• Title/Summary/Keyword: equilibrium state

검색결과 857건 처리시간 0.026초

산발적인 데이터를 이용한 HIV 변이모델의 파라미터 추정 (Parameter Estimation of an HIV Model with Mutants using Sporadically Sampled Data)

  • 김석균;김정수;윤태웅
    • 제어로봇시스템학회논문지
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    • 제17권8호
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    • pp.753-759
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    • 2011
  • The HIV (Human Immunodeficiency Virus) causes AIDS (Acquired Immune Deficiency Syndrome). The process of infection and mutation by HIV can be described by a 3rd order state equation. For this HIV model that includes the dynamics of the mutant virus, we present a parameter estimation scheme using two state variables sporadically measured, out of the three, by employing a genetic algorithm. It is assumed that these non-uniformly sampled measurements are subject to random noises. The effectiveness of the proposed parameter estimation is demonstrated by simulations. In addition, the estimated parameters are used to analyze the equilibrium points of the HIV model, and the results are shown to be consistent with those previously obtained.

Torsion-Effusion 법에 의한 Bismuth Triiodide의 승화압과 표준 엔탈피 (Sublimation Pressure and Standard Enthalpy of Bismuth Triiodide by Torsion-Effusion Method)

  • 김준학
    • 한국세라믹학회지
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    • 제28권2호
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    • pp.109-118
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    • 1991
  • Steady-state sublimation vapour pressures of anhydrous bismuth triiodide have been measured by the torsion-effusion method from 488.8 to 570.5 K and equilibrium sublimation pressures were obtained from the steady-state data. The standard sublimation enthalpy changes derived by both second(modified sigma function) and third(average enthalpy method) law methods were 159.316${\pm}$0.055, 137.67${\pm}$1.43 kJ$.$mol-1 respectively. The standard sublmation entropy change derived by modified sigma function was 232.88${\pm}$0.10 J$.$K-1$.$mol-1. The reliable standard sublimation enthalpy change based on a correlation of {{{{ { TRIANGLE }`_{cr } ^{g } }} H{{{{ { 0} atop {m } }}(298.15K) and {{{{ { TRIANGLE }`_{cr } ^{g } }} S{{{{ { 0} atop {m } }}(298.15K), a recommended p(T) equation has been obtained for BiI3(cr) ; lg(p/Pa)=-(C$.$K/T)+5.071lg(T/K)-2.838${\times}$10-3(T/K)-7.758${\times}$103(K/T)2+1.4519 where C={{{{{ { TRIANGLE }`_{cr } ^{g } }} H{{{{ { 0} atop {m } }}(298.15K)/0.019146 kJ$.$mol-1}-456.27.

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정체점 유동장에서 수소-액체산소 화염의 음향파 응답 특성 (Acoustic Response of Hydrogen/Liquid Oxygen Flame in Stagnation-Point Flow)

  • 박성우;정석호;김홍집
    • 대한기계학회논문집B
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    • 제27권4호
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    • pp.440-446
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    • 2003
  • Steady-state structure and acoustic pressure responses of GH$_2$-LOx diffusion flames in stagnation-point flow configuration have been studied numerically with a detailed chemistry to investigate the acoustic instabilities. The Rayleigh criterion is adopted to judge the instability of the GH$_2$-LOx flames from amplification and attenuation responses at various acoustic pressure oscillation conditions for near-equilibrium to near-extinction regimes. Steady state flame structure showed that the chain branching zone is embedded in surrounding two recombination zones. The acoustic responses of GH$_2$-LOx flame showed that the responses in near-extinction regime always have amplification effect regardless of realistic acoustic frequency. That is, GH$_2$-LOx flame near-extinction is much sensitive to pressure perturbation because of the strong effect of a finite-chemistry.

물의 T-s 선도 상에서 엑서지 및 엑서지율의 고찰 (Consideration of Exergy and Exergy Ratio on T-s Chart of Water)

  • 김덕진;김덕봉
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.827-832
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    • 2009
  • Exergy is the amount of reversible work obtainable when some matter is brought to a state of thermodynamic equilibrium with ambient. This exergy is availability or useful work induced from carnot cycle, and this can calculate the irreversible loss work which occurs within any thermal or power cycle. The exergy ratio is the value of exergy divided by enthalpy of ambient reference, where the quality of energy or enthalpy in substances is evaluated by exergy ratio. Exergy is very important in optimal design method of thermal system or each component, and the value of exergy at given state is calculated by equation. Here, designer can easily understand and find the value of enthalpy because enthalpy is graphically drawn in chart, however exergy did not. In this paper, exergy and exergy ratio of air were drawn on temperature-entropy chart, and we wish to this chart is a help to design, analysis and education.

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$H_2S$를 포함하는 LNG 혼합물에 대한 Cubic과 Noncubic 상태방정식의 예측 비교 (A comparison of predicted VLE of LNG mixtures containing $H_2S$ by use of Cubic and Noncubic EOS)

  • 최은주;이태종
    • 한국가스학회지
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    • 제4권4호
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    • pp.1-5
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    • 2000
  • [ $H_2S$ ]를 포함하는 액화천연가스(Liquified Natural Gas)의 기-액 조성을 noncubic 형태인 Modified-Benedict-Web-Robin EOS로 예측하였고, 그 결과를 대표적 cubic형태의 Peng-Robinson, Soave-Redlich-Kwong EOS로 예측한 기-액 조성과 비교 검토하였다.

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Electronic Structures, Magnetic, and Superconducting Properties of bcc Ni and V-doped Ni (Ni16-xVx)

  • Kim, Bong-Jae;Choi, Hong-Chul;Kim, Kyoo;Min, B.I.
    • Journal of Magnetics
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    • 제13권4호
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    • pp.128-131
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    • 2008
  • We have investigated the electronic structures and magnetic properties of both undoped and doped bcc Ni using the full-potential linearized augmented plane wave (FLAPW) band method. A ferromagnetic ground state is obtained at the equilibrium volume of bcc Ni. When the system is under strain, the nonmagnetic ground state is stabilized. When the Ni is doped with V, the $Ni_{16-x}V_x$ material loses its magnetic properties when x > 2. We have also discussed the possible superconducting properties of $Ni_{16-x}V_x$.

Design and Preparation of High-Performance Bulk Thermoelectric Materials with Defect Structures

  • Lee, Kyu Hyoung;Kim, Sung Wng
    • 한국세라믹학회지
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    • 제54권2호
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    • pp.75-85
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    • 2017
  • Thermoelectric is a key technology for energy harvesting and solid-state cooling by direct thermal-to-electric energy conversion (or vice versa); however, the relatively low efficiency has limited thermoelectric systems to niche applications such as space power generation and small-scale or high-density cooling. To expand into larger scale power generation and cooling applications such as ATEG (automotive thermoelectric generators) and HVAC (heating, ventilation, and air conditioning), high-performance bulk thermoelectric materials and their low-cost processing are essential prerequisites. Recently, the performance of commercial thermoelectric materials including $Bi_2Te_3$-, PbTe-, skutterudite-, and half-Heusler-based compounds has been significantly improved through non-equilibrium processing technologies for defect engineering. This review summarizes material design approaches for the formation of multi-dimensional and multi-scale defect structures that can be used to manipulate both the electronic and thermal transport properties, and our recent progress in the synthesis of conventional thermoelectric materials with defect structures is described.

Ar의 녹는점에 관한 분자동역학적 고찰 (Study on the Melting Point of Ar by Molecular Dynamic Simulation)

  • 정재동
    • 설비공학논문집
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    • 제19권12호
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    • pp.883-888
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    • 2007
  • As a starting point of investigating what molecular dynamic simulations can reveal about the nature of atomic level of heating and cooling process, argon described by the LJ potential is considered. Stepwise heating and cooling of constant rates are simulated in the NPT (constant number, pressure and temperature) ensemble. Hysteresis is found due to the superheating and supercooling. Drastic change of volume and energy is involved with phase change, but the melting point can not be obtained by simply observing the changes of these quantities. Since liquid and solid phases can co-exist at the same temperature, Gibbs free energy should be calculated to find the temperature where the Gibbs free energy of liquid is equal to that of the solid since the equilibrium state is the state of minimum Gibbs free energy. The obtained melting temperature, $T^*=0.685$, is close to that of the experiment with only 2% error.

데드비트 및 디지털 반복제어에 의한 고차 체인드 시스템의 제어 (High order chained system control using deadbeat and iterative control)

  • 남택근
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권4호
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    • pp.455-461
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    • 2007
  • In this paper a state steering strategy for high order chained system is presented. High order chained system can be derived from the acceleration constraints that cannot be integrable. The system classified as a nonholonomic system cannot be controlled to its equilibrium points by continuous and time-invariant controller. Using variable transformation two sub system can be obtained from the high order chained system. Deadbeat control and iterative state steering methods are proposed to control the system. Simulation results are given to show the effectiveness of the proposed control scheme.

과응력에 기초하여 일반화된 점소성 이론 (A Generalized Viscoplasticity Theory Based on Overstress)

  • 호광수
    • 대한기계학회논문집A
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    • 제26권10호
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    • pp.1953-1960
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    • 2002
  • The viscoplasticity theory based on overstress, one of the unified state variable theories, is generalized to model zero (no influence of loading rate) and negative (flow stress decreases with loading rate) as well as positive (flow stress increases with loading rate) rate sensitivity in a consistent way. On the basis of the long-time asymptotic solution the different types of rate sensitivity are classified with respect to an augmentation function that is introduced in the evolution law fur a state variable equilibrium stress. The theory predicts normal relaxation and creep behaviors even if unusual rate sensitivity is modeled. The constitutive model fir the behavior of a modified 9Cr-1 Mo steel at various temperatures is then compared with experimental data found in the literature.