• 제목/요약/키워드: equivalency

검색결과 94건 처리시간 0.023초

A Statistical Termodynamic Study of Phase Equilibria in Microemulsions

  • Kyung-Sup Yoo;Hyungsuk Park
    • Bulletin of the Korean Chemical Society
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    • 제12권3호
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    • pp.334-342
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    • 1991
  • To investigate the phase equilibria and structural properties of microemulsions, we study a simple phenomenological model on the basis of the cubic lattice cell with which the oil- and water-filled cells are connected one another, respectively. The surfactant is assumed to be insoluble in both oil and water, and to be adsorbed at the oil-water interface. The Schulman condition, according to which the lateral pressure of the surfactant layer is compensated by the oil-water interfacial tension, is found to hold to good approximation in the middle-phase microemulsion. Our results show that the oil- and water-filled domains in that microemulsion are about 50-150 $\AA$ across, and depend sensitively on the curvature parameters. The phase diagram is not symmetric in this model. It may be asymmetrized intrinsically by non-equivalency of oil and water. The two- and tree-phase equilibria including critical points and critical endpoints are found.

Indoor Exposure and Health Risk of Polycyclic Aromatic Hydrocarbons (PAHs) in Public Facilities, Korea

  • Kim, Ho-Hyun;Lim, Young-Wook;Jeon, Jun-Min;Kim, Tae-Hun;Lee, Geon-Woo;Lee, Woo-Seok;Lim, Jung-Yun;Shin, Dong-Chun;Yang, Ji-Yeon
    • Asian Journal of Atmospheric Environment
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    • 제7권2호
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    • pp.72-84
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    • 2013
  • In the study, pollution levels of indoor polycyclic aromatic hydrocarbons (PAHs) in public facilities (vapor phase or particulate phase) were evaluated, and a health risk assessment (HRA) was carried out based on exposure scenarios. Public facilities in Korea covered by the law, including underground subway stations, funeral halls, child care facilities, internet cafes (PC-rooms), and exhibition facilities (6 locations for each type of facility, for a total of 48 locations), were investigated for indoor assessment. For the HRA, individual excess cancer risk (ECR) was estimated by applying main toxic equivalency factor (TEF) values suggested in previous studies. Among the eight public facilities, internet cafes showed the highest average $PM_{2.5}$ concentration at $110.0{\mu}g/m^3$ (range: $83.5-138.5{\mu}g/m^3$). When assuming a risk of facility exposure time based upon the results of the surveys for each public facility, the excess cancer risk using the benzo(a)pyrene indicator assessment method was estimated to be $10^{-7}-10^{-6}$ levels for each facility. Based on the risk associated with various TEF values, the excess cancer risk based upon the seven types cancer EPA (1993) and Malcolm & Dobson's (1994) assessment method was estimated to be $10^{-7}-10^{-5}$ for each facility. The excess cancer risk estimated from the TEF EPA (2010) assessment was the highest: $10^{-7}-10^{-4}$ for each facility. This is due to the 10-fold difference between the TEF of dibenzo(a,e)fluoranthene in 2010 and in 1994. The internet cafes where smoking was the clear pollutant showed the highest risk level of $10^{-4}$, which exceeded the World Health Organization's recommended risk of $1{\times}10^{-6}$. All facilities, with the exception of internet cafes, showed a $10^{-6}$ risk level. However, when the TEFs values of the US EPA (2010) were applied, the risk of most facilities in this study exceeded $1{\times}10^{-6}$.

컴파일러에 의한 C레벨 에러 체크 (Compiler triggered C level error check)

  • 정지문;윤종희;이종원;백윤흥
    • 정보처리학회논문지A
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    • 제18A권3호
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    • pp.109-114
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    • 2011
  • IR(Intermediate Representation) 최적화 과정은 컴파일러 back-end의 중요한 부분으로서 sub-expression elimination, dead code elimination 등 최적화 기법들을 사용한다. 하지만 IR 최적화 단계에서 생기는 에러들을 검출하고 디버깅하는데 많은 어려움이 있다. 그 첫 번째 이유로는 컴파일 된 어셈블리 코드를 해독하여 에러를 체크하기 어렵고 두 번째로는 IR 최적화 단계에서 에러가 생겼는지 결정 짓기 어렵기 때문이다. 이런 이유들로 인하여, 우리는 C 레벨에서 IR 코드변환 무결점 여부를 체크하기 위한 기법들에 관한 연구를 진행하여 왔다. 우리는 MeCC(Memory Comparison-based Clone) 탐색기를 기반으로 하여, 최적화하기 전 IR코드와 최적화 한 후의 IR코드를 각각 C코드로 다시 변환한 뒤, 이 두 개의 C코드를 MeCC의 입력으로 주고, 결과의 일치 여부를 확인하는 방법을 사용한다. 하지만 MeCC가 완벽한 결과를 알려주지 않기 때문에, 우리는 각 IR 최적화 기법마다의 특징에 대한 정보를 사전에 처리해서 그 결과의 정확도를 높였다. 이 논문에서는 dead code elimination, instruction scheduling 및 common sub-expression elimination 등 최적화 기법들을 이용한 변환 코드들을 예시로 실험하여 최종적으로 MeCC에서의 C 레벨 코드의 정확한 에러 체크 동작여부를 보여준다.

Analysis of the CREOLE experiment on the reactivity temperature coefficient of the UO2 light water moderated lattices using Monte Carlo transport calculations and ENDF/B-VII.1 nuclear data library

  • El Ouahdani, S.;Erradi, L.;Boukhal, H.;Chakir, E.;El Bardouni, T.;Boulaich, Y.;Ahmed, A.
    • Nuclear Engineering and Technology
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    • 제52권6호
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    • pp.1120-1130
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    • 2020
  • The CREOLE experiment performed In the EOLE critical facility located In the Nuclear Center of CADARACHE - CEA have allowed us to get interesting and complete experimental information on the temperature effects in the light water reactor lattices. To analyze these experiments with accuracy an elaborate calculation scheme using the Monte Carlo method implemented in the MCNP6.1 code and the ENDF/B-VII.1 cross section library has been developed. We have used the ENDF/B-VII.1 data provided with the MCNP6.1.1 version in ACE format and the Makxsf utility to handle the data in the specific temperatures not available in the MCNP6.1.1 original library. The main purpose of this analysis is the qualification of the ENDF/B-VII.1 nuclear data for the prediction of the Reactivity Temperature Coefficient while ensuring the ability of the MCNP6.1 system to model such a complex experiment as CREOLE. We have analyzed the case of UO2 lattice with 1166 ppm of boron in ordinary water moderator in specified temperatures. A detailed comparison of the calculated effective multiplication factors with the reference ones [1] in room temperature presented in this work shows a good agreement demonstrating the validation of our 3D calculation model. The discrepancies between calculations and the differential measurements of the Reactivity Temperature Coefficient for the analyzed configuration are relatively small: the maximum discrepancy doesn't exceed 1,1 pcm/℃. In addition to the analysis of direct differential measurements of the reactivity temperature coefficient performed in the poisoned UO2 lattice configuration, we have also analyzed integral measurements in UO2 clean lattice configuration using equivalency of the integral temperature reactivity worth with the driver core fuel reactivity worth and soluble boron reactivity worth. In this case both of the ENDF/B-VII.1 and JENDL.4 libraries were used in our analysis and the obtained results are very similar.

베이루트항에서 발생한 질산암모늄 폭발에 의한 영향 평가 (An Evaluation of the Impact of Ammonium Nitrate Explosion Occurred in Beirut Port)

  • 윤용균
    • 화약ㆍ발파
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    • 제41권4호
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    • pp.1-8
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    • 2023
  • 2020년 8월 4일에 베이루트항 저장 창고에 저장되었던 2750 ton의 질산암모늄이 폭발하였다. 이 폭발은 지금까지의 질산암모늄 폭발 중 가장 규모가 큰 것으로 알려졌다. TNT 등가법을 적용하여 2750 ton의 질산암모늄의 폭발 에너지에 상응하는 TNT 등가량을 구한 결과 856 ton으로 나타났다. Kingery-Bulmash 폭발 특성 계산기 툴을 활용하여 폭원으로부터 3600 m 까지의 범위에서 과압과 충격량을 산정하였다. 폭원으로부터 멀어짐에 따라 과압과 충격량은 지수적으로 감소하지만 과압이 더 크게 감소하여 과압이 충격량보다 거리에 따른 영향을 더 크게 받는 것으로 나타났다. 과압과 충격량이 구조물에 미치는 영향을 평가하기 위해서 구조물의 손상 기준을 적용한 결과 구조물의 부분적 붕괴, 심각한 손상, 가벼운 손상이 발생하는 임계거리는 폭원으로부터 각기 약 500, 800, 2200 m로 나타났다. 구조물과 인체의 손상 확률을 평가하기 위해서 프로빗 함수를 적용하였다. 구조물의 붕괴, 구조물의 심각한 손상, 구조물의 가벼운 손상, 창유리의 파손 가능성이 50% 이상이 되는 지점은 각기 약 500, 810, 2200, 3200 m가 되는 것으로 나타났다. 폭원으로부터 200 m 이내 지점에 있는 사람의 경우 폐 손상으로 인해 사망할 확률이 99% 이상인 것으로, 고막 파열이 발생할 확률이 50%인 지점은 약 300 m인 것으로 나타났다. 전신 이동에 따른 두개골 파열과 전신 충격에 의해 사망할 확률이 100%인 지점은 각기 300, 100 m인 것으로 평가되었다.

탄소공구강의 전단설계 변수에 따른 특성 상관관계 연구 (I) (A Study of Characteristic correlation go after the variable of shear process design for Carbon Tool Steel (I))

  • 류기룡;노현철;송재선;박춘달
    • Design & Manufacturing
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    • 제6권2호
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    • pp.84-89
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    • 2012
  • In recent years, technology of press plastic working having made remarkable progress. We can say this because it facilitates mass production and have superior performances in machining speed and equivalency of quality than other processing methods. In characteristics of press plastic working, mold manufacturing according to characteristics of each product should be preceded before processing and it has a great influence on machining speed and quality of products and etc according to manufacturing method. Therefore, mold design technology is a critical technology in press plastic working. There are lots of variables in press plastic working according to worked material, mold materials, conditions of heat treatment, clearance and so on. Abrasion of mold depends on these kind of conditions and sheared surface which is crucial for quality of product also depends on them. In this study, we conduct research on abrasion loss of mold according to 8, 10 and 12% of clearance for thickness of 1.0mm of worked material out of mold design variables of the products whose worked materials are high carbon steel and carbon tool steel by a practical experiment.

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소형 삼지 회전교차로의 용량분석을 위한 승용차 환산계수에 관한 연구 (Determination of Passenger Car Equivalents When Estimating Capacity at Small 3-leg Roundabouts)

  • 이용재;이인경;이동민
    • 대한교통학회지
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    • 제28권6호
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    • pp.65-74
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    • 2010
  • 이 연구는 다양한 차종의 차량이 혼합되어 운영되는 소형 3지 회전교차로에서 용량과 지체를 산정할 때 고려될 수 있는 새로운 형태의 승용차 환산계수의 모형과 이를 이용한 보정계수의 개발에 관한 것이다. 연구를 위하여 현재 회전교차로의 효과척도로 사용되고 있는 제어지체(Control Delay)를 기반으로 한 산정모형을 개발하고 현장에서 직접 수집한 실험자료를 적용하여 결과를 도출하고, 이를 이용재 외(2001)에서 제의한 모형의 결과와 비교 분석한다. 신호 교차로와는 달리, 회전교차로에서는 아직 중차량에 대한 영향을 객관적으로 감안할 수 있는 승용차 환산계수의 모형이 아직 제시되고 있지 않다. 두 가지 접근법에 의한 분석의 결과는 상호 높은 상관성을 보이고 있으며, 외국의 다른 연구결과와도 유사한 결과를 보이고 있어 향후 이 분야의 연구에 도움을 줄 것으로 판단된다.

나프타분해플랜트의 부탄추출공정에서 부탄증기의 연속누출에 의한 증기운 폭발사고의 영향평가 (The Consequence Analysis for Unconfined Vapor Cloud Explosion Accident by the Continuous Release of Butane Vapor in the Debutanizing Process of Naphtha Cracking Plant)

  • 손민일;이헌창;장서일;김태옥
    • 대한안전경영과학회지
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    • 제2권4호
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    • pp.33-43
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    • 2000
  • The consequence analysis for the unconfined vapor cloud explosion(UVCE) accident by the continuous release of butane vapor was performed and effects of process parameters on consequences were analyzed in standard conditions. For the case of continuous release(87.8 kg/s) of butane vapor at 8 m elevated height in the debutanizing process of tile naphtha cracking plant operating at 877 kPa & 346.75 K, we found that combustion ranges of dispersed vapor estimated by HMP model were 11.2~120.2 m and overpressures estimated by TNT equivalency model at 200 m were about 37.35~55.1 kPa. Also, overpressures estimated by Model UVCE I based on advective travel time to $X_{LFL}$ were smaller than those estimated by Model UVCE IIbased on real travel time between $X_{UFL}$ and $X_{LFL}$. At the same time, damage intensities at 200 m and effect ranges by overpressure could be predicted. Furthermore, simulation results showed that effects of operating pressures on consequences were larger than those of operating temperatures and results of accidents were increased with increasing operating pressures. At this time, sensitivities of overpressures for UVCE accident by the continuous release were about 5 kPa/atm.

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Quantitative Assessment of Infrared Analysis of Concrete Admixtures

  • Casale, Anthony J. III;Doukakis, Johanna;Najm, Husam;Davis, Kimberly
    • International Journal of Concrete Structures and Materials
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    • 제7권3호
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    • pp.203-214
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    • 2013
  • This study investigates quantitative methods for assessment of infrared analysis of concrete admixtures using correlation coefficients by performing IR scans following the ASTM C494/C494M-11 specifications. In order to achieve this goal, numerous IR scans were performed on specimens supplied by the manufacturer from different batches to ensure uniformity and equivalency. These scans were then analyzed to create correlation coefficients for each admixture. The correlation coefficients were used to quantitatively evaluate and interpret IR Scans of job samples. The study focused on 23 most commonly used concrete admixtures by the New Jersey Department of Transportation (NJDOT). They include air-entrainers, accelerators, retarders, water reducers, and other combinations of these admixtures. Their correlation coefficients were established by analyzing a total of 12 scans of each admixture from three different batches supplied by the manufacturer at different time intervals. In order to validate the obtained correlation coefficients and establish a target correlation, job samples were tested and compared to the obtained correlations. The study also evaluated the effects of drying time and using different types of KBr on correlation coefficients.

Gametophyte life-history dominance of Chondrus crispus (Gigartinaceae, Rhodophyta) along the Atlantic coast of Nova Scotia, Canada

  • Mclachlan, Jack L.;Blanchard, Wade;Field, Christopher;Lewis, Nancy I.
    • ALGAE
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    • 제26권1호
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    • pp.51-60
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    • 2011
  • Similar to other species of Gigartinaceae Chondrus crispus has an alternation of perennial, isomorphic gametophytic and sporophytic generations. As these two generations co-exist independently within populations and obtain their resources in a similar manner, intraspecific competition is expected. In populations within the southern Gulf of St. Lawrence, fronds of both generations of C. crispus occur in similar numbers. This equivalency can be related to substratum instability, where the population is dynamic with a high turn-over rate of genets. These observations support a stochastic hypothesis to account for distribution of gametophytes and sporophytes in this area. Along the Atlantic coast of Nova Scotia, where the substratum is stable, gametophytes are overwhelmingly predominant. Gametophytic predominance is greatest in the lower littoral zone where C. crispus is abundant and space is limited. Under the fucoid canopy where "free-space" exists, the gametophyte to sporophyte ratio is lower. Gametophytic and sporophytic fronds are distributed equally among different size-classes and size-distribution is not considered a competitive factor. Previous studies have shown that sporophytic fronds of C. crispus are more susceptible to infections by endophytic algae and other pathogens, and are more heavily grazed by herbivores than are gametophytic fronds. Thus, mechanistic factors are strongly implied in the selection of gametophytes in the Atlantic population.