• Title/Summary/Keyword: fiber & film

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Determination of Processing Parameters Affecting the Conversion and Thermal Stability of Photocurable Acrylate-based Binder (아크릴계 광바인더의 전환율과 열안정성 향상을 위한 공정변수 결정)

  • Kim, Byungchul;Seo, Dong Hak;Chae, Heon-Seung;Shin, Seunghan
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.18-22
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    • 2012
  • Photocurable binder for a transparent glass fiber composite was prepared with alicyclic methacrylate and fluorene-based diacrylate. ANOVA (analysis of variance) analysis was used to know main factors affecting the conversion of photocurable binder. It showed radiation intensity and photoinitiator (PI) concentration were main factors. The conversion of photocurable binder was simply increased with radiation intensity. Its increment however was abated with increasing PI concentration. We found that average conversion of the binder measured by FTIR-ATR was 87% when it was exposed to $5J/cm^2$ of UV dose with 5 wt% of PI. Oxime ester type PI was very effective to get a high degree of conversion, but it caused a yellowing problem. Owing to post-baking process, UV cured film showed an improved thermal stability by increase of conversion and removal of volatile organic compounds. TG% at $260^{\circ}C$ of film cured with 5 wt% of PI (TPO+MBF) and $5J/cm^2$ of UV radiation increased from 95.4 to 99.0% by post-baking at $230^{\circ}C$ for 5 min.

Manufacture and Qualification of Composite Main Reflector of High Stable Deployable Antenna for Satellite (위성용 전개형 고안정 반사판 안테나 주반사판 제작 및 검증)

  • Dong-Geon Kim;Hyun-Guk Kim;Dong-Yeon Kim;Kyung-Rae Koo;Ji-min An;O-young Choi
    • Composites Research
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    • v.37 no.3
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    • pp.219-225
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    • 2024
  • It is essential to develop a light-weight, high-performance structure for the deployable reflector antenna, which is the payload of a reconnaissance satellite, considering launch and orbital operation performance. Among them, the composite main reflector is a key component that constitutes a deployable reflector antenna. In particular, the development of a high-performance main reflector is required to acquire high-quality satellite images after agile attitude control maneuvers during satellite missions. To develop main reflector, the initial design of the main reflector was confirmed considering the structural performance according to the laminate stacking design and material properties of the composite main reflector that constitutes the deployable reflector antenna. Based on the initial design, four types of composite main reflectors were manufactured with the variable for manufacturing process. As variables for manufacturing process, the curing process of the composite structure, the application of adhesive film between the carbon fiber composite sheet and the honeycomb core, and the venting path inside the sandwich composite were selected. After manufacture main reflector, weight measurement, non-destructive testing(NDT), surface error measurement, and modal test were performed on the four types of main reflectors produced. By selecting a manufacturing process that does not apply adhesive film and includes venting path, for a composite main reflector with light weight and structural performance, we developed and verified a main reflector that can be applied to the SAR(Synthetic Aperture Rader) satellite.

Histologic Study on the Effect of Two Types of Bovine Bone Powder in Extraction Socket of Beagle Dogs (성견 발치와에 매식한 2종의 Bovine Bone Powder가 치유에 미치는 영향에 관한 조직학적 연구)

  • Park, Tae-Seong;Lim, Sung-Bin;Chung, Chin-Hyung;Kim, Jong-Yeo
    • Journal of Periodontal and Implant Science
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    • v.30 no.3
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    • pp.527-538
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    • 2000
  • Several extraction cases with advanced bone loss as a result of periodontal disease, root or labial bone fracture, extensive caries, and periapical lesions occur esthetic, functional problems and severe bone loss. Therefore, to treat these cases used several surgical methods and socket preservation among this therapies have been evaluated simple, effective and good prognosis in the implant placement. Socket preservation therapy have been used with barrier membranes or/and graft materials. Deproteinized bovine bone mineral have been evaluated ideal grafting materials. Recently, calcium-phosphate thin film coated bovine bone powders were developed in our country, but the study for these material wasn't reported. When two types of xenograft materials were implanted in extraction sockets of Beagle dogs, the effects of these were analyzed after 4 weeks and 8 weeks histological views. The results of this study were as follows. 1. In control groups, 4 weeks after implantation, the extraction sockets were filled with connective tissue which has dilated vessels and epithelial growth. And after 8 weeks, irregular connective bundles were observed. But new bone formation was not seen. 2. In Bio-Oss groups, epithelial growth was not seen and bone powder was covered with connective tissue fiber. New bone formation was found around the interproximal bone. There was no special change seen after 8 weeks, connective tissue fibers became more regular, and bone growth near bone powder was not made well. 3. In Ca-P BBP groups, epithelial cells didn't grow in the extraction sockets, there was a lot of new bone made around the bone powder after 8 weeks, new bone around bone powder was replaced with mature bone. It is thought that bone powder grafting into the extraction sockets is very useful for conservation of ridge, and Ca-P BBP is more effective in bone formation than Bio-Oss.

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QUICK DETERMINATION OF MEAT COLOR, METMYOGLOBIN FORMATION AND LIPID OXIDATION IN BEEF, PORK AND CHICKEN BY NEAR-INFRARED SPECTROSCOPY

  • Mitsumoto, Mitsuru;Sasaki, Keisuke;Murakami, Hitoshi
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1259-1259
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    • 2001
  • Meat becomes brown and rancid during storage in the refrigerator and display in the case. Color changes, metmyoglobin formation and lipid oxidation are the important problems in the transportation / distribution of meat and retail display. The freshness of meat is determined by the sense of vision and smell. Since conventional method determining lipid oxidation is time consuming and destructive (it needs to homogenize meat with reagents, filtrate, time for reaction and read optical density using spectroscopy), more rapid and nondestructive technical tools are desired. The objective of this work was to evaluate near-infrared spectroscopy as an analytical tool for determining meat color, metmyoglobin formation and lipid oxidation. in beef, pork and chicken. Semitendinosus and longissimus thoracis muscles from six beef steers, biceps femoris and longissimus thoracis muscles from twelve LWD crossbred pigs, and superficial pectoral muscles from twenty-four broilers were used. About a 5-cm diameter and 1-cm thick sample (20.0g) was cut from the muscle and placed on plastic foam, over-wrapped with PVC film, and displayed under flourescent lights at 4 degrees C. during 10 days for beef and pork or 4 days for chicken. The spectra was measured by NIR systems Model 5500 Spectrophotometer using fiber optic scan at range of 400 - 1100 nm. Data were recorded at 2 nm intervals and 10 scans / 10 sec were averaged for every sample. Data obtained were saved as log 1/Re, where Re is the reflectance energy, and then mathematically transformed to second derivatives to reduce effects of differences in particle size. $L^{*}$, $a^{*}$ and $b^{*}$, and metmyoglobin formation were determined by conventional spectrophotometer using the integrating sphere unit. 2-Thiobarbituric acid reactive substances (TBARS) were measured for lipid oxidation. A multiple linear regression was used to find the equation which would best fit the data. The number of wavelengths used in the equation was selected based on the fewer number compared to the increasing multiple correlation and Decreasing standard error. (omitted)

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Study for Biodegradability of Cellulose Derived from Styela clava tunics (미더덕껍질 셀룰로오스의 매립 생분해성에 대한 연구)

  • Seong, Keum-Yong;Lee, Seunghyun;Yim, Sang-Gu;Son, Hong Joo;Lee, Young-Hee;Hwang, Dae Youn;Jung, Young Jin
    • Textile Coloration and Finishing
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    • v.27 no.2
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    • pp.149-154
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    • 2015
  • To investigate the biodegradation of the cellulose powder(CP) derived from Styela clava tunics(SCT), some physico-chemical properties and biodegradability of SCT-CP were measured after the incubation for 45 days. The particles size of SCT-CP prepared with washing, bleaching, drying, and grinding processes was $150-400{\mu}m$ although most of particles (70%) was more than $400{\mu}m$. The cellulose structures of SCT-CP detected using the X-ray diffraction and DSC analysis was very similar with that of wood pulp powder(WP-CP). The glass transition temperature was not detected in both samples. Furthermore, more than 90% of the SCT-CP was degraded, whereas only over 70% of the WP-CP was degraded after the incubation for 45 days. Therefore, these results suggest the possibility that SCT-CP is particularly applicable to prepare medical fiber and film for disease treatment.

Numerical Simulation of the Delamination Behavior of Polymeric Adhesive Tapes Using Cohesive Zone Element (응집 영역 요소를 이용한 고분자 접착 테이프의 박리거동 모사)

  • Jang, Jinhyeok;Sung, Minchang;Yu, Woong-Ryeol
    • Composites Research
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    • v.29 no.4
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    • pp.203-208
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    • 2016
  • Metal and polymer sandwich composites, which are made of sheet metal sheath and polymer or fiber reinforced plastic core, have been reconsidered as an alternative to sheet metal due to their lightness and multifunctional properties such as damping and sound-proof properties. For the successful applications of these composites, the delamination prediction based on the adhesion strength is important element. In this study, the numerical simulation of the delamination behavior of polymeric adhesive tapes with metallic surfaces was performed using cohesive zone elements and finite element software. The traction-separation law of the cohesive zone element was defined using the fracture energy derived from peel mechanics and experimental results from peel test and implemented in finite element software. The peel test of the polymeric adhesive film against steel surface was simulated and compared with experiments, demonstrating reasonable agreement between simulation and experiment.

Efficiency of Retarding Reflection Crack in Reinforced-and-Modified Asphalt Pavement Overlay (개질재.보강재를 이용한 덧씌우기 아스팔트 포장의 반사균열 지연 효과)

  • Kim, Kwang-Woo;Doh, Young-Soo;Lim, Sung-Bin;Rhee, Suk-Keun;Eum, Joo-Yong
    • International Journal of Highway Engineering
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    • v.1 no.1
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    • pp.85-96
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    • 1999
  • This study was performed to evaluate performance of polymer-modified asphalt mixtures and specially designed reinforcement techniques against reflection cracking of the asphalt pavement overlay. Selected polymers were used for asphalt modification and polyester fiber, a polypropylene film (vinyl) and a grid were used for mixture reinforcement. Using the asphalt mixture with optimum asphalt content, a slab was made and cut into two pieces of specimen. A layer of grid or vinyl was placed at the bottom of specimen to strengthen the pavement layer against crack. A repeated loading was applied to the asphalt mixture specimen which is Placed on a cement concrete with a pseudo-crack. Crack propagation under repeated loading was monitored and effectiveness of the devised crack retarding techniques was evaluated. From the test results. a significant retardation of mode I crack progress was monitored from some of the modified and reinforced asphalt mixtures.

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Miniature Jumping Robot Using SMA Coil Actuators and Composite Materials (형상기억합금 코일 구동기와 복합재를 이용한 소형 도약 로봇 설계 및 제작)

  • Jung, Sun-Pill;Koh, Je-Sung;Jung, Gwang-Pil;Cho, Kyu-Jin
    • The Journal of Korea Robotics Society
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    • v.8 no.2
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    • pp.136-142
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    • 2013
  • In nature, many small insects are using jumping as a survival strategy. Among them, fleas jump in a unique method. They use an elastomer, 'Resilin', an extensor muscle and a trigger muscle. By contracting the extensor muscle, the elastic energy, that makes a flea to jump, is stored in the resilin. After storing energy, the trigger muscle begins contracting and pulling the extensor muscle. When the extensor muscle crosses the rotational joint, direction of torque generated from the extensor muscle reverses, 'torque reversal mechanism'. Simultaneously, the elastic energy stored in the resilin releases rapidly and is converted into the kinetic energy. It makes a flea to jump 150 times its body length. In this paper, miniaturized jumping robot using flea-inspired catapult mechanism is presented. This mechanism is based on the 4-bar linkage and the reversal joint and is actuated by Shape Memory Alloy (SMA) coiled springs describing the flea's muscle. The robot prototype is fabricated by SCM process using glass fiber prepregs and a sheet of polyimide film. The prototype is 20mm link length, 34mm width and 2.0g weight and can jump 103cm.

Acrylic Acid-Grafted Hydrophilic Electrospun Nanofibrous Poly(L-lactic acid) Scaffold

  • Park, Kwi-Deok;Jung, Hyun-Jung;Kim, Jae-Jin;Ahn, Kwang-Duk;Han, Dong-Keun;Ju, Young-Min
    • Macromolecular Research
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    • v.14 no.5
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    • pp.552-558
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    • 2006
  • Biodegradable nanofibrous poly(L-lactic acid) (PLLA) scaffold was prepared by an electrospinning process for use in tissue regeneration. The nanofiber scaffold was treated with oxygen plasma and then simultaneously in situ grafted with hydrophilic acrylic acid (AA) to obtain PLLA-g-PAA. The fiber diameter, pore size, and porosity of the electrospun nanofibrous PLLA scaffold were estimated as $250\sim750nm,\;\sim30{\mu}m$, and 95%, respectively. The ultimate tensile strength was 1.7 MPa and the percent elongation at break was 120%. Although the physical and mechanical properties of the PLLA-g-PAA scaffold were comparable to those of the PLLA control, a significantly lower contact angle and significantly higher ratio of oxygen to carbon were notable on the PLLA-g-PAA surface. After the fibroblasts were cultured for up to 6 days, cell adhesion and proliferation were much improved on the nanofibrous PLLA-g-PAA scaffold than on either PLLA film or unmodified nanofibrous PLLA scaffold. The present work demonstrated that the applications of plasma treatment and hydrophilic AA grafting were effective to modify the surface of electrospun nanofibrous polymer scaffolds and that the altered surface characteristics significantly improved cell adhesion and proliferation.

Packaging Substrate Bending Prediction due to Residual Stress (잔류응력으로 인한 패키지 기판 굽힘 변형량 예측)

  • Kim, Cheolgyu;Choi, Hyeseon;Kim, Minsung;Kim, Taek-Soo
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.1
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    • pp.21-26
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    • 2013
  • This study presents new analysis method to predict bending behavior of packaging substrate structure by comparing finite element method simulation and measured curvature using 3D scanner. Packaging substrate is easily bent and deflected while undergoing various processes such as curing of prepreg and copper pattern plating. We prepare specimens with various conditions and measure contours of each specimen and compute the residual stresses on deposited films using analytical solution to find the principle of bending. Core and prepreg in packaging substrate are made up of resin and bundles of fiber which exist orthogonally each other. Anisotropic material properties cause peculiar bending behavior of packaging substrate. We simulate the bending deflection with finite element method and verify the simulated deflection with measured data. The plating stress of electrodeposited copper is about 58 MPa. The curing stresses of solder resist and prepreg are about 13 MPa and 6.4 MPa respectively in room temperature.