• 한국안전학회지
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• 제16권4호
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• pp.109-114
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• 2001

Explosive characteristics of the city gas were determined by using the gas explosion apparatues. The explosive range is determined between lower explosive limit of 5.0% and upper explosive limit of 15.3% at atmosphere and even though the oxygen concentration is decreased, lower explosive limit is not changed, but upper explosive limit is rapidly decreased. The minimum oxygen for combustion is determined 10%. The maximum explosion pressure is determined 5.72$\textrm{cm}^2$ and the maximum rate of explosion pressure rise is oxygen concentration of 12% to determined 160.12$\textrm{cm}^2{\cdot}$sec.

• Korean Chemical Engineering Research
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• 제58권3호
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• pp.493-497
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• 2020

Hazardous area classification is designed to prevent chemical plant explosions in advance. Generally, the duration of the explosive atmosphere is used for zone type classification. Herein, IEC code, a quantitative zone type classification methodology, was used to achieve Zone 2 NE, which indicates a practical non-explosion condition. This study analyzed the operating pressure of a vessel handling propane to achieve Zone 2 NE by applying the IEC code via MATLAB. The resulting zone type and hazardous area grades were compared with the results from other design standards, namely API and EI codes. According to the IEC code, the operating pressure of vessels handling propane should be between 101325-116560.59 Pa. In contrast, the zone type classification criteria used by API and EI codes are abstract. Therefore, since these codes could interpret excessively explosive atmospheres, care is required while using them for hazardous area classification design.

• 한국가스학회지
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• 제20권3호
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• pp.30-37
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• 2016

내압 방폭전기기계 기구는 인화성 가스가 존재하는 위험장소에서 사용되어도 인화성 가스의 점화원이 되지 않는 구조로 이루어져야 한다. 또한 전기 스파크를 발생시키는 부품이 점화원이 되어 기계 기구 내부에서 폭발 시 최대 압력에 견디고 내부 화염이 외부로 전파되어 가스나 증기 폭발을 일으키지 않도록 설계되어야 한다. 본 연구에서는 화염 틈새를 통해 외부로 분사되는 연소 생성물의 분사가 외부 가스나 증기를 점화시킬 정도의 온도나 에너지를 가질 수 없도록 하는 MESG(Maximum Experimental Safe Gap)의 중요한 물리적인 메커니즘에 대해 규명하였다. IEC 60079-20-1:2010 기준에 의해 프로판- 아세틸렌-공기로 이루어진 3성분계 혼합가스의 MESG를 실험하여 MESG 값을 측정하고 가스 폭발시의 최대 폭발압력을 측정하였다. 결과로는 아세틸렌 가스 보다는 폭발력이 낮은 프로판 가스의 조성이 MESG 값과 폭발압력에 더욱 큰 변수로 작용함을 알 수 있었다.

• 방재기술
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• 통권15호
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• pp.22-27
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• 1993

The classification of hazardous area is a method of analysing and classifying the environment where explosive gas or vapour atmosphere may be expected to be present. The object of area classification is to enable the proper selection and installation of electical apparatus and other equipments. This report is intended to serve a general reference about the classification procedure of hazardous area with explanations of related Korean Standard.

• 한국가스학회지
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• 제20권1호
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• pp.29-39
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• 2016

폭발성 가스가 존재하는 위험장소에서 사용하는 전기기기는 폭발성 가스의 점화원이 되지 않도록 설계되어야 한다. 내압방폭 구조의 설계는 전기 스파크를 발생시키는 부품을 가진 용기가 내부에서 가스나 증기의 폭발시 최대 압력에 견디고 내부 화염이 외부 가스나 증기 폭발로 전파되지 않도록 설계되어야 한다. 이 논문은 화염 틈새를 통해 외부로 분사되는 연소 생성물의 분사가 외부 가스나 증기를 점화시킬 정도의 온도나 에너지를 가질 수 없도록 하는 MESG(Maximum Experimental Safe Gap)의 중요한 물리적인 메커니즘에 대해 설명하였다. IEC 60079-20-1:2010 기준에 의해 프로판과 아세틸렌의 MESG를 실험하여 MESG 값을 측정하고 가스폭발시의 최대 폭발압력을 측정하였다. 결과로는 최소 MESG가 측정될 때 가스의 농도는 화학당량 농도보다 높고 폭발압력은 최소 MESG에서 가장 높게 나타났다.

• Journal of Advanced Marine Engineering and Technology
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• 제28권6호
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• pp.938-945
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• 2004

Intrinsic safety is generally considered the safest method of operating electrical instrumention in potentially explosive atmospheres. The method of intrinsic safety limits the energy passing into the hazardus area. The energy limitation is provided by the use of safety barriers which are mounted in the safe area. Because of the energy limitation, regardless of the fault in the hazardous area, sufficient energy cannot be released to ignite the explosive atmosphere. The following industries are known to have hazardous locations: chemical. munitions, petrochemical, auto(paint spray booths), grain, waste water, printing, distillers, pharmaceutical. breweries, cosmetics, and utilities. In this paper, a isolator type barrier for ship(LNG, LPG, etc,) and test equipment confidence are proposed. The test equipments are designed for mechanical electrical life time test and vibration. All of test results satisfy the goal and the studied barrier shows the improved confidence.

• Safety and Health at Work
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• 제6권1호
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• pp.18-24
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• 2015

Background: In 2006, three farmers died at the bottom of an agricultural shallow well where the atmosphere contained only 6% oxygen. This study aimed to document the variability of levels of oxygen and selected hazardous gases in the atmosphere of wells, and to identify ambient conditions associated with the low-oxygen situation. Methods: A cross-sectional survey, conducted in June 2007 and July 2007, measured the levels of oxygen, carbon monoxide, hydrogen sulfide, and explosive gas (percentage of lower explosive limit) at different depths of the atmosphere inside 253 wells in Kamphaengphet and Phitsanulok provinces. Ambient conditions and well use by farmers were recorded. Carbon dioxide was measured in a subset of wells. Variables independently associated with low-oxygen condition (<19.5%) were identified using multivariate logistic regression. Results: One in five agricultural shallow wells had a low-oxygen status, with oxygen concentration decreasing with increasing depth within the well. The deepest-depth oxygen reading ranged from 0.0% to 20.9%. Low levels of other hazardous gases were detected in a small number of wells. The low-oxygen status was independently associated with the depth of the atmosphere column to the water surface [odds ratio (OR) = 13.5 for 8-11 m vs. <6 m], depth of water (OR = 0.17 for 3-<8 m vs. 0-1 m), well cover (OR = 3.95), time elapsed since the last rainfall (OR = 7.44 for >2 days vs. <1 day), and location of well in sandy soil (OR = 3.72). Among 11 wells tested, carbon dioxide was detected in high concentration (>25,000 ppm) in seven wells with a low oxygen level. Conclusion: Oxygen concentrations in the wells vary widely even within a small area and decrease with increasing depth.

• 센서학회지
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• 제29권6호
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• pp.382-387
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• 2020

Hydrogen (H₂) is considered as a new clean energy resource for replacing petroleum because it produces only H₂O after the combustion process. However, owing to its explosive nature, it is extremely important to detect H₂ gas in the ambient atmosphere. This has triggered the development of H₂ gas sensors. 2-dimensional (2D) graphene has emerged as one of the most promising candidates for chemical sensors in various industries. In particular, graphene exhibits outstanding potential in chemoresistive gas sensors for the detection of diverse harmful gases and the control of indoor air quality. Graphene-based chemoresistive gas sensors have attracted tremendous attention owing to their promising properties such as room temperature operation, effective gas adsorption, and high flexibility and transparency. Pristine graphene exhibits good sensitivity to NO₂ gas at room temperature and relatively low sensitivity to H₂ gas. Thus, research to control the selectivity of graphene gas sensors and improve the sensitivity to H₂ gas has been performed. Noble metal decoration and metal oxide decoration on the surface of graphene are the most favored approaches for effectively controlling the selectivity of graphene gas sensors. Herein, we introduce several strategies that enhance the sensitivity of graphene gas sensors to H₂ gas.

• 대한기계학회논문집B
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• 제32권11호
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• pp.832-840
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• 2008

Ablation occurs at irradiance beyond $10^9\;W/cm^2$ with nanosecond and short laser pulses focused onto any materials. Phenomenologically, the surface temperature is instantaneously heated past its vaporization temperature. Before the surface layer is able to vaporize, underlying material will reach its vaporization temperature. Temperature and pressure of the underlying material are raised beyond their critical values, causing the surface to explode. The pressure over the irradiated surface from the recoil of vaporized material can be as high as $10^5\;MPa$. The interaction of high power nanosecond laser with a thin metal in air has been investigated. The nanosecond pulse laser beam in atmosphere generates intensive explosions of the materials. The explosive ejection of materials make the surrounding gas compressed, which form a shock wave that travels at several thousand meters per second. To understand the laser ablation mechanism including the heating and ionization of the metal after lasing, the temporal evolution of shock waves is captured on an ICCD camera through laser flash shadowgraphy. The expansion of shock wave in atmosphere was found to agree with the Sedov's self-similar spherical blast wave solution.

• 대한안전경영과학회지
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• 제19권3호
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• pp.1-9
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• 2017

In the industrial field, various type of fuel have been used for product processing facilities. Recent for 10 years, the usage of natural gas (NG) was gradually increased. Because it has many merits; clean fuel, no transportation, storage facility and so on. There are common safety concept that strict explosion protection approaches are needed for facilities where explosive materials such as flammable liquid, vapor and gases exist. But some has an optimistic point of view that the lighter than air gases such as NG disperse rapidly, hence do not form explosion environment upon release into the atmosphere, many parts has a conventional safety point of view that those gases are also inflammable gases, hence can form explosion environment although the extent is limited and present. In this paper, the heating equipments (Hot Oil Heater) was reviewed and some risk management measures were proposed. These measures include hazardous area classification and explosion-proof provisions of electric apparatus, an early gas leak detection and isolation, ventilation system reliability, emergency response plan and training and so on. This study calculates Hazardous Area Classification using the hypothetical volume in the KS C IEC code.