• Title/Summary/Keyword: fiber analysis

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Nafion Impregnated Electrospun Polyethersulfone Membrane for PEMFC (Nafion 용액 함침과 전기방사를 이용한 고분자 전해질 연료전지용 폴리에테르술폰 막)

  • Lee, Hong-Yeon;Hwang, Hyung-Kwon;Park, Sang-Sun;Choi, Sung-Won;Shul, Yong-Gun
    • Membrane Journal
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    • v.20 no.1
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    • pp.40-46
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    • 2010
  • In this study, we manufactured the membrane using the polyethersulfone (PES) of fiber by using the electrospinning method. The polymer electrolyte membrane for fuel cells was manufactured by impregnating Nafion solution to the porous PES membrane. We confirmed that electrospun PES membrane has higher thermal stability than Nafion 212 membrane by thermogravimetric analysis. Impregnated Nafion in the pores of the electrospun PES membrane was characterized by scanning electron microscopy. The AC impedance data shows the hydrogen ionic conductivity of $10^{-2}$ S/cm below $100^{\circ}C$. Nafion impregnated PES membrane shows the maximum performance at $90^{\circ}C$ showing current density of 389 mA/$cm^2$ at 0.6 V, while Nafion 212 membrane shows maximum at $75^{\circ}C$.

Studies on Synthesis of N,N’-Bis(diphenyl phosphoro)diaminohexane and Flame Retardancy Effects of BDPDH on PET Fabrics. (N,N’-Bis(diphenyl phosphoro)diaminohexane의 합성과 PET 직물에 대한 방염성에 관한 연구)

  • Lee, Kwang-Woo;Heo, Man-Woo;Yoon, Jong-Ho;Lee, Chang-Sub;Cho, Yong-Seok;Kim, Sam-Soo;Cho, Hwan
    • Textile Coloration and Finishing
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    • v.6 no.2
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    • pp.55-62
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    • 1994
  • The mend for fabric products has been increased remarkably with increasing population, housings, mutistory buildings,...and etc. during the last two decades. However, since fabrics are highly combustible and can produce toxic gases during the combution, fabric products can result in serious human injury as well as financial damage. Acknowledged by this, a new phosphorus based flame retardant suitable for PET fabric has been synthesized by making use of the reaction of diphenyl chloro phosphate and hexamethylenediamine. Since the starting meterials are relatively cheap and the yield of this reaction is high (more than 90%), this reaction seems to be very effective as wall as very economic. By analyzing various spectrophotometric analysis data such as NMR, FT-IR, and Mass, this new flame retardant is identified to be N,N’-Bis(diphenyl chlorophosphoro)diamino hexane. In the mean time, DSC measurement has shown that the melting point and the boiling point of this material are around 115$^{\circ}C$ and around 40$0^{\circ}C$, respectively. The flame retardancy test done on the PET fabric processed by this flame retardant have shown excellent in times of flame contact, times of flame contact for washable. The most economical finishing condition estimated 10% in concentration of BDPDH, Moreover, it has been also found that the drape stiffness of the PET fiber processed by the flame retartant is changed very litter compared to the unprocessed original PET fabrics. Judging from this, the potential of this new phosphrdus based compond as a flame retardant for PET fabric seems to be high.

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Study on the Environmental Factor Analysis of Interior Material using Hanji (한지 소재 내장재의 친환경적 요소 분석 연구)

  • Kim, Ji-Soo;Lee, Yu-Ra;Lim, Hyun-A
    • Journal of the Korea Furniture Society
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    • v.22 no.1
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    • pp.63-71
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    • 2011
  • Hanji has known for its high qualities for more than thousand years. Hanji is stronger, and has better durability, air permeability, flexibility, thermal insulation, soundproofs and UV absorbability. Therefore, developing industrial interior finishing materials using Hanji is replaced with the PVC (Poly-Vinyl Chloride) materials instead, it will be a new environment-friendly material and positively represents Korean brand marketing. The industrial inter-construction material is discomposed by heat or light because of material characteristics. As a result, it emits a lot of noxious substances. Hanji is essentially a neutral paper since it does not rely on any acidic chemicals of artificial bleaching methods. Hanji is also known as the living paper because of its close relation to nature. Therefore, I would like to suggest that Hanji made from alternative material as a chicken fiber. It will be a non-polluting interior finishing materials by making use of Hanji to a taste of Korean culture in the green industry around the world. Rather than PVC used commonly in construction material, kitchen and office furniture, interior materials in the subway, trains, or other vessels, credit cards, and ID cards, I created an interior construction material by using patented Hanji. This will be increased the value of usefulness in the environment-friendly green industry instead of PVC.

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Studies on the effect of heating conditions on the quality of soybean flours (대두분 품질에 미치는 가열처리조건에 관한 연구)

  • 이성갑;김준평
    • Journal of the Korean Professional Engineers Association
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    • v.17 no.4
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    • pp.28-39
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    • 1984
  • Experiments were carried out for the development of a processing method of soybean into full-fat or defatted flour, using two varieties of soybean (kwangkyo produced in Korea and Bragg produced in India) Samples were subjected to dry dehulling, size reduction and wet heat treatment processes to make soybean flours. The quality of soybean flours were evaluated, and the results obtained were summarized as follows. 1. Crude fiber content of dehulled soybean was under 3.0% which indicated satisfactory dehulling, and there was no significant difference in crude fibre content between two varieties. 2. When dehulled soybean was cracked into soy grits by a hammer mill, 98.71∼98.86% of the soy grit was in the range of 10∼18 mesh which was the optimum size of particle for quick and uniform penetration of heat into the intra-particle air spaces. 3. Moisture content of soy flour after steam treatment at 15 psig for 5 to 30 min was only 0.29∼1.68% which did not hinder the next milling operation. 4. From the color analysis of soy flours, it was observed that the dominant wavelength for all the samples are in a very narrow range from 575 to 581 nm and the color variation was from yellow to yellowish orange. Twenty to twenty five % higher reflectance was observed in the defatted flours than full fat flours. The % chroma of the defatted flour slightly increased as the duration of steaming of soy grits increased, whereas that of the full-fat flour did not. 5. The protein extractability in the defatted flour at pH 7.6 showed progressive decrease in solubility from 48.40% (Bragg), 75.20% (kwangkyo) for untreated flours to 9.75% (Bragg), 26.27% (kwangkyo) for 30 min steaming. But Kwangkyo variety showed twice higher protein extractability than Bragg variety.

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Algorithm for Discrimination of Brown Rice Kernels Using Machine Vision (기계시각을 이용한 현미의 개체 품위 판별 알고리즘 개발)

  • 노상하;황창선;이종환
    • Journal of Biosystems Engineering
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    • v.22 no.3
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    • pp.295-302
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    • 1997
  • An ultimate purpose of this study was to develop an automatic system for brown rice quality inspection using image processing technique. In this study emphasis was put on developing an algorithm for discriminating the brown rice kernels depending on their external quality with a color image processing system equipped with an adaptor magnifying the input image and optical fiber for oblique lightening. Primarily, geometical and optical features of images were analyzed with paddy and the various brown rice kernel samples such as a sound, cracked, peen-transparent, green-opaque, colored, white-opaque and brokens. Secondary, geometrical and optical parameters significant for identifying each rice kernels were screened by a statistical analysis(STEPWISE and DISCRIM procedure, SAS wer. 6) and an algorithm fur on- line discrimination of the rice kernels in static state were developed, and finally its performance was evaluated. The results are summarized as follows. 1) It was ascertained that the cracked kernels can be detected when e incident angle of the oblique light is less than 2$0^{\circ}C$ but detectivity was significantly affected by the angle between the direction of the oblique light and the longitudinal axis of the rice kernel and also by the location of the embryo with respect to the oblique light. 2) The most significant Parameters which can discriminate brown rice kernels are area, length and R, B and r values among the several geometrical and optical parameters. 3) Discrimination accuracies of the algorithm were ranged from 90% to 96% for a sound, cracked, colored, broken and unhulled, about 81 % for green-transparent and white-opaque and 75 % for green-opaque, respectively.

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The Experimental Analysis of the PVC Foam Cored CFRP Sandwich Composite for the Mixed Mode Delamination Characteristics (복합모드 층간분리특성에 대한 PVC폼 코아 탄소섬유샌드위치 복합재의 실험적 해석)

  • Kwak, Jung Hoon;Yun, Yu Seong;Kwon, Oh Heon
    • Journal of the Korean Society of Safety
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    • v.33 no.2
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    • pp.8-13
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    • 2018
  • The light weight composite materials have been replacing in high performance structures. The object of this study is to examine the effects of the initial crack location about a delamination in a PVC foam cored sandwich composite that is used for the strength improvement of structures. The initial crack location and fiber laminates thickness were changed with several types. The MMB specimen was used for evaluating the fracture toughness and crack behaviors. The material used in the experiment is a commercial twill carbon prepreg in CFRP material and Airex in PVC foam core. Sandwich laminate composites are composed by PVC foam core layer between CFRP face sheets. The face sheets were fabricated as 2 types of 5 and 8 plies. The initial cracks were located in a PVC form core and the interface of upper CFRP sheet. From the results, the crack initiation was affected with the location of the initial crack inserted in the PVC foam core. Among them, the initial crack at 1/3 of the upper part of the PVC foam core was the most rapid progression. And the critical energy release rate was $0.40kJ/m^2$, which is the lowest value when the initial crack was inserted into the interface between a PVC foam core and CFRP laminated with 5 plies. Meanwhile, the highest value of $1.27kJ/m^2$ was obtained when the initial crack was located at the center line in case of the 8 plies.

Fabrication and Characterization of MgO-Al2O3-SiO2-ZrO2 Based Glass Ceramic (MgO-Al2O3-SiO2-ZrO2계 글라스 세라믹의 제조 및 특성 평가)

  • Yoon, Jea-Jung;Chun, Myoung-Pyo;Shin, Hyo Soon;Nahm, San
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.11
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    • pp.712-717
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    • 2014
  • Glass ceramic has a high mechanical strength and low sintering temperature. So, it can be used as a thick film substrate or a high strength insulator. A series of glass ceramic samples based on MgO-$Al_2O_3-SiO_2-ZrO_2$ (MASZ) were prepared by melting at $1,600^{\circ}C$, roll-quenching and heat treatment at various temperatures from $900^{\circ}C$ to $1,400^{\circ}C$. Dependent on the heat treatment temperature used, glass ceramics with different crystal phases were obtained. Their nucleation behavior, microstructure and mechanical properties were investigated with differential thermal analysis (DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM), and Vicker's hardness testing machine. With increasing the heat treatment temperature of MASZ samples, their hardness and toughness initially increase and then reach the maximum points at $1,300^{\circ}C$, and begin to decrease at above this temperature, which is likely to be due to the softening of glass ceramics. As the content of $ZrO_2$ in MAS glass ceramics increases from 7.0 wt.% to 13 wt.%, Vicker's hardness and fracture toughness increase from $853Kg/mm^2$ to $878Kg/mm^2$ and $1.6MPa{\cdot}m^{1/2}$ to $2.4MPa{\cdot}m^{1/2}$ respectively, which seems to be related with the nucleation of elongated phases like fiber.

Study on Buckling of Composite Laminated Cylindrical Shells with Transverse Rib (횡리브로 보강된 복합적층 원통형 쉘의 좌굴거동에 관한 연구)

  • Chang, Suk Yoon
    • Journal of Korean Society of Steel Construction
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    • v.16 no.4 s.71
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    • pp.493-500
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    • 2004
  • In this study, the effects of ring stiffeners for buckling of cylindrical shells with composite materials were analyzed. The finite element method was used: 3-D beam elements were used for stiffeners and flat shell elements were used for cylindrical shells and were improved by introducing a substitute shear strain. The ring stiffeners were of the transverse rib type. The buckling behaviors of the cylindrical shells were analyzed based on various parameters, such as locations and sizes of stiffeners, diameter/length ratios and boundary conditions of shells, and fiber-reinforced angles. Effective reinforcement was examined by understanding the exact behaviors for buckling. The results of the analysis may serve as references for designs and future investigations.

Comparison of Mutagenic Activities of Various Ultra-Fine Particles

  • Park, Chang Gyun;Cho, Hyun Ki;Shin, Han Jae;Park, Ki Hong;Lim, Heung Bin
    • Toxicological Research
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    • v.34 no.2
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    • pp.163-172
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    • 2018
  • Air pollution is increasing, along with consumption of fossil fuels such as coal and diesel gas. Air pollutants are known to be a major cause of respiratory-related illness and death, however, there are few reports on the genotoxic characterization of diverse air pollutants in Korea. In this study, we investigated the mutagenic activity of various particles such as diesel exhaust particles (DEP), combustion of rice straw (RSC), pine stem (PSC), and coal (CC), tunnel dust (TD), and road side dust (RD). Ultra-fine particles (UFPs) were collected by the glass fiber filter pad. Then, we performed a chemical analysis to see each of the component features of each particulate matter. The mutagenicity of various UFPs was determined by the Ames test with four Salmonella typhimurium strains with or without metabolic activation. The optimal concentrations of UFPs were selected based on result of a concentration decision test. Moreover, in order to compare relative mutagenicity among UFPs, we selected and tested DEP as mutation reference. DEP, RSC, and PSC induced concentration-dependent increases in revertant colony numbers with TA98, TA100, and TA1537 strains in the absence and presence of metabolic activation. DEP showed the highest specific activity among the particulate matters. In this study, we conclude that DEP, RSC, PSC, and TD displayed varying degrees of mutagenicity, and these results suggest that the mutagenicity of these air pollutants is associated with the presence of polycyclic aromatic hydrocarbons (PAHs) in these particulate matters.

Optimum Use of Forest Biomass Generated from the National Forest Management Operation (Part 1) - Study of Characteristics of Kraft Pulps Made from Single Wood Species - (숲가꾸기 산물의 최적용도 개발을 위한 연구 (제1보) - 단일 수종으로 제조된 크라프트 펄프의 특성 연구 -)

  • Park, Hyun-Jin;Kim, Chul-Hwan;Lee, Jee-Young;Lee, Gyeong-Sun;Lee, Ji-Young;Sheikh, M.I.;Sim, Sung-Woong;Yim, Su-Jin;Lee, Young-Min;Ahn, Byung-Il
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.63-71
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    • 2012
  • This study was carried out to investigate pulping properties of the forest biomass arising from the national forest management operation. The forest biomass was collected and classified into many groups according to their species and age. After the chips were made from the forest biomass, the measurement of chip size and chemical analysis were performed. To make the pulps from the forest biomass, the kraft pulping was applied and thereafter the physical and optical properties of kraft pulps were measured. The pulp fibers from the forest biomass had the similar mean fiber length, but their properties became different according to wood species and ages. Differently from the other species, kraft pulps from chestnut wood had the highest kappa number. Acacia, paulownia and chestnut woods made kraft pulps with lower tensile strength and brightness than the others. It could be concluded that acacia, paulownia and chestnut woods must be screened out in order to make a good quality of kraft pulps while being collected during Forest Management Operation.