• 제목/요약/키워드: environmental diffusion

검색결과 922건 처리시간 0.025초

Enhanced vertical diffusion coefficient at upper layer of suspended sediment concentration profile

  • Kim, Hyoseob;Jang, Changhwan;Lhm, Namjae
    • Ocean Systems Engineering
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    • 제2권4호
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    • pp.289-295
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    • 2012
  • Assume fluid eddy viscosity in the vertical direction is parabolic. Sediment particles diffuse with the given fluid eddy viscosity. However, when the vertical diffusion coefficient profile is computed from the suspended sediment concentration profile, the coefficient shows lager values than the fluid mixing coefficient values. This trend was explained by using two sizes of sediment particles. When fine sediment particles like wash load are added in water column the sediment mixing coefficient looks much larger than the fluid mixing coefficient.

Evaluation of Chloride Ion Diffusion Characteristics of Concrete according to the Replacement Rate of Recycled Aggregate (순환골재 치환율에 따른 콘크리트 염소이온 확산 특성 평가)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 한국건축시공학회 2023년도 가을학술발표대회논문집
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    • pp.203-204
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    • 2023
  • Recycled aggregate is an aggregate that satisfies the quality as an aggregate by crushing waste concrete and passing it through a separator. The government grants a floor area ratio of up to 15% and building height mitigation when more than 25% of the recycled building materials are used. In addition to environmental protection issues, it is necessary to actively utilize recycled aggregates that meet the standards to secure the business feasibility of buildings. This study attempted to derive the results according to the substitution rate by measuring the chloride ion diffusion characteristics based on the electrophoresis method.

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A Study on Resistance of Chloride Ion Penetration in Ground Granulated Blast-Furnace Slag Concrete (고로슬래그 미분말 콘크리트의 염화물 침투 저항성에 관한 연구)

  • Song, Ha-Won;Kwon, Seung-Jun;Lee, Suk-Won;Byun, Keun-Joo
    • Journal of the Korea Concrete Institute
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    • 제15권3호
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    • pp.400-408
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    • 2003
  • Chloride ion inside concrete destroys the so-called passive film surrounding reinforcing bars inside concrete so that the so-called salt attack accelerates corrosion which is the most critical factor for durability as well as structural safety of reinforced concrete structures. Recently, as a solution of the salt attack, the ground granulated blast-furnace slag(GGBFS) have been used as binder or blended cement more extensively. In this paper, characteristics of chloride ion diffusion for the GGBFS concrete, which is known to possess better resistance to damage due to the chloride ion penetration than ordinary portland cement(OPC) concrete possesses, are analyzed and a chloride ion diffusion model for the GGBFS concrete is proposed by modifying an existing diffusion model for the OPC concrete. The proposed model is verified by comparing diffusion analysis results using the model accelerated chloride penetration test results for concrete specimens as well as field test results for an RC bridge pier. Then, an optimal resistance condition to chloride penetration for the GGBFS concrete is obtained according to degrees of fineness and replacement ratios of the GGBFS concrete. The result shows that the GGBFS concrete has better resistance to chloride ion penetration than OPC concrete has and the resistance is more affected by the replacement ratio than the degree of fineness of the GGBFS.

Assessing the Influence Radius of a Water Treatment System Installed in a Reservoir Using Tracer Experiment and 3D Numerical Simulation (추적자 실험 및 3차원 수치모의를 이용한 저수지 수처리 장치의 영향반경 평가)

  • Park, Hyung Seok;Lee, Eun Ju;Ji, Hyun Seo;Choi, Sun Hwa;Chun, Se Woong
    • Journal of Korean Society of Water Science and Technology
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    • 제26권6호
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    • pp.3-12
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    • 2018
  • The objective of this study was to evaluate the radius of influence of effluent of water treatment system developed for the purpose of improvement of reservoir water quality using fluorescent dye (Rhodamine-WT) tracer experiment and 3-D numerical model. The tracer experiment was carried out in a medium-sized agricultural reservoir with a storage capacity of $227,000m^3$ and an average depth of 1.6 m. A guideline with a total length of 160 m was installed at intervals of 10 m in the horizontal direction from the discharge part, and a Rhodamine measurement sensor (YSI 6130, measurement range $0-200{\mu}g/L$) was used to measure concentration changes in time, distance, and depth. Experimental design was established in advance through Jet theory and the diffusion process was simulated using ELCOM, a three dimensional hydraulic dynamics model. As a result of the study, the direct effect radius of the jet emitted from the applied water treatment system was about 50-70 m, and the radius of physical effect by the advection diffusion was judged to be 100-120 m. The numerical simulations of effluent advection-diffusion of the water treatment system using ELCOM showed very similar results to those of the impact radius analysis using the tracer experiment and jet flow empirical equations. The results provide valuable information on the spatial extent of the water quality improvement devices installed in the reservoir and the facility layout design.

The Comparison of Apparent Chloride Diffusion Coefficients in GGBFS Concrete Considering Sea Water Exposure Conditions (해양 폭로 환경에 따른 GGBFS 콘크리트의 겉보기 염화물 확산계수 비교)

  • Yoon, Yong-Sik;Jeong, Gi-Chan;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • 제26권2호
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    • pp.18-27
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    • 2022
  • In this study, the time-dependent chloride ingress behavior in GGBFS concrete was evaluated considering marine exposure conditions and the properties of concrete mixtures. The concrete mixture for this study had 3 levels of water to binder ratio and the substitution rate of GGBFS, and outdoor exposure tests were performed considering submerged area, tidal area, and splash area. According to the evaluation results of diffusion coefficient considering properties of concrete mixtures, as the substitution rate of GGBFS increased, the decreasing rate of the diffusion coefficient decreased based on exposure periods of 730 days(2 years). As the evaluation result of the diffusion behavior according to the marine exposure conditions, the diffusion coefficient was evaluated in the order of submerged area, tidal area, and splash area. In tidal area, a relatively high diffusion coefficient was evaluated due to the repetition of wet and dry seawater. In this study, the effects of GGBFS substitution rate on the decreasing behavior of apparent chloride diffusion coefficient was analyzed in consideration of exposure conditions and periods. Linear regression analysis was performed with apparent chloride diffusion coefficient as output value and GGBFS substitution rate as input value. After 730 days of exposure, the effect of GGBFS on diffusion coefficient was significantly reduced. Even for OPC concrete, after 730 days, the diffusion coefficient was as low as that of GGBFS concrete, so the gradient of the regression equation decreased significantly. It is thought that improved durability performance for chloride ingress can be secured before 730 days through the use of GGBFS.

Diffusion Analysis of the High Temperature and Salinity Water by the 3-D Baroclinic Flow Model (3-D 밀도류모델을 이용한 고온${\cdot}$고염수의 확산해석)

  • Kim, Jong-In;Kim, Hyeon-Ju
    • Journal of Ocean Engineering and Technology
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    • 제13권3B호
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    • pp.3-13
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    • 1999
  • The diffusion characteristics of the high temperature and salinity water discharged in Chinhae Bay under BMP(Barge-Mounted Plants) desalination processes were simulated to access environmental impact. The 3-D baroclinic flow model is formulated by integrating the basic equations with respect to each control volume and by transforming them into a finite difference form using the space-staggered grid system. With a 3-D baroclinic flow model, the tide-induced and density-induced current was computed and confirmed by comparing with observed data. From the results of numerical experiment, it is expected that the maximum diffusion lengths of the high temperature and salinity which increase $0.6^{circ}C$ and 0.2 after discharging are 1 km and 3.5km, respectively. It may be expected that the discharge has an effect on surrounding area of discharge, but not an effect on whole area of Chinhae Bay.

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Study on Simulation of Dust Diffusion at Open Pit Mines (노천광산의 발파분진 비산영역 예측에 관한 연구)

  • 김복윤;이상권;조영도;김임호
    • Tunnel and Underground Space
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    • 제8권3호
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    • pp.194-199
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    • 1998
  • This research was aimed to figure out the trend of dust diffusion at open pit limestone mine for assessing the environmental impacts on the high voltage power transmission line. It is rather easy to assess the dust generation and size distribution of limestone dust at the blasting site, but it is very hard to assess the expected area of dust diffusion and amount of dust fall by the distances from the dust source. In this research, a 3-dimensional fluid dynamic simulation software (3D-Flow) was used for analysing the above mentioned matters to assess the impacts to the insulators on the transmission tower by the blasting dust. It was verfied that the 3D-Flow is reliable tool for simulating dust movement, and the limestone dust is not much hazardous to the power transmission line.

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Adsorption Characteristics of Cu Ions by Zeolite Na-A Synthesized from Jeju Volcanic Rocks (제주 화산석으로부터 합성한 Na-A 제올라이트에 의한 Cu 이온의 흡착 특성)

  • Ju, Chang-Sik;Lee, Chang-Han;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • 제27권5호
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    • pp.299-308
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    • 2018
  • The adsorption characteristics of Cu ions were studied using the zeolite Na-A synthesized from Jeju volcanic rocks. The effects of various operating parameters such as initial concentration of Cu ions, contact time, solution pH, and solution temperature were investigated in batch experiments. The adsorption of Cu ions by Na-A zeolite was fitted well by pseudo-second-order kinetics and the Langmuir isotherm model. The maximum adsorption capacity determined using the Langmuir isotherm model was 152.95 mg/g. In addition, the adsorption of Cu ions by zeolite Na-A was primarily controlled by particle diffusion model in comparison with the film diffusion model. As the temperature increased from 303 K to 323 K, ${\Delta}G^o$ decreased from -2.22 kJ/mol to -3.41 kJ/mol, indicating that the adsorption of Cu ions by Na-A zeolite is spontaneous process.

Removal Characteristics of Cu(II) by PSf/D2EHPA/CNT Beads Prepared by Immobilization of Carbon Nanotubes (CNT) and Di-(2-ethylhexyl)-phosphoric acid (D2EHPA) on Polysulfone (PSf) (Polysulfone으로 carbon nanotubes (CNT)와 di-(2-ethylhexyl)-phosphoric acid (D2EHPA)를 고정화한 PSf/D2EHPA/CNT 비드에 의한 Cu(II)의 제거특성)

  • Lee, Chang-Han;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • 제25권11호
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    • pp.1485-1491
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    • 2016
  • PSf/D2EHPA/CNT beads were prepared by immobilizing di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and carbon nanotubes (CNT) on polysulfone (PSf) and used to remove Cu(II) from aqueous solutions. Optimum pH was in the range of 4 to 6. The removal kinetic of Cu(II) by the prepared PSf/D2EHPA/CNT beads was mainly governed by internal diffusion, and the diffusion coefficient of Cu(II) by PSf/D2EHPA/CNT beads was found to be $2.19{\times}10^{-4}{\sim}2.64{\times}10^{-4}cm^2/s$. The Langmuir isotherm model predicted the experimented data well. The maximum removal capacity of Cu(II) obtained from this isotherm was 7.32 mg/g. Calculated thermodynamic parameters such as ${\Delta}G^o$, ${\Delta}H^o$ and ${\Delta}S^o$ showed that the adsorption of Cu(II) ions onto PSf/D2EHPA/CNT beads was feasible, spontaneous and endothermic at 293-323 K.

Equilibrium and Kinetic Studies of the Biosorption of Dissolved Metals on Bacillus drentensis Immobilized in Biocarrier Beads

  • Seo, Hanna;Lee, Minhee;Wang, Sookyun
    • Environmental Engineering Research
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    • 제18권1호
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    • pp.45-53
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    • 2013
  • Biocarrier beads with dead biomass, Bacillus drentensis, immobilized in polymer polysulfone were synthesized to remove heavy metals from wastewater. To identify the sorption mechanisms and theoretical nature of underlying processes, a series of batch experiments were carried out to quantify the biosorption of Pb(II) and Cu(II) by the biocarrier beads. The parameters obtained from the thermodynamic analysis revealed that the biosorption of Pb(II) and Cu(II) by biomass immobilized in biocarrier beads was a spontaneous, irreversible, and physically-occurring adsorption phenomenon. Comparing batch experimental data to various adsorption isotherms confirmed that Koble-Corrigan and Langmuir isotherms well represented the biosorption equilibrium and the system likely occurred through monolayer sorption onto a homogeneous surface. The maximum adsorption capacities of the biocarrier beads for Pb(II) and Cu(II) were calculated as 0.3332 and 0.5598 mg/g, respectively. For the entire biosorption process, pseudo-second-order and Ritchie second-order kinetic models were observed to provide better descriptions for the biosorption kinetic data. Application of the intra-particle diffusion model showed that the intraparticle diffusion was not the rate-limiting step for the biosorption phenomena. Overall, the dead biomass immobilized in polysulfone biocarrier beads effectively removed metal ions and could be applied as a biosorbent in wastewater treatment.