• Journal of the Korean Society of Combustion
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• v.4 no.1
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• pp.49-57
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• 1999

An experimental study on double-concentric diffusion flame has been carried out in order to investigate the shape, the flame length, and the other characteristics of the flame. Flow visualization of the flame by the $TiO_2$ particles and also the emission measurements are conducted. The commercial grade LP gases are used as fuel. The inverse diffusion flames are formed at the center when the central air flow rate is about 0.1 L/min. With a larger flow rate of the central air jet than 0.2 L/min the flame turns to be an annular-shaped flame, which is very bright. When the central air flow rate increases over 2.4 L/min, the flame turns to blue and the flame tips are opened because of the lifting of the inner part of the flame. Because of this lifting and the incomplete combustion, the CO emission increases abruptly from 25 ppm to more than 150 ppm. On the contrary, the NOx emission is decreased.

• The Journal of Engineering Geology
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• v.20 no.3
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• pp.271-279
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• 2010

Time-dependent behavior similar to secondary deformation related to mineral dissolution is easily observed when performing a laboratory pressure experiment. In this research, to observe the dissolution of quartz found in bentonite used as buffer material for the geological disposal of high-level waste (HLW) under conditions of high pH, we calculated the diffusion of $OH^-$ ions and the behavior of quartz dissolution using the homogenization analysis method. The results reveal that the rate of quartz dissolution is proportional to the temperature and interlayer water thickness. In particular, in a high-pH environment, the reacted area (and therefore the dissolution rate) increases with decreasing interlayer water thickness.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.25 no.2
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• pp.133-143
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• 1992

The water-quality control for coastal waters is continuously required in view point of the environmental protection. The purpose of this study is to simulate the hydrodynamic process and the dispersion phenomena of several pollutants in Suyeong Bay, Pusan. The present study employs the depth-averaged 2-dimensional model for nemerical simulation of the hydrodynamics and diffusion. The nemerical solution is obtained by ADI(Altenating Direction Implicit) scheme which is frequently used for tidal current and diffusion computations in the coastal zone. To verify the nunlerical results, the field observations of various water quality parameters such as COD, SS and nutrients were performed during the spring tide. In the results of this study, the computed tidal currents show the clockwise flows for ebb tide and counter-clockwise flows for flood tide. In comparison with the water-qualities in ebb tide and flood tide, there seems to be slightly deteriorated in ebb tide and especially near the estuary of Suyeong River. In flood tide, however, the water-quality near Kwangan Beach is deteriorated. The computed distributions of COD and SS are in god agreements with the observed ones, while those of $PO_4\;^{3-}-P\;and\;NO_3\;^--N$ show slight differences due to the complex transformation processes.

• Journal of Environmental Science International
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• v.9 no.2
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• pp.165-171
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• 2000

A kinetic study for anion exchange was performed for commercially available Cl- type anion exchange resin in use to remove nitrate in water. The obtained results from the batch reactor were applied to the Langmuir and Freundlich models. The constants for Lagmuir model were qmax =29.82 and b=0.202, and for Freundlich model were K=5.509 and n=1.772. Langmuir model showed betterfit than Frendlich model for the experimental results. Ion exchange reaction rate was also calculated and the the approximate first-order reaction, rate constant k1 was 0.16 L/mg.hr. Effective diffusion coefficient was obtained in the range from $9.67$\times$10^{-8} cm^2/sec$ for initial concentration change, and from $6.09$\times$10^{-7} to 3.98$\times$10^{-6} cm^2/sec$ for reaction temperature change. Activation energy during the diffusion was calculated as 26 kcal/mol.

• Journal of Environmental Science International
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• v.23 no.12
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• pp.2121-2127
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• 2014

Analyzing the observational data of volcanic activities around the northern part of Korean peninsula, the odds of volcano eruption increases continuously. For example, the cumulative seismic moment and frequence observed near Mt. Baekdu show a sudden increased values. In this study, predicting the diffusion of volcanic ash for two cases were carried out by using interactive realtime simulator, which was developed during last 2 years as a research and development project. The first case is Sakurajima volcano (VEI=3) erupted in August 2013. The second case is assumed as the volcanic eruption at Mt. Baekdu (VEI=7) under landing circumstance of typhoon Maemi (August 2003) in Korean peninsula. The synoptic condition and ash diffusion for the two cases were simulated by WRF(Weather Research and Forecast) model and Lagrangian dispersion model, respectively. Comparing the simulated result of the first case (i.e., Sakurajima volcano) with satellite image, the diffusion pattern show acceptable result. The interactive realtime simulator can be available to support decision making under volcanic disaster around East Asia by predicting several days of ash dispersion within several minutes with ordinary desktop personal computer.

• Journal of Environmental Science International
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• v.27 no.3
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• pp.167-177
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• 2018

The removal characteristics of As and Se ions from aqueous solution by hexadecyl trimethyl ammonium bromide (HTMAB) modified anthracite (HTMAB-AT) were investigated under various conditions of contact time, pH and temperature. When the pH is 6, the zeta potential value of anthracite (AT) is -24 mV and on the other hand, the zeta potential value of the HTMAB-AT is +44 mV. It can be seen that the overall increase of about 60 mV. Increasing the (+) potential value indicates that the surface of the adsorbent had a stronger positive charge, so adsorption for the anion metal was increased. The isotherm data was well described by Langmuir and Temkin isotherm model. The maximum adsorption capacity was found to be 7.81 and 6.89 mg/g for As and Se ions from the Langmuir isotherm model at 298 K, respectively. The kinetic data was tested using pseudo first and pseudo second order models. The results indicated that adsorption fitted well with the pseudo second order kinetic model. The mechanism of the adsorption process showed that adsorption was dependent on intra particle diffusion model according to two step diffusion. The thermodynamic parameters(${\Delta}G^{\circ}$, ${\Delta}H^{\circ}$, and ${\Delta}S^{\circ}$) were also determined using the equilibrium constant value obtained at different temperatures. The thermodynamic parameters indicated that the adsorption process was physisorption, and also an endothermic and spontaneous process.

• Journal of Environmental Science International
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• v.2 no.1
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• pp.17-26
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• 1993

The layer that is directly influenced by ground surface is called the atmospheric boutsdary layer in comparison with the free atmosphere of higher layer. In the boundary layer, the changes of wind, temperature and coefficient of turbulent diffusion in altitude are large and have great influences an atmospheric diffusion. The purpose of this paper is to express the structure and characteristics of development of mixed layer by using laboratory experiment and numerical simulation. Laboratory experiment using water tank are performed that closely simulate the process of break up of nocturnal surface inversion above heated surface and its phenomena are analyzed by the use of horizontally averaged temperature which is observed. The result obtained from the laboratory experiment is compared with theoretical ones from ; \textsc{k}-\varepsilon numerical model. The results are summarized as follows. 1) The horizontally averaged temperature was found to vary smoothly with height and the mixed layer developed obviously being affected by the convection. 2) The mean height of mixed layer may be predicted as a function of time, knowing the mean initial temperature gradient. The experimental values are associated well with the theoretical values computed for value of the universal constant $C_r$= 0.16, our $C_r$ value is little smaller than the value found by Townsend and Deardoru et al.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.35-41
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• 2003

Laboratory procedures are available for estimating contaminant migration from sediment into caps by diffusion, but diffusion may not be the major process affecting capping effectiveness. Movement of contaminated pore water from sediment into caps due to sediment consolidation during and after cap placement may be much more significant than contaminant diffusion into caps. To verify this phenomenon, model tests were conducted by utilizing a research centrifuge. In this study, test was modeled for 22.5 hours at 100 g, which modeled a contaminant migration time of 25 years for a prototype that was 100 times larger than the centrifuge model. Centrifuge test results illustrate that advection and dispersion due to consolidation are dominating the migration of contaminants.

• Journal of Ocean Engineering and Technology
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• v.18 no.6 s.61
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• pp.22-28
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• 2004

A mathematical model has been developed to evaluate the capability of sea water exchanges under tidal and diffusive environments and has been verified through comparison with numerical experiments. From the mathematical analysis, this study presents the rates of sea water exchanges due to the tidal inflow and diffusion process. The port characteristic length $L_p$ is the most significant evaluation index.

• Journal of the Korean earth science society
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• v.39 no.4
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• pp.317-326
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• 2018

Effect of the nonuniform grid on the two-dimensional transport equation was investigated in terms of theoretical analysis and finite difference method (FDM). The nonuniform grid having a typical structure of the numerical weather forecast model was incorporated in the vertical direction, while the uniform grid was used in the zonal direction. The staggered and non-staggered grid were placed in the vertical and zonal direction, respectively. Time stepping was performed with the third-order Runge Kutta scheme. An error analysis of the spatial discretization on the nonuniform grid was carried out, which indicated that the combined effect of the nonuniform grid and advection velocity produced either numerical diffusion or numerical adverse-diffusion. An analytic function is used for the quantitative evaluation of the errors associated with the discretized transport equation. Numerical experiments with the non-uniformity of vertical grid were found to support the analysis.