• Korean Journal of Materials Research
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• v.8 no.6
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• pp.538-544
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• 1998

The spallation of a thermal barrier coating layer depends on the formation of brittle spinels. thermal expansion mismatch between ceramic and metal. the phase transformation of a ceramic layer and residual stress of coating layer. In this work. the formation mechanism of oxide scale formed by oxidation treatment at 90$0^{\circ}C$ was investigated in order to verify oxidation behavior at the interface between E-beam coated $Zr0_2$-7wt.% $Y_20_3$ and plasma sprayed CoNiCrAIY. Some elements distributed in the bond coating layer were selectively oxidized after oxidation. At the initial time of oxidation. AI-depletion zone and $\alpha$-$Al_O_3$,O, were formed at the bond coating layer by the AI-outward diffusion. After layer grew until critical thickness. spinels. $Cr_20$, and $C0_2CrO_4$ by outward diffusion of Co. Cr, Ni were formed. It was found that the formation of spinels may be related to the spallation of $Zr0_2$-7wt.% $Y_20_3$ during isothermal oxidation.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.6
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• pp.1775-1781
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• 2008

The effects of the type of curing agent on the swelling of the natural rubber(NR) sponge applicable to the self-sealing layer of a helicopter fuel tank were investigated. The curing systems employed were peroxide and mixed ones of sulfur and peroxide. The NR compounds were prepared in a kneader and a roll-mill. The compounds were partially cured in a press at high pressure and subsequently cured fully with expansion in another press at atmospheric pressure. The apparent density of the NR sponge was measured and the cell structure was observed with scanning electron microscopy. The swelling experiments were performed at room temperature using toluene, iso-octane, and an aircraft fuel as a solvent. More rapid volume swelling of the NR sponge cured by peroxide was achieved than cured by sulfur and peroxide with similar amount of curing agent added in rubber compounds. The apparent density and cell structure of the sponge were extremely sensitive to the amount of peroxide, which influences again the swelling behavior of the NR sponge. It is important to control properly two reactions of decomposition of foaming agent and crosslinking of NR in the mold to obtain rapid swelling of the NR sponge on contact of the fuel.

• Information Systems Review
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• v.17 no.3
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• pp.39-64
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• 2015

As information and information technology become more important in competitive corporate environments, the risk of information security breaches has increased accordingly. Although organizations establish security measures to manage information security risks, members of organizations do not comply with them well, and their information security behavior intention is unclear. Therefore, to understand the information security risk management intention of the members of organizations, the present study developed a research model using Protection Motivation Theory, Supervisory Authority Pressure, and Background factors. This study presents empirical research findings based on the analysis of survey data from 201 members of financial institutions. Perceived Severity, Self-efficacy, and Supervisory Authority Pressure had a positive effect on intention; however, Perceived Vulnerability and Response Efficacy did not affect intention. Security Avoidance Habit, which was considered a background factor, had a negative effect on all parameters, and did not have an effect on intention. Security Awareness Training, another background factor, had a positive effect on information security risk management intention and perceived vulnerability, self-efficacy, response efficacy, and supervisory authority pressure, and had no effect on perceived severity. This study used supervisory authority pressure and background factors in the field of information security, and provided a basis to use supervisory authority pressure in future studies on behavior of organizations and members of an organization. In addition, the use of various background factors presented the groundwork for the expansion of protection motivation theory. Furthermore, practitioners can use the study findings as a foundation for organization's security activities, and to improve regulations.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.1
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• pp.35-42
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• 2020

Torsional behavior due to the plane irregularities of the piloti building can cause excessive story drift in the torsionally outermost column, which can lead to shear failure of the column. As a seismic retrofit method that can control the torsional behavior of the piloti building, the expansion of RC wall, steel frame or steel brace may be used, but such methods may hinder the openness of the piloti floor. Therefore, in this study, linear dynamic analysis and nonlinear static analysis for piloti buildings retrofitted by knee brace were performed, and seismic performance evaluation and torsion control effect of knee brace were analyzed. The results showed that the shear force of the column increased when the piloti building retrofitted by knee brace, but it was effective in controlling the torsional deformation. In case of retrofit between knee brace and column by 30°, the shear force of the column increased less than that of 60°, and the lateral displacement of column was decreased in the order of □, ◯ and Ｈ in cross-section.

• Journal of the Korean Institute of Landscape Architecture
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• v.49 no.2
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• pp.41-50
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• 2021

This study was conducted to see the differences of park users by classifying them with their park use frequency in terms of park use, management policy and perception, using the same survey results conducted in 2014 and 2020. Research was conducted on urban parks in Yangju, South Korea, and 740 in 2014 and 431 in 2000 survey results were used. After classifying the high-use and low-use groups according to park use frequency, this study compared the demographic differences and park use method differences according to the group, the recognition differences for the future park management direction between the two groups were analyzed and compared using statistical analysis by year. The results showed that the park's quantitative expansion and accessibility improvements were the most important issues in 2014, while the importance of park management, such as checking and improving aging facilities, providing various programs, and creating a themed neighborhood park that could reveal the identity of the area, was increased in 2020. Despite recognizing the importance of persistent management in the case of high-use groups, the results showed that they were less willing to participate in park management programs compared to less-use groups, which showed the need for a discussion of how to involve high-use groups for long term park management. This study contribute the body of literature that it seeks to understand differences of park user in terms of their park use frequency. However, in future studies, analyzing the differences of park users through a short-term study is required.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.1
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• pp.32-36
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• 2021

This study was investigated in carbon diffusion behavior of laser-carburized TiZrN coating layer and the changes of mechanical properties. The carbon paste was deposited on TiZrN coatings, and the laser was irradiated to carburize into the coatings. The XRD peak corresponding to the (111) plane shifted to a lower angle after the carburization, showing the lattice expansion by doped carbon. The decreased grain size implied the compression by the grain boundary diffusion of carbon. The XPS spectra for the bonding states of carbon was analyzed that carbon was substitute to nitrogen atoms in TiZrN, as carbide, through the thermal energy of laser. In addition, the combination of sp2 and sp3 hybridized bonds represented the formation of an amorphous carbon. The cross-sectional TEM image and the inverse FFT of the TiZrN coating after carburizing were observed as the wavy shape, confirming the amorphous phase located in grain boundaries. After the carburization, the hardness increased from 34.57 GPa to 38.24 GPa, and the friction coefficient decreased by 83 %. In particular, the ratio of hardness and elastic modulus (H/E) which is used as an index of the elastic recovery, increased from 0.11 to 0.15 and the wear rate improved by 65 %.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.35 no.3
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• pp.167-174
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• 2022

This study investigates the behavior of a jointless bridge that integrates superstructure and abutment without an expansion joint. Based on the sensitivity analyses conducted in previous studies, a shell-based model was determined to be the most suitable numerical analysis model for jointless bridges due to the similarity of the model's results compared with the obtained displacement shape, which was influenced by relative errors, precision, and practical aspects. Accordingly, the behavior of a jointless bridge was analyzed at various wall depths using shell element-based and solid element models. In addition, the results of MIDAS Civil and ABAQUS analysis programs were compared. In the case of semi-integrated bridges (A and B), the displacement decreased as the wall depth increased due to the ground reaction force in Case 1 under a linear spring condition and +30℃. In the case where temperature was -30℃, the change in displacement was small because the ground reaction did not occur. As for bridge C (a fully integrated alternating bridge) and bridge D (an integrated chest wall alternating bridge), the displacement decreased as the wall depth increased at both +30 and -30℃ due to pile resistance. As for the comparison between the analysis programs used, the relative error in Case 1 was small, whereas a significant difference in Case 2 was observed. The foregoing variation is possibly due to the difference in the application of the nonlinear spring in the programs.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.394-400
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• 2023

In this study, the tuning phenomena, gas storage capacity, and thermal expansion behaviors of binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates were investigated for the potential applications of clathrate hydrates to gas storage. To understand the tuning behaviors of binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates, ¹³C solid-state NMR spectroscopy was used, and the results confirmed that maximum tuning factors for the binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates were achieved at 0.5 mol% and 1.0 mol% of guest concentration, respectively. The gas storage capacity of binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates were also checked, and the results showed the CH₄ capacity of our hydrate systems was superior to that of binary (tetrahydrofuran + CH₄) and (cyclopentane + CH₄) clathrate hydrates. The synchrotron diffraction patterns of these hydrates collected at 100, 150, 200, and 250 K confirmed the formation of a cubic Fd-3m hydrate. In addition, the lattice constant of clathrate hydrates with cyclopentylamine and methane were larger than that with cyclopropylamine and methane due to the effects of molecular size and shape.

• The Korean Journal of Financial Management
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• v.6 no.1
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• pp.31-62
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• 1989

By using deterministic dynamic models, we observe the behavior of the foreign exchange rate of a small open economy with rational expectation formation and different restrictions on the international economic integrations. First, an economy connected to the world by purchasing power parity and uncovered interest parity is studied in the next section. In both sections, financial assets available in the economy are domestic money and bonds. Stocks are added as a financial instrument in the next section, and real capital accumulation is also taken into account. Furthermore, the economy concerned there is fairly autonomous, and not directly governed by either purchasing power parity or uncovered interest parity. The expectation formation used throughout the whole paper is complete perfect foresight, which is the certainty version of rational expectation and free from any forecast errors. It is found that upon monetary expansion the short run depreciation of the foreign exchange rate is a fairly robust result regardless of the degree of the international economic integration, while it is not true for fiscal expansion. The expectation on the long run state significantly affects the short run response of the exchange rate. All of our models postulate that the current account should be balanced eventually. As the result, the short run behavior of the exchange rate is affected by the expectation on the long run balance and may well be a blend of the traditional flow view and modem asset view. The initial overshooting of the exchange rate is easily observed even in the fairly autonomous economy Furthermore, the initial overshooting is not reduced over time, but augmented for some time before it is eventually eliminated. As long as we maintain rational expectaion, introducing time delay in the adjustment of the foreign goods price to the foreign exchange rate does not make much difference.

• The Journal of Engineering Geology
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• v.31 no.4
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• pp.621-630
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• 2021

This study evaluated cracks and climate monitoring in Ipseok-dae columnar joints and Jigong Neodeol rock blocks in Mudeungsan National Park. The rocks' state of cracking and their surface temperatures were measured alongside air temperature, relative humidity, and wind velocity. The maximum crack behavior in Ipseok-dae was 0.367 mm at one point, and showed a slight tendency at other points. One in Jigong Neodeol was within 0.15 mm and showed a stable state with little change. The surface temperature of the Ipseok-dae columnar joints was higher on the side exposed to sunlight than on the shaded side. All blocks of Jigong Neodeol rock showed similar temperatures. The air temperature showed a similar distribution for both rock types. The air temperature showed a similar distribution for both Ipseok-dae and Jigong Neodeol. The relative humidity was mostly between 20% and 60% in Ipseok-dae and was between 20 and 70% in Jigong Neodeol. Both areas had low wind speeds, with maxima of 5 m/s in Ipseok-dae and 3 m/s in Jigong Neodeol. As a result, it is evaluated that crack behavior in Ipseok-dae columnar joints and Jigong Neodeol rock blocks have maintained a very stable state so far. The surface temperature, temperature, relative humidity, and wind velocity of the two areas showed small difference depending on the season, indicating that they were affected to some extent by the season. From a long-term perspective, this can continuously affect the deformation of the Ipseok-dae columnar joints or Jigong Neodeol rock blocks. Therefore, in order to accurately evaluate their stability, it is considered that the current microscopic delamination and exfoliation or the propagation and expansion of cracks should be continuously measured.