• Title/Summary/Keyword: fast ion

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음이온교환막 연료전지 응용을 위한 UV 중합법을 이용한 세공 충진 음이온교환막 개발 (Development of Pore Filled Anion Exchange Membrane Using UV Polymerization Method for Anion Exchange Membrane Fuel Cell Application)

  • 곽가진;김도형;남상용
    • 멤브레인
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    • 제33권2호
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    • pp.77-86
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    • 2023
  • 본 연구에서는 낮은 막 저항과 높은 수산화 이온 전도성을 가지는 세공 충진 이온교환막 제조법으로 연구하였다. 알칼리 내구성을 향상하기 위해 폴리 테트라 플로오 에틸렌 소재인 다공성 지지체를 사용하였고 세공에는 단량체 2-(dimethylamino)ethyl methacrylate (DMAEMA), vinylbenzyl chloride (VBC)를 이용하여 copolymer를 제조했다. 가교제는 divinylbenzene (DVB)를 사용하였고 가교제 함량별로 이온교환막을 제조하여 DMAEMA-DVB와 VBC-DMAEMA-DVB copolymer에서 가교제 함량이 미치는 영향에 관해 연구하였다. 그 결과, PTFE 소재 지지체를 이용하여 화학적 안정성이 향상했고 저압 UV 램프를 사용하여 낮은 온도에서 빠른 광중합이 가능하여 생산성을 높일 수 있는 장점이 있다. 음이온교환 막 연료전지에 요구되는 이온교환막의 물리적 및 화학적 안정성을 확인하기 위해서 인장강도와 내알칼리성 테스트를 진행하였다. 그 결과, 가교도가 증가할수록 인장강도 대략 40 MPa가 증가하였고, 최종적으로 이온전도도와 내알칼리성 테스트를 통해 가교제 함량이 증가할수록 알칼리 안정성이 증가하는 것을 확인하였다.

고 탄소 미세 강선의 기계적 특성에 미치는 잔류 응력과 표면 결함의 영향 (Effects of Residual Stress and Surface Defect on the Mechanical Properties of the High Carbon Steel Filaments)

  • 양요셉;배종구;박찬경
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 추계학술대회 논문집
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    • pp.134-137
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    • 2008
  • The effects of residual stress and surface defects on the mechanical properties of the high carbon steel filament used for the automotive tire have been experimentally investigated. The samples were fabricated with annealing temperature. The residual stress was measured by focused ion beam and strain mapping software which has advantages, such as data with high accuracy and fast data acquisition time. Mechanical properties, such as tensile strength and fatigue resistance, were gradually increased up to $200^{\circ}C$ and then slightly decreased. From the measurement of residual stress and level of surface defect, it was revealed that the critical factor was varied with different temperature region. That is, the fatigue resistance increased due to decreasing the residual stress and decreased due to increasing the size and distribution of surface defect.

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영전압/영전류 스위칭을 이용한 고효율의 직렬 접속 배터리 전압 밸런싱 방법 (A High Efficiency Zero Voltage/Zero Current Transition Converter for Series Connected Battery Cell Equalization)

  • 김태훈;박남주;현동석;김래영
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2011년도 추계학술대회
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    • pp.26-27
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    • 2011
  • This paper focuses on the zero-voltage/zero current transition voltage equalization circuit for the series connected battery cell. By adding auxiliary resonant cells at the main switching devices such as MOSFET or IGBT, zero current switching is achieved and turned off loss of switching elements is eliminated and by the voltage/second balancing of the inductor, zero voltage switching can be applied to switching element. Transformer coupling between battery cells and ZVZCT (Zero Voltage Zero Current Transition) switching method allow the fast balancing speed and high frequency operation, which reduces the size and weight of the circuit. The validity of the battery equalization is further verified using simulation involving four lithium-ion battery cell models.

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액적의 속도 측정을 위한 이색 PIV 알고리즘 연구 (The Study on Two-color PIV Algorithm for a Measurement of Droplet Velocity)

  • 이기형;이창식;오승익
    • 한국분무공학회지
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    • 제4권1호
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    • pp.13-18
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    • 1999
  • It has been known that spray characteristics have an important effect on the mixture formation and directly influence the engine performances and the emissions. Up to now, the measurement of droplet size is well developed such as PDPA and PMAS though the behavior of small droplets during secondary atomization is not clear. Particle image velocimetry(PIV), a planar measuring technique, is a very efficient tool for studying complicated behavior and a fast and reliable method to track numerous droplets during injection. In this study, two-color scanning PIV is designed to obtain quasi-instantaneous two dimensional velocity data by using he-ion laser, rotating mirror and beam splitter. This PIV method which has high temporal and spatial resolution provides the information about the small complex droplet behavior.

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유선형스텝에 의해 안정화된 예혼합 화염의 구조와 연소특성에 관한 연구(I) (A Study of Flams Structure and Combustion Characteristics in a Premixed Flame Stabilized by a Stramlined Step(I))

  • 이재득;최병륜
    • 오토저널
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    • 제12권3호
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    • pp.63-70
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    • 1990
  • In a premixed flame stabilized by a streamlined step, the flame structure and combustion characteristics were investigated to identify the effect of the pressure pulsation in a combustion air. A flame stabilizing limits, visualization, mean temperature, ion current and gas concentration (O$_{2}$, CO$_{2}$, CO, UHC) were measured. With the combustion air of higher pressure pulsation, the development of the mixing layer was fast and wide, the temperature and combustion intensity were higher at arbitrary section. But, the effect was notably decreased with X=150 mm downstream. And a first eddy formation from step edge was earlier. Thus, with the combustion air of higher pressure pulsation, high rate of heat generation was expected.

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IPMC의 동적 특성 (Dynamic Characteristics of Ionic-Polymer-Metal-Composite)

  • 전진한;신동군;이관호;오일권
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2005년도 춘계학술대회논문집
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    • pp.356-359
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    • 2005
  • Ionic-polymer-metal-composite(IPMC), one of new actuation materials of electroactive polymers plated with noble metallic electrodes is known for the fast bending upon electric field. The IPMC strip bends towards anode under electrical field. It has many merits of low driving voltage, quick responsiveness, high durability, possibility of miniaturizability. In this paper, we studied for developing the large deflection of IPMC according several fabricating parameters. We measured the large deflection by the different process of sandpaper and sandblasting in surface treatment, the initial compositing process and the surface electroding process, and the different counter ions in ion exchanging process. In fundamental, the displacement of IPMC strip depends on voltage magnitude and applied signal frequency and its maximum deformation is observed at a critical frequency, resonant frequency.

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엑시머 레이져를 이용한 극히 얕은 접합과 소스, 드레인의 형성과 50nm 이하의 극미세 n-MOSFET의 제작 (Ultra Shallow Junction wish Source/Drain Fabricated by Excimer Laser Annealing and realized sub-50nm n-MOSFET)

  • 정은식;배지철;이용재
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.562-565
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    • 2001
  • In this paper, novel device structures in order to realize ultra fast and ultra small silicon devices are investigated using ultra-high vacuum chemical vapor deposition(UHVCVD) and Excimer Laser Annealing (ELA). Based on these fundamental technologies for the deep sub-micron device, high speed and low power devices can be fabricated. These junction formation technologies based on damage-free process for replacing of low energy ion implantation involve solid phase diffusion and vapor phase diffusion. As a result, ultra shallow junction depths by ELA are analyzed to 10~20nm for arsenic dosage(2${\times}$10$\_$14//$\textrm{cm}^2$), exciter laser source(λ=248nm) is KrF, and sheet resistances are measured to 1k$\Omega$/$\square$ at junction depth of 15nm and realized sub-50nm n-MOSFET.

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3차원 나노구조화 기술을 이용한 고성능 기능성 세라믹 연구개발 동향 (Recent Advances in High-performance Functional Ceramics using 3D Nanostructuring Techniques)

  • 안창의;박준용;전석우
    • 세라미스트
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    • 제22권3호
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    • pp.230-242
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    • 2019
  • Functional ceramics are widely utilized in a variety of application fields such as structural materials, sensors, energy devices, purification filter and etc due to their high strength, stability and chemical activity. With the breakthrough development of nanotechnology, many researchers have studied new types of nanomaterials including nanoparticle, nanorod, nanowire and nanoplate to realize high-performance ceramics. Especially several groups have focused on the 3D nanostructured ceramics because of their large surface area, efficient load transfer, ultra-fast ion diffusion and superior electrical (or thermal) conductivity. In this review, we introduce the reported fabrication strategies of the 3D nanostructured and functional ceramics, also summarized the 3D nanostructured ceramic based high-performance applications containing photocatalysts, structural materials, energy harvesting and storage devices.

Mössbauer Study of the Dynamics in BaFe12O19 Single Crystals

  • Choi, J.W.;Sur, J.C.;Lim, Jung-Tae;Kim, Chin-Mo;Kim, Chul-Sung
    • Journal of Magnetics
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    • 제17권1호
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    • pp.6-8
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    • 2012
  • M$\ddot{o}$ssbauer spectra of hexagonal $BaFe_{12}O_{19}$ single crystals were studied at various temperatures (4-300 K). It was found that the spin states in Fe atoms were parallel to the ${\gamma}$-ray's direction into a single crystal along the caxis. The location of the Fe ion in the 2b site is unusual in an oxide structure and has strong anisotropic lattice vibrations. Moreover, at room temperature, the zero absorption lines of the Fe ions at the 2b site were observed due to fast diffusion motion in a double well atomic potential. The two Fe ions of the single crystal mainly enter into the sites in the mirror plane of the trigonalbipyramidal structure.

웨이브렛 변환을 이용한 전자빔 용접 진단 (Electron Beam Welding Diagnosis Using Wavelet Transform)

  • 윤충섭
    • Journal of Welding and Joining
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    • 제21권6호
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    • pp.33-39
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    • 2003
  • Wavelet transform analysis results show a spectrum energy distribution of CWT along scale factors distinguish the partial, full and over penetration in a electron beam welding by analyzing the curve of spectrum energy at small scale, middle and large scale range, respectively. Two types of signals collected by Ion collector and x-ray sensors and analyzed. The acquired signals from sensors are very complicated since these signals are very closely related the dynamics of keyhole which interact the very high density energy with materials during welding. The results show the wavelet transform is more effective to diagnosis than Fourier Transform, further for the general welding defects which are not a periodic based, but a transient, non-stationary and time-varying phenomena.