• Title/Summary/Keyword: filled rubber

Search Result 236, Processing Time 0.029 seconds

A study on the change of the fatigue life and the fracture morphology due to the carbon black on the Natural rubber for vibration-proof (철도차량 부쉬용 방진 천연고무의 카본블랙 강화제에 의한 피로수명과 파단 모폴로지 변화 연구)

  • Kim Jae-Hoon;Hur Hyun-Moo
    • Journal of the Korean Society for Railway
    • /
    • v.8 no.1
    • /
    • pp.21-26
    • /
    • 2005
  • The effects of carbon black on the fatigue lift and the fracture morphology and the carbon black dispersion of the carbon-black filled natural rubbers, for the vibration-proof, were investigated. Different kinds of carbon blacks resulted in different fatigue lift and fracture morphologies, which are classified by micro-scale and macro-scale fracture morphologies. These results be related to the size distribution of carbon black particles, the development of the carbon black agglomerate and the combine forces between the carbon black and the natural rubber.

저구조 Black의 보강특성과 그 이용

  • Baek, Bong-Gi
    • The tire
    • /
    • s.6
    • /
    • pp.29-34
    • /
    • 1967
  • Low-structure black has proved to be a useful addition to the group of reinforcing fillers, allowing greater compounding flexibility and economy. Quite apart from the quality advantages, the volume used to date represents a considerable dollar saving by the rubber industry. Low-structure has also filled a need in a number of critical applications, and promises to become of increasing importance.

  • PDF

Amino Silane, Vinyl Silane, TESPD, ZS (TESPD/Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber (CIIR) Compounds Part III: Comparative Studies on Hard Clay and Soft Clay Filled Compounds

  • Kim, Kwang-Jea
    • Carbon letters
    • /
    • v.10 no.3
    • /
    • pp.190-197
    • /
    • 2009
  • Various silanes, amino silane, vinyl silane, sulfur silane (TESPD), and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB) and CIIR/hard clay/CB compounds and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. Comparing hard clay and soft clay filled compounds, hard clay (Suprex) filled system shows a higher die C tear than the soft clay (GK) filled one. The other properties (Mooney, extrusion torque/pressure, torque rise ($M_H-M_L$), modulus at 300%) are close to each other. Among various silanes, the ZS treated hard clay (Suprex) compound shows the highest mechanical property following hard clay(S)/vinyl silane(V) and soft clay(GK)/vinyl silane(V) compounds. The TESPD and the ZS effectively helps a formation of a strong 3-dimensional network structure between silica and CIIR via coupling reaction due to bifunctional nature of TESPD. In addition to that, the ZS added compounds show both a better processability and mechanical properties compared to the S2 ones at low concentration due to improved compatibility between zinc soap and CIIR matrix. Only the ZS added compound shows both improved processabilities (Mooney, Extrusion torque-& pressure) and improved mechanical properties (degree of crosslinking, elongation modulus, tear, and fatigue to failure counts) on both CIIR/hard clay/CB and CIIR/soft clay/CB compounds.

Amino Silane, Vinyl Silane, TESPD, ZS(TESPD/Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber(CIIR) Compounds Part I: Effects on Hard Clay/Carbon Black Filled Compounds

  • Kim, Kwang-Jea
    • Carbon letters
    • /
    • v.10 no.2
    • /
    • pp.101-108
    • /
    • 2009
  • Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/hard clay/carbon black (CB) compound and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. In hard clay/CB filled system, only ZS silane added compound shows both lower Mooney viscosity and extrusion torque while vinyl silane added compound showed only a lower extrusion torque. All the ZS added compounds showed the lowest viscosity among them. The silane added compounds showed an increased modulus. In 'fatigue to failure' count test, the ZS added compound showed superior counts compared to other silane (amino, vinyl, TESPD) added compounds. The mechanical properties were significantly increased when the S2 and ZS were added into CIIR/hard clay/CB compound. The ZS added compounds showed a significant improvement on elongation modulus.

Amino Silane, Vinyl Silane, TESPD, ZS(TESPD/Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber(CIIR) Compounds Part II: Effects on Soft Clay/Carbon Black Filled Compounds

  • Kim, Kwang-Jea
    • Carbon letters
    • /
    • v.10 no.2
    • /
    • pp.109-113
    • /
    • 2009
  • Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB). The vulcanization characteristics, the processability, and the mechanical properties are measured. In soft clay/CB filled CIIR system, there are no significant changes in Mooney viscosity among compounds. Vinyl silane added compound shows a low extrusion torque. All the silane added compounds shows an increased modulus. The mechanical properties are significantly increased when the S2 is added into CIIR/soft clay/CB compounds.

Conductive Carbon Block filled Composite(I): The Effect of Carbon Block on the Conductivity (전도성 카본블랙이 충전된 도전성 고분자 복합재료(I): 카본블랙이 전기전도성에 미치는 영향)

  • Kim, Jin-Kuk
    • Elastomers and Composites
    • /
    • v.33 no.5
    • /
    • pp.355-362
    • /
    • 1998
  • The purpose of this paper is to develop a rational engineering conductive carbon filled composite through understanding of the effect of conductive carbon black. Polycabonate(PC), Acrylonitrile Butadiene Styrene copolymer(ABS) and PC/ABS resin were used as matrix of the conductive polymer composites. From the experimental results, PC filled with the fiber shaped carbon black showed a possibility to be a rational engineering conductive composite.

  • PDF

A Study of Isolation-Effect of Surface Wave Using Open or In-filled Trenches (진동차단 구조물에 의한 표면파의 진동차단효과에 관한 연구)

  • 김문겸
    • Proceedings of the Earthquake Engineering Society of Korea Conference
    • /
    • 1999.04a
    • /
    • pp.100-108
    • /
    • 1999
  • rectangular open or in-filled trenches(concrete and rubber) are often used to reduce the ground vibrations caused by propagating surface(Rayleigh) waves. This paper presents the experimental data for estimating the vibration screening effectiveness of open or in-filled trenches Field dynamic tests using the exciter which can generate the 100kN vertical cyclic load in the range of 100-250 Hz were performed. One hundred and twenty accelerometers to measure the ground response are used in 6 radial direction. To compare the effectiveness of the vibration isolation the contours of the amplitude ratio with the dimensionless parameters dividing by Rayleight wave lengths were presented.

  • PDF

Estimation of Electric Properties of Insulating Silicone Rubbers Added Reinforcing Fillers (보강성 충전제를 첨가한 절연용 실리콘 고무의 전기 특성 평가)

  • Lee, Sung-Ill
    • Elastomers and Composites
    • /
    • v.32 no.5
    • /
    • pp.309-317
    • /
    • 1997
  • Estimation of the dielectric properties of insulating silicone rubbers added reinforcing fillers $(SiO_2,\;0{\sim}140phr)$ are very important to investigate the polymer structure. The characteristies of the dielectric absorption in insulating silicone rubbers were studied in the frequency range from 30Hz to 1MHz at the temperature range from $0{\sim}170^{\circ}C$. In the case of non-filled specimen, the dielectric loss is due to the syloxane which is the main chain of silicone rubber at the low temperature below $50^{\circ}C$ and the frequency at 330Hz, and is due to methyl and vinyl radical over the frequency of 1MHz. It is confirmed that the methyl radical or the vinyl radical becomes thermal oxidation at the high temperature over $100^{\circ}C$ and then the dielectric disperssing owing to the carboxyl radical Is appeared. In the case of filled specimen, the dielectric constant is in creased with the additives of reinforcing fillers due to the effect of interfacial polarization explained by MWS(Maxwell-Wagner-Sillars)'s law. The dielectric loss is decreased by the disturbance of reinforcing fillers that is permeated between networks.

  • PDF

Investigation of tracking resistance of engineering plastic and engineering plastic coated silicon rubber (엔지니어링 플라스틱과 실리콘 고무가 코팅된 엔지니어링 플라스틱의 내트래킹성 검토)

  • Heo, Jun;Jung, Eui-Hwan;Lim, Jong-Nam;Lim, Kee-Joe;Kang, Seong-Hwa
    • Proceedings of the KIEE Conference
    • /
    • 2009.07a
    • /
    • pp.1449_1450
    • /
    • 2009
  • Surface contamination and leakage current have caused operating problems. A flashover in a substation may result in destruction of an insulator or many others electrical equipment. Engineering plastics have good characteristic (light weight, good productivity and little of void) as compare with epoxy or porcelain insulators. Outdoor insulator must have resistance to contamination. However, they are not suited to outdoor insulator by reason of being not good hydrophobic. RTV has a good property of hydrophobic and ATH has characteristic obstructing exothermic reaction. In order to reduce the incidence of insulator flashover and damage, the silicon rubber contained nano size ATH coat on surface of engineering plastics. In this paper, it compares resistance tracking of the engineering plastic coated RTV with that of non-coated engineering plastic and ATH filled composites performed much better than non-filled composites.

  • PDF

A Study on Dynamic Properties for the Filler Compounded NR Vulcanizates ( I ) (각종(各種) 충전제(充塡劑)를 배합(配合)한 천연(天然)고무 강황체(加黃體)의 특성(特性)에 관(關)한 연구(硏究) ( I )(동적(動的) 특성(特性)에 관(關)하여))

  • Choi, Jae-Woon;Herh, Dong-Sub;Hong, Chung-Sug
    • Elastomers and Composites
    • /
    • v.19 no.4
    • /
    • pp.231-242
    • /
    • 1984
  • NR vulcanizate has its unigue characteristic of cushion, silence, vibration energy absorbtion etc. By reason of the above captioned characters, The vulcanizate has been widely applied to production of auto tires, belts and engine mounts, The purpose of this study is to examine the effect of rubber-filler attachments on the various dynamic properties of the NR vulcanizates. For this study, the elastic modulus and damping values are examined by means of the (RDS) the Good Rich Flexometer. The results of this study showed as follows. The damping values of the vulcaniz ates in the elastic region showed showed strong relations the damping values and the filler characteristics. The vulvanizates filled with carbon black had higher damping values than the vulcanizates loaded with inorganic filler. The Goodrich Flexometer test showed that build up for the silica filled NR vulcanizates was higher than those for which contained other fillers.

  • PDF