• Title/Summary/Keyword: environmental durability

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Durability Evaluation of Cement Concrete Using Ferrosilicon Industrial Byproduct (페로실리콘 산업부산물 활용 시멘트 콘크리트의 내구성능 평가)

  • Chang-Young Kim;Ki Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.89-96
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    • 2023
  • In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO2 content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.

Some Physical Properties of 9-Year-Old Xylia xylocarpa Planted in Malaysia

  • Sahd, Mohd. Hamami;Josue, James;Chun, Su-Kyoung
    • Journal of the Korea Furniture Society
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    • v.19 no.6
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    • pp.411-419
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    • 2008
  • Xylia xylocarpa is fast-growing trees that are currently planted on trial basis in Sabah, Malaysia. The wood quality of trees grown in Sabah may differ from those grown in other places due to the environmental factors. Five 9-year-old trees of each species were extracted from their respective plots at Luasong, Tawau. Wood specimens were prepared from three height levels; bottom, middle and top, at the inner and outer radial positions. The within-tree and between-tree variations of physical properties of these species were analyzed. The basic density, oven-dry density and green moisture content(MC) are 0.72g/$cm^3$, 0.78g/$cm^3$ and 49.8% respectively. The shrinkage from green to oven-dry conditions for the radial and tangential directions were 3.35% and 5.76%, respectively. The trends of within-tree variations for most properties were more consistent in radial rather than vertical direction. This suggests diameter growth to be a more important factor contributing to the variations compared to height. Samples from the outer part of the stem were found to have higher density, shrinkage and mechanical strengths. The between-trees variations of some wood properties were found to be significantly different, probably due to genetic and micro-environmental factors. Significant correlation was recorded among the physical properties of the species. The true potential of X. xylocarpa for end-uses would be enhanced by further research such as the study on properties of wood from different sites and other properties like durability, seasoning, processing and machining characteristics. The characteristics of X. xylocarpa are comparable to a number of local popular hardwood species, indicating its suitability for heavy construction uses.

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Study on Effects of Ni/Al2O3 Catalysts Added with Mo on Durability Improvement in Steam Reforming Reactions (Mo를 첨가한 Ni/Al2O3 촉매의 수증기 개질반응에서의 내구성 증진 특성연구)

  • Won, Jong Min;Park, Gi Woo;Lee, Jin Woo;Hong, Sung Chang
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.560-567
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    • 2016
  • In this study, we characterized steam reforming reactions and surface of $Ni/Al_2O_3$ catalysts. Ni-Mo based catalysts were prepared by loading Mo as the co-catalyst and reaction activities of the Ni-Mo based catalysts were compared with those of Ni-based catalysts. Through the $H_2$-TPR and XPS analysis it was confirmed that this characteristic efficiency. $O_2$-TPO analysis was performed to examine the deposition characteristics, bonding structures and evaporation characteristics of carbon deposited on the surface of catalysts after long run experiments were performed for steam reforming reactions. As the results, it was found that durability was improved in Ni-Mo based catalysts inhibiting formation of graphitic carbon species which reduced reaction activities of the catalysts by strongly interacting with Ni in the steam reforming reaction.

A Study on the Cover Property of Offshore Reinforced Concrete Structure (내구성 해양 RC 구조물의 철근 피복적정성에 관한 연구)

  • Im, Jung-Soon;Bahng, Yun-Suk;Jo, Jae-Byung
    • Journal of the Korean Society of Hazard Mitigation
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    • v.4 no.3 s.14
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    • pp.73-81
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    • 2004
  • On this study, durability decreasing element caused by salt damage was analyzed elementally and studied with the data of the inside and outside in the country. The design strength and water-cement ratio according to diffusion coefficients of chloride were applied to Fick's diffusion equation. The required over depended on environmental conditions is estimated with endurance period, and the influences on cover according to the transformation of the each parameter were investigated. In consequence, if water-cement ratio decreases and design strength increases, it shows that slowing infiltration velocity of chloride ion can decrease required cover. Especially, it is more effective to use Portland blast-furnace slag cement into high strength concrete in the splash zone environmental conditions in blocking the diffusion of chloride ion. As the result, in the case of the offshore concrete structure needed high durability, it is needed to increase cover($3cm{\sim}8cm$) than minimum standard cover(8cm) according to environmental conditions.

A Study on Seepage Cutoff Effect of the Environmentally Friendly SCM (SCM 친환경주입공법에 의한 차수 효과에 관한 연구)

  • Chun, Byung-Sik;Roh, Jong-Ryun;Jooi, Tae-Seong;Do, Jong-Nam
    • Journal of the Korean GEO-environmental Society
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    • v.6 no.4
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    • pp.65-71
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    • 2005
  • Recently, difficulties in soft ground improvement that caused by effectiveness of the ground improvement, the durability and environmentally friendliness of the injection material come to the fore. This paper studies the field applicability of the SCM in reinforcement and seepage cutoff of the back of an existing continuous wall. SCM uses double rod which imposes heavy pressure($10-100kgf/cm^2$) to disturbed, cut, discharge, and mix the ground. It is observed that a bulb is formed by using cement paste and environmentally friendly injection materials with minimal alkali leaching. Unconfined compression test and fish poison tests are performed. Test results indicate that the method results in higher durability, less leaching through use of the environmentally friendly injection material, and faster mobilization of the strength. In addition, field tests confirm the formation of the bulb and the seepage cutoff wall.

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Evaluation of grout for reinforcing soft section in subsea tunnel (해저터널 연약 구간 보강용 그라우트 내구성 평가)

  • Moon, Junho;Jeong, Ghangbok;Xin, Zhenhua;Kim, Younguk
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.6
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    • pp.947-956
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    • 2018
  • Subsea tunnel built in abyssal zone is exposed to environment under high water pressure caused by seawater and etc., and this high pressure from underground water may facilitate leaching. In particular, since underground water can be easily flown in during construction, this might cause many problems related to cutoff water. Therefore, in order to secure safety, it is necessary to apply grouting equipment and materials which are appropriate to construction environment. Accordingly, in this research, evaluation was made on the physical characteristics of grouting materials (strength, leaching and etc. depending on curing methods for each of used materials and condition) which can be applied during subsea tunnel construction. As a result of this research, stable strength increase was found in CA and CSA type, and it is determined that no decrease in their durability was found, so these can be used as stable materials for structures under influenced by seawater.

Effect of Active Metal Loading on Catalytic Activity of V2O5/TiO2 Catalysts (V2O5/TiO2 촉매의 활성금속 함량이 촉매 활성에 미치는 영향)

  • Jang, Younghee;Kim, Sung Chul;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.482-487
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    • 2022
  • In this study, the activity test and characterization were performed to evaluate the hydrogen sulfide removal characteristics using a V/TiO2 catalyst at room temperature. The optimal vanadium loading was 10 wt%, and the durability was greater than 60 minutes at 60~80% relative humidity. The Brunauer-Emmett-Teller (BET) surface area and raman spectroscopy results confirmed that the structure of the vanadium site exposed to the surface was a dominant factor in catalyst activity. From Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) and X-ray crystallography (XRD) analyses, it was found that sulfur can be accumulated on the catalyst surface, which results in a decrease in durability under catalytic activity tests. Therefore, it is judged that a combined process of catalytic oxidation and regeneration is needed.

Evaluation of Static Spring Constant and Accelerated Life Prediction for Compression Set of Polyurethane Resilient Pad in Rail Fastening System

  • Lee, Seung-Won;Park, Jun-Young;Park, Eun-Young;Ryu, Sung-Hwan;Bae, Seok-Hu;Kim, Nam-Il;Yun, Ju-Ho;Yoon, Jeong-Hwan
    • Elastomers and Composites
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    • v.53 no.4
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    • pp.220-225
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    • 2018
  • Resilient pads play a major role in reducing the impact of loads on a rail in a rail-fastening system, which is essentially used for a concrete track. Although a compression set test is commonly used to measure the durability of a resilient pad, the static spring constant is often observed to be different from the fatigue test. In this study, a modified compression set test method was proposed to monitor the variations in the compression set and static spring constant of a resilient pad with respect to temperature and time. In addition, the life of the resilient pad was predicted by performing an acceleration test based on the Arrhenius equation.

Corrosion Behaviour of Some Alloys in Tropical Urban and Marine Atmospheres

  • Dang, Vu Ngoan;Bui, Ba Xuan;Nguyen, Nhi Tru
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.125-129
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    • 2008
  • Results of corrosion testing for different grades of titanium, copper, zinc, alluminium alloys and steels after two years of outdoor exposure under humid tropical urban and marine conditions have been presented and discussed. Mass loss and corrosion product characteristics for the exposed specimens at Hanoi testing site with high humidity and Nhatrang marine stations (at 100 and 1,000 meters distances from sea) with different airborne salinities (35.9 and $90.0mg/m^2.d$ respectively) have been selected for investigation. From time dependence of the specimen mass loss and corrosion product characteristics, the strong influence of environmental parameters upon durability for the investigated metals and alloys has been demonstrated. Only titanium alloys show high resistance to the marine conditions. All the other specimens (copper, zinc, alluminium alloys and steels) have been underwent strong deterioration under influence of aerosol salinity. Results of corrosion products analysis have been also presented for characterization of environmental impact on the metal degradation processes.

A Feasibility Analysis on Steel Net Gabion Reinforcement of Reinforced Earth-retaining Wall (자연친화적인 보강토 옹벽의 철판망 gabion 보강재 타당성 분석)

  • Chung, Dae-Seouk
    • Journal of Environmental Science International
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    • v.17 no.2
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    • pp.135-140
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    • 2008
  • Steel net gabion is eco-friendly retaining wall structure showing favorable ability to overcome construction and environmental restriction and also to resist corrosion, chemical attack and degradation. This paper is dealt with the applicability of gabion metal net as a substitution of existing strengthening material. Pull out test was carried out to verify the applicability of gabion metal net. According to results, the increase of surcharge loading and horizontal load resulted in a yield of metal net. The stress at the time of yield was in the range of elasticity. Accordingly, gabion metal net can be substituted for existing geogrid and there is a need for experiment and analysis of arrangement direction and durability of gabion steel net.