• Korean Journal of Metals and Materials
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• v.56 no.11
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• pp.829-834
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• 2018

Although magnesium-based alloys are attractive materials for hydrogen storage applications, their activation properties, hydrogenation/dehydrogenation kinetics, thermodynamic equilibrium parameters, and degradation characteristics must be improved for practical applications. Further, magnesium poses several risks, including explosion hazard, environmental pollution, insufficient formability, and industrial damage. To overcome these problems, CaO-added Mg alloys, also called Eco-Mg (environment-conscious Mg) alloys, have been developed. In this study, $Eco-MgH_x$ composites were fabricated from Mg-CaO chips by hydrogen-induced mechanical alloying in a high-pressure atmosphere. The balls-to-chips mass ratio (BCR) was varied between a low and high value. The particles obtained were characterized by X-ray diffraction (XRD), and the absorbed hydrogen was quantified by thermogravimetric analysis. The XRD results revealed that the $MgH_2$ peaks broadened for the high BCR. Further, PSA results revealed particles size were decreased from $52{\mu}m$ to $15{\mu}m$.

• Journal of the Korean Society of Safety
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• v.34 no.2
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• pp.28-33
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• 2019

After the Tianjin Port explosion on 2015, it is highlighted that securing safety for dangerous goods in Korea and try to establish safety standards for railroad dangerous substances transport. In Korea, the regulation for the transport of dangerous goods is stipulated to need 3 buffer cars. However, It is inefficient that 3 buffer cars. because 3 buffer cars, increase transportation too much costs in transit and it is too strict compared to other country rules. The purpose of this study was to improve transportation efficiency by mitigating the criteria for isolated railroads through rational safety assessment. In order to verify this, we used a risk assessment software which is PHAST 7.2 developed by DNV GL. We calculated safety distances that could prevent ignitions setting up scenarios when relief system work installed on a train loaded with propylene, nonane. As a result, we confirmed that buffer cars can be reduced from three to one. This result would be implemented in the application of Korail.

• Journal of the Korean Society of Safety
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• v.38 no.4
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• pp.23-31
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• 2023

Revising the Occupational Safety and Health Act led to enacting and revising related laws and systems, such as placing fire observers in hot workplaces. However, the operating standards in such cases are still ambiguous. Although fire accidents occur through multiple and multi-step factors, the hazards of fire accidents have been identified in this study as individual rather than interrelated factors. The aim has been to identify multiple factors of accidents, outlining fire and explosion accidents that recently occurred in the domestic manufacturing industry. First, major keywords were extracted through text mining. Then representative accident types were derived by combining the main keywords through the co-word network analysis to identify the hazards and their relationships. The representative fire accidents were identified as six types, and their major hazards were then addressed for improving safety measures using the identification of hazards in the "Risk Assessment" tool. It is found that various safety measures, such as professional fire observers' training and clear placement standards, are needed. This study will provide useful basic data for revising practical laws and guidelines for fire accident prevention, system supplementation, safety policy establishment, and future related research.

• Fire Science and Engineering
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• v.15 no.1
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• pp.16-22
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• 2001

Thermal properties of PP and LLDPE dusts from chemical plant and their risks of coexisting with oxidizer were investigated by a pressure vessel. The thermal decomposition of PP and LLDPE dusts with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of PP and LLDPE dusts. Using the pressure vessel which can estimate ignition and explosion of PP and LLDPE dusts coexisting with oxidizer, a series of bursting of a rupture disc, experiments has been conducted by varying the orifice diameters the weight ratio of the sample coexisting with oxidizers and the species of oxidizer. And fire gases was measured by gas analyser ($ECOM-A^+$). According to the results of the thermal analysis of PP and LLDPE dusts, the decomposition temperature range of PP and LLDPE dusts was 200 to 350 and 300 to $500^{\circ}c$, respectively. The risk of PP and LLDPE dusts coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the weight ratio of the sample to the oxidizer were increased. In addition, the risk of PP and LLDPE dusts coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer. It is found that the risk of fire becomes high when the decomposition temperature of the sample is about same as that of oxidizer. Also, the fire gases was occurred carbon monoxide and carbon dioxide. The amount of carbon monoxide generated was found to be much higher in PP decomposition than in LLDPE due to incomplete combustion of PP which has high content of carbon in chemical compound.

• Journal of the Korean Institute of Gas
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• v.7 no.2 s.19
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• pp.33-41
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• 2003

There exists high hazard when transporting LPG as well as using, storing, and producing. For small scale LPG consumer, retailers deliver LPG to customers via a truck loading many LPG cylinders. Suppose there occurred a accident during LPG cylinder transfer, this could result in serious damages to the life and properties in the near or neighbor of the accident spot. In this regard, we made a quantitative risk analysis to estimate the possible damages and the probability through the identification of accidents causes and the simulation of the possible scenario. In this study, we made the Excel & Visual Basic computer program to perform quantitative LPG accident analysis. The simulation showed the following results. In case of UVCE(Unconfined Vapor Cloud Explosion), the effect within l0m of the accident spot showed very severe structural damages and even the accident can break the window glasses of the area of 150 m apart from accident spot. In case of TNT corresponding probit analysis, after 10 minutes LPG leaking, $75\%$ window glasses of 40 m distance was expected to be broken. And $16\%$ frames of 20m distance, $10\%$ frames of 40m distance was expected to be collapsed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.4
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• pp.332-339
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• 2016

This study examined the intensity of the association of factors affecting major burns by statistical analysis for patients injured by the release of chemical hazards. A total of 446 patients were evaluated as chemical injury patients, who had visited the emergency room from 1/Jan/2010 to 31/Dec/2014. The major burn was used as a dependent variable representing the severity of chemical injury. A chi-square test (CST) and binary logistic regression test (BLRA) were used as the statistical analysis method for determining the association between major burns and the independent variables. In CST, female and their presence at an incident scene, multiple site injury were associated with major burn (p<0.05). In BLRA, the presence at an incident scene and spills (comparing explosion), discharge (comparing admission) were associated with major burns (p<0.05). In this study, the presence at an incident scene was the most significant factor concerning major burns. Furthermore, gender and injury number, exposure mechanism (spill comparing explosion), and disposition (discharge comparing admission) were also associated with major burns.

• Fire Science and Engineering
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• v.25 no.6
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• pp.168-177
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• 2011

The combustion test for real box of AC outdoor unit has been performed in this study in order to estimate the fire hazard in multi-system type of AC outdoor unit which is currently used for commercial use. The result showed that in test, there was explosion inside of AC outdoor unit, and flame erupted and fire spread through upper side grill. And then this fire burnt the combustibles such as wires, electronic control board, heat exchange copper plate and plastics etc inside the unit, refrigerant gas pipe was burst due to fire, and accelerated the explosion and flame eruption to outside while the refrigerant was erupting. It is found in this test that the maximum heat release rate of AC outdoor unit is 5,830 kW, the maximum internal temperature measured with infrared camera and thermocouple is $1,201^{\circ}C$, maximum ambient temperature is $881^{\circ}C$, and flame rose higher than about 5 m. It is concluded that the fire in AC outdoor unit cause fire to combustibles around the unit, and may give big damage by generating the secondary fire. It is expected that the result obtained from the test on the real object may be applied to fire realization of AC outdoor unit and estimation of fire spreading to the combustibles around in the future computer simulation.

• Journal of the Korean Society of Hazard Mitigation
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• v.5 no.3 s.18
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• pp.83-88
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• 2005

It is necessary to hold the school safety manual because recently, the safety-related accidents occur frequently in schools. Accidents can occur inside of schools as well as out of schools, and they can be classified with human accidents, traffic accidents, fire accidents, and explosion accidents. Safety-related accidents occurring in the school are dangerous because nobody can predict them. Illegally infringing violence, targeting unspecified and a lot of people, informs the parents and persons concerned to education of danger. School safety manual, never precedented before, describes epoch-making educational methods for students' safety. It describes safety security such as refuging ways at an emergency, the way to recognize danger for elevated safety based on prevention education, the use and practice of checklist for related facilities, and the implements and facilities for school personnels and students. So, the school safety manual is an important guidance for safety education at the level of prevention from various accidents which occur inside the school as well as out of the school. It presents a variety of prompt response after an accident. At the same time, it checks facilities and dangerous factors in schools and facilities for safety, and analyzes special factors based on them. So it will present the status of safety management of existing facilities and implements, the installment of new facilities and implements, and the way to secure safety for use.

• Fire Science and Engineering
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• v.29 no.5
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• pp.1-6
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• 2015

Flash point is one of the most important variables used to characterize fire and explosion hazard of liquids. The lower flash point data were measured for the binary systems {methanol + 1-butanol}, {ethanol + 1-butanol} and {2-propanol + 1-butanol} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured flash points were compared with the predicted values calculated using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The measured FP data agreed well with the predicted values of Raoult's law, Wilson, NRTL and UNIQUAC models. The average absolute deviation between the predicted and measured lower FP was less than 1.14 K.

• Journal of the Korean Institute of Gas
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• v.22 no.2
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• pp.52-58
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• 2018

The flash point is one of the most important properties to characterize fire and explosion hazard of flammable liquid mixture. In this paper, the flash points of ternary liquid mixture, n-nonane+n-decane+n-tridecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and multiple regression analysis. The absolute average errors(AAE) of the results calculated by Raoult's law is $0.6^{\circ}C$. The absolute average errors of the results calculated by multiple regression analysis is $0.4^{\circ}C$. As can be seen from AAE, the calculated values based on multiple regresstion analysis were found to be better than those based on Raoult's law.