• Title/Summary/Keyword: equilibrium test

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Heavy metal adsorption of a novel membrane material derived from senescent leaves: Kinetics, equilibrium and thermodynamic studies

  • Zhang, Yu;Tang, Qiang;Chen, Su;Gu, Fan;Li, Zhenze
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.95-104
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    • 2018
  • Copper pollution around the world has caused serious public health problems recently. The heavy metal adsorption on traditional membranes from wastewater is limited by material properties. Different adsorptive materials are embedded in the membrane matrix and act as the adsorbent for the heavy metal. The carbonized leaf powder has been proven as an effective adsorbent material in removing aqueous Cu(II) because of its relative high specific surface area and inherent beneficial groups such as amine, carboxyl and phosphate after carbonization process. Factors affecting the adsorption of Cu(II) include: adsorbent dosage, initial Cu(II) concentration, solution pH, temperature and duration. The kinetics data fit well with the pseudo-first order kinetics and the pseudo-second order kinetics model. The thermodynamic behavior reveals the endothermic and spontaneous nature of the adsorption. The adsorption isotherm curve fits Sips model well, and the adsorption capacity was determined at 61.77 mg/g. Based on D-R model, the adsorption was predominated by the form of physical adsorption under lower temperatures, while the increased temperature motivated the form of chemical adsorption such as ion-exchange reaction. According to the analysis towards the mechanism, the chemical adsorption process occurs mainly among amine, carbonate, phosphate and copper ions or other surface adsorption. This hypothesis is confirmed by FT-IR test and XRD spectra as well as the predicted parameters calculated based on D-R model.

A Preliminary Configuration Design of Methane/Oxygen Bipropellant Small-Rocket-Engine through Theoretical Performance Analysis (이론성능해석에 의한 메탄/산소 이원추진제 소형로켓엔진의 예비형상설계)

  • Bae, Seong Hun;Jung, Hun;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.3
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    • pp.47-53
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    • 2015
  • Design parameters required for Methane/oxygen bipropellant small-rocket-engine were derived through a theoretical performance analysis. The theoretical performance of the rocket engine was analyzed by using CEA and optimal propellant mixture ratio, characteristic length, and optimal expansion ratio were calculated by assuming chemical equilibrium. A coaxial-type swirl injector was chosen because of its outstanding atomization performance and high combustion efficiency compared to other types of injector and also a bell nozzle with 80% of its full length was designed. The rocket engine configuration with 1.72 MPa of chamber pressure, 0.18 kg/s in total propellant mass flow, and O/F ratio of 2.7 was proposed as a ground-firing test model.

Mechanical performance of sand-lightweight concrete-filled steel tube stub column under axial compression

  • Zhang, Xianggang;Deng, Dapeng;Lin, Xinyan;Yang, Jianhui;Fu, Lei
    • Structural Engineering and Mechanics
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    • v.69 no.6
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    • pp.627-635
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    • 2019
  • In order to study the axial compression performance of sand-lightweight concrete-filled steel tube (SLCFST) stub columns, three circular SLCFST (C-SLCFST) stub column specimens and three SLCFST square (S-SLCFST) stub column specimens were fabricated and static monotonic axial compression performance testing was carried out, using the volume ratio between river sand and ceramic sand in sand-lightweight concrete (SLC) as a varying parameter. The stress process and failure mode of the specimens were observed, stress-strain curves were obtained and analysed for the specimens, and the ultimate bearing capacity of SLCFST stub column specimens was calculated based on unified strength theory, limit equilibrium theory and superposition theory. The results show that the outer steel tubes of SLCFST stub columns buckled outward, core SLC was crushed, and the damage to the upper parts of the S-SLCFST stub columns was more serious than for C-SLCFST stub columns. Three stages can be identified in the stress-strain curves of SLCFST stub columns: an elastic stage, an elastic-plastic stage and a plastic stage. It is suggested that AIJ-1997, CECS 159:2004 or AIJ-1997, based on superposition theory, can be used to design the ultimate bearing capacity under axial compression for C-SLCFST and S-SLCFST stub columns; for varying replacement ratios of natural river sand, the calculated stress-strain curves for SLCFST stub columns under axial compression show good fitting to the test measure curves.

Research on Relationship between Urbanization and Energy Consumption (중국의 도시화와 에너지 소비 관계에 대한 연구)

  • Won, Doohwan;Jung, Sukwan
    • Journal of International Area Studies (JIAS)
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    • v.22 no.1
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    • pp.91-112
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    • 2018
  • This study examined the dynamic relationship between urbanization and energy consumption in China. As an alternative to the conventional method of having the same integration of time series and large samples, ARDL method and Toda-Yamamoto causality analysis were applied. As a result, urbanization income, income, and energy consumption have a long-term stable equilibrium. Urbanization and income have a positive effect on energy consumption in the long run, but short-term changes of urbanization and income have no significant effect on energy consumption changes. The adjusted coefficient was -0.2395, which was statistically significant. In the causality test, income and energy consumption are useful to predict each other, but urbanization is exogenous because there are no causality with other variables. Since the process of urbanization in China has been proceeding slowly and deliberately by the government, it can be seen that the long-term effects of urbanization are clear and exogenous.

Interrelationships between KRW/JPY Real Exchange Rate and Stock Prices in Korea and Japan - Focus on Since Korea's Freely Flexible Exchange Rate System - (한·일 원/엔 실질 환율과 주가와의 관계 분석 - 한국의 자유변동환율제도 실시 이후를 중심으로 -)

  • Kim, Joung-Gu
    • International Area Studies Review
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    • v.13 no.2
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    • pp.277-297
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    • 2009
  • This paper empirically investigates a long-run and short-run equilibrium relationships for exchange rate and stock prices in Korea and Japan from January 1998 to July 2008. Because using monthly data in my study, analyzes unit root test and VEC model including seasonality to overcome bias that happen in seasonal adjustment. The empirical evidence suggests that exists strong evidence supporting the long-run cointegration relationships between exchange rates and stock prices of the Korea and Japan. This implies that it is possible to predict one market from another for both countries, which seems to violate the efficient market hypothesis. In the long-run a negative relationship running from the KRW/JPY real exchange rate to the stock prices of Korea strongly argues for the traditional approach.

Electrical Characteristics Analysis According to Electrode Shape and Distance Between Electrodes (전극 형태와 전극 간 거리에 따른 전기적 특성 분석)

  • Tae-Hee Kim;Soon-Hyung Lee;Mi-Yong Hwang;Yong-Sung Choi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.4
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    • pp.408-412
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    • 2023
  • In this paper, in order to analyze high electrical insulation and cooling performance using mineral oil, the liquid insulating oil was changed in electrode shape and distance between electrodes to compare and analyze electrical characteristics according to equal electric field, quasi-equivalent electric field, and unequal electric field. As a result, the breakdown voltages were 36,875 V and 36,875 V in the form of sphere-sphere and plate-plate electrodes with equal electric fields. The breakdown voltage was 31,475 V in the sphere-plate electrode type, which is a quasi-equilibrium field, and the breakdown voltage was 28,592 V, 27,050 V, and 22,750 V in the needle-needle, sphere-needle, and needle-plate electrode types, which are unequal fields. Through this, it is possible to know the difference in breakdown voltage according to the type of electric field. The more equal the field, the higher the breakdown voltage, and the more unequal field, the lower the breakdown voltage. The difference in insulation breakdown voltage could be seen depending on the type of electric field, the insulation breakdown voltage was higher for the more equal electric field, and the insulation breakdown voltage was lower for the more unequal electric field. Also, it was confirmed that the closer the distance between the electrodes, the higher the insulation breakdown voltage, the higher the insulation breakdown current, and the insulation breakdown voltage and the insulation breakdown current were proportional.

A General and Versatile XFINAS 4-node Co-Rotational Resultant Shell Element for Large Deformation Inelastic Analysis of Structures (구조물의 대변형 비탄성 해석을 위한 범용 목적의 XFINAS 4절점 순수 변위 합응력 쉘요소)

  • Kim, Ki Du;Lee, Chang Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3A
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    • pp.447-455
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    • 2006
  • A general purpose of 4-node co-rotational resultant shell element is developed for the solution of nonlinear problems of reinforced concrete, steel and fiber-reinforced composite structures. The formulation of the geometrical stiffness presented here is defined on the mid-surface by using the second order kinematic relations and is efficient for analyzing thick plates and shells by incorporating bending moment and transverse shear resultant forces. The present element is free of shear locking behavior by using the ANS (Assumed Natural Strain) method such that the element performs very well as thin shells. Inelastic behaviour of concrete material is based on the plasticity with strain hardening and elasto-plastic fracture model. The plasticity of steel is based on Von-Mises Yield and Ivanov Yield criteria with strain hardening. The transverse shear stiffness of laminate composite is defined by an equilibrium approach instead of using the shear correction factor. The proposed formulation is computationally efficient and versitile for most civil engineering application and the test results showed good agreement.

Application of the optimal fuzzy-based system on bearing capacity of concrete pile

  • Kun Zhang;Yonghua Zhang;Behnaz Razzaghzadeh
    • Steel and Composite Structures
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    • v.51 no.1
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    • pp.25-41
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    • 2024
  • The measurement of pile bearing capacity is crucial for the design of pile foundations, where in-situ tests could be costly and time needed. The primary objective of this research was to investigate the potential use of fuzzy-based techniques to anticipate the maximum weight that concrete driven piles might bear. Despite the existence of several suggested designs, there is a scarcity of specialized studies on the exploration of adaptive neuro-fuzzy inference systems (ANFIS) for the estimation of pile bearing capacity. This paper presents the introduction and validation of a novel technique that integrates the fire hawk optimizer (FHO) and equilibrium optimizer (EO) with the ANFIS, referred to as ANFISFHO and ANFISEO, respectively. A comprehensive compilation of 472 static load test results for driven piles was located within the database. The recommended framework was built, validated, and tested using the training set (70%), validation set (15%), and testing set (15%) of the dataset, accordingly. Moreover, the sensitivity analysis is performed in order to determine the impact of each input on the output. The results show that ANFISFHO and ANFISEO both have amazing potential for precisely calculating pile bearing capacity. The R2 values obtained for ANFISFHO were 0.9817, 0.9753, and 0.9823 for the training, validating, and testing phases. The findings of the examination of uncertainty showed that the ANFISFHO system had less uncertainty than the ANFISEO model. The research found that the ANFISFHO model provides a more satisfactory estimation of the bearing capacity of concrete driven piles when considering various performance evaluations and comparing it with existing literature.

Stability Analysis of Open Pit Slopes in the Pasir Coal Field, Indonesia (인도네시아 Pasir 탄전에서의 노천채탄장 사면의 안전성해석)

  • 정소걸;선우춘;한공창;신희순;박연준
    • Proceedings of the Korean Society for Rock Mechanics Conference
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    • 2000.09a
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    • pp.183-193
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    • 2000
  • A series of studies such as geological logging data analysis, detailed geological survey, rock mass evaluation, in-situ and laboratory tests, rock strength and mechanical properties of the rock were concerned. The stability of the slope were carried out inorder to design the pit slope and individual benches using the stereographic projection analysis and numerical methods in Roto Pit of Pasir coal fetid. The bedding plane was one of the major discontinuities in the Roto Pit and the dip of which is about $60^{\circ}$in the northern part and $83^{\circ}$in the southern part. The dip of bedding becomes steeper from north to south. The plane and toppling failures are presented in many slopes. In laboratory test the average uniaxial compressive strength of mudstone was 9 MPa and that of weak sandstone was 10 MPa. In-situ test showed that the rocks of Roto north mining area are mostly weak enough to be classified in grade from R2(weak) to R3(medium strong weak) and the coal is classified in grades from R1(Very weak) to R2(Weak). The detailed stability analysis were carried out on 4 areas of Roto north(east, west, south and north), and 2 areas of Roto south(east and west). In this paper, the minimum factor of safety was set to 1.2 which is a general criterion for open pit mines. Using the stereographic projection analysis and the limit equilibrium method, slope angles were calculated as 30~$36^{\circ}$for a factor of safety greater than 1.2. Then these results were re-evaluated by numerical analysis using FLAC. The final slope angles were determined by rational described abode. A final slope of 34 degrees can guarantee the stability for the eastern part of the Roto north area, 33 degrees for the western part, 35 degrees for the northern part and 35 degrees for the southern part. For the Roto south area, 36 degrees was suggested for both sides of the pit. Once the pit slope is designed based on the stability analysis and the safety measures. the stability of 니ope should be checked periodically during the mining operations. Because the slope face will be exposed long time to the rain fall, a study such aspreventive measures against weathering and erosion is highly recommended to be implemented.

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Stability Analysis of Open Pit Slopes in the Pasir Coal Field, Indonesia (인도네시아 Pasir 탄전에서의 노천채탄장 사면의 안정성 해석)

  • 정소걸;선우춘;한공창;신희순;박연준
    • Tunnel and Underground Space
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    • v.10 no.3
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    • pp.430-440
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    • 2000
  • A series of studies such as geological logging data analysis, detailed geological survey, rock mass evaluation, in-situ and laboratory tests, rock strength and mechanical properties of the rock were concerned. The stability of the slope were carried out inorder to design the pit slope and individual benches using the stereographic projection analysis and numerical methods in Roto Pit of Pasir coal field. The bedding plane was one of the major discontinuities in the Roto Pit and the dip of which is about 60$^{\circ}$ in the northern part and 83$^{\circ}$ in the southern part. The dip of bedding becomes steeper from north to south. The plane and toppling failures are presented in many slopes. In laboratory test the average uniaxial compressive strength of mudstone was 9MPa and that of weak sandstone was 10MPa. In-situ test showed that the rocks of Roto north mining area are mostly weak enough to be classified in grade from R2(weak) to R3(medium strong weak) and the coal is classified in grades from R1(Very weak) to R2(Weak). The detailed stability analysis were carried out on 4 areas of Roto north (east, west, south and north), and 2 areas of Roto south(east and west). In this paper, the minimum factor of safety was set to 1.2 which is a general criterion for open pit mines. Using the stereographic projection analysis and the limit equilibrium method, slope angles were calculated as 30∼36$^{\circ}$ for a factor of safety greater than 1.2. Then these results were re-evaluated by numerical analysis using FLAC. The final slope angles were determined by rational described above. A final slope of 34 degrees can guarantee the stability for the eastern part of the Roto north area, 33 degrees for the western part, 35 degrees for the northern part and 35 degrees for the southern part. For the Roto south area, 36 degrees was suggested for both sides of the pit. Once the pit slope is designed based on the stability analysis and the safety measures, the stability of slope should be checked periodically during the mining operations. Because the slope face will be exposed long time to the rain fall, a study such aspreventive measures against weathering and erosion is highly recommended to be implemented.

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