009
  • N,N-dimethyldodecylamine (tertiary amine)-modified MMT (DDA-MMT) was prepared as an organically modified layered silicate (OLS), after which styrene-butadiene rubber (SBR) nanocomposites reinforced with the OLS were manufactured via the latex method. The layer distance of the OLS and the morphology of the nanocomposites were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). By increasing the amount of N,N-dimethyldodecylamine (DDA) up to 2.5 g, the maximum values of torque, tensile strength and wear resistance of the SBR nanocomposites were increased due to the increased dispersion of the silicate layers in the rubber matrix and the increased crosslinking of the SBR nanocomposites by DDA itself. When SBR nanocomposites were manufactured by using the ternary filler system (carbon black/silica/OLS) to improve their dynamic properties as a tire tread compound, the tan $\delta$(at $0^{\circ}C$ and $60^{\circ}C$) property of the compounds was improved by using metal stearates instead of stearic acid. The mechanical properties and wear resistance were increased by direct substitution of calcium stearate for stearic acid because the filler-rubber interaction was increased by the strong ionic effect between the calcium cation and silicates with anionic surface. However, as the amount of calcium stearate was further increased above 0.5 phr, the mechanical properties and wear resistance were degraded due to the lubrication effect of the excessive amount of calcium stearate. Consequently, the SBR/organoclay nanocomposites that used carbon black, silica, and organoclay as their ternary filler system showed excellent dynamic properties, mechanical properties and wear resistance as a tire tread compound for passenger cars when 0.5 phr of calcium stearate was substituted for the conventionally used stearic acid.

HNO3 Etching Properties of BaO-B2O3-ZnO-P2O5 System of Barrier Ribs in PDP (플라스마 디스플레이 패널의 격벽용 BaO-B2O3-ZnO-P2O5계의 HNO3를 이용한 에칭 특성)

  • Jeon, J.S.;Kim, J.M.;Kim, N.S.;Kim, H.S.
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.235-240
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    • 2006
  • We investigated the effect of ZnO filler on the microstructure of $BaO-B_2O_3-ZnO-P_2O_5$ glass system to find an etching mechanism of barrier ribs. The sintering behavior of composites heated in the temperature range $560-600^{\circ}C$ was studied by volumetric shrinkage rate and microstructure. The etching test was carried out in $HNO_3$ solution at $50^{\circ}C$ for 10 min. The volumetric shrinkage of sintered sample decreased with the increased firing temperature because of the formation of two crystals. Glass and ZnO filler react forming the $BaZn_2(PO_4)_2$ crystal phases during the sintering process. Etching phenomenon of sintered samples by $HNO_3$ showed that the $BaZn_2(PO_4)_2$ crystal phase was strongly leached compared to glass matrix, crystal phases and fillers. Therefore, the control of interface by condition of sintering is so important to achieve etching effect in barrier ribs.

A Study on the Efficiency Improvement of Glazing Panel with DSC Modules (염료감응형 태양전지를 적용한 유리 패널의 효율 향상에 관한 연구)

  • Jang, Han-Bin;Kang, Jun-Gu;Lee, Sang-Gil;Kim, Jun-Tae
    • Journal of the Korean Solar Energy Society
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    • v.33 no.2
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    • pp.35-41
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    • 2013
  • Dye-sensitized solar cell (DSC) allows light transmission and the application of various colors that make it especially suitable for building-integrated PV (BIPV) application. In order to apply DSC module into windows, it has to be panelized: DSC module should be protected with reinforced glass to the entire surface. Up to date, it seems to be common to make double glazing with DSC modules with air gaps between the glasses and the DSC modules. Few research has been conducted on the characteristics of various glazing types with DSC modules. This study aims to analyze the electrical performance of DSC modules according to panelizing method for glazing unit with DSC modules. The prototype of the DSC glazing that applied silicone filler between DSC modules and glasses was developed. The electrical performances of this type of DSC glazing with the filler and rather conventional double glazing with DSC modules were compared. Their performances were measured using a solar simulator that is suitable for DSC performance testing. The results indicated that the electrical performance of the filler type DSC glazing improved by 7% compared to that of the conventional DSC double glazing type.

Esthetic Properties of Photoinitiated Polymeric Dental Restorative Nanocomposites (광중합형의 치아수복용 고분자 나노복합체의 심미 특성)

  • Kim, Oh-Young;Han, Sang-Hyuk;Kim, Chang-Keun
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.102-105
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    • 2005
  • Photoinitiated polymeric dental restorative nanocomposites (PDRNC) were designed to be useful for the variety of dental restoration. Hybrid-filler composed of barium silicate (avg. dia.:1 ${\mu}m$) and nano-sized silica (avg. dia: 40 and 7 nm) was adopted as a filler system. To improve the interfacial behavior with the resin matrix of bisphenol A glycerolate methacrylate/triethyleneglycol dimethacrylate (60/40 wt%), the surface of the filler was hydrophobically treated with a silane coupling agent. A visible light system of camphorquinone photo-initiator and 2-(dimethylamino)ethyl methacrylate photo-accelerator was utilized to activate the PDRNC. Esthetic properties of PDRNC was investigated by measuring the Hunter L, a, b values and it was discovered that PDRNC produced in this work showed excellent esthetic properties with an increase in 7 nm nanofiller content.

Filtration Characteristics of Magnetic Fibrous Polymeric Filter Elements for Industrial Lub-systems (산업용 자성폴리머 필터소재의 여과특성 연구)

  • 안병길;최웅수;이용훈;정용진;권오관
    • Tribology and Lubricants
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    • v.12 no.3
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    • pp.39-47
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    • 1996
  • The magnetic fibrous polymeric oil filter elements for industrial lub-systems were obtained by pneumoextrusion processing prepared from thermoplastic pqlymer (polyamide) containing a magnetic particulate filler (Ba ferrite), and treated subsequently in a magnetic fields. Using the standard laboratory oil filtration test rig, metallic particle quantifier and image analyser system, the dependence of filtration charateristics of the magnetic filter media on the parameters of porosity and magnetic properties was investigated. The pressure drops and efficiencies of lubricating filter elements were measured on the packing density and magnetised filler content of filter element. Also, the industrial lub-systems such as lubricant filters for gear test rig and electric discharge processing machine were used for testing the flitrational characteristics of tl, c magnetised filter elements. The magnetic fibrous polymeric filter material was shown to possess a highly filtration efficiency in filtering the fine ferrous particles with increasing the magnetic force of filter element. Therefore, it is expected that the magnetic fibrous polymeric filter material should be used for effective oil filrers on the industrial lub-systems.

Mechanical and Thermal Characteristics of Cu Particle Filled Epoxy Resin Composites for EMI Shielding (CU 분말 충전된 전자파 차폐용 에폭시 수지 복합체의 기계적, 열적특성)

  • Cho, Young-Shin;Shim, Mi-Ja;Kim, Sang-Wook
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1591-1593
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    • 1996
  • The experimental study was carried out to investigate the effects of metallic particulate filler on the mechanical properties and the thermal properties of epoxy resin system filled with Cu powder. As Cu contents increased, the tensile strength, surface hardness and $T_d$ decreased. $T_g$ increased and decreased at 300 phr. $E_d$ decreased and increased at 200 phr, because the thermal conducting path of filler was formed and dissipated thermal stress.

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