• Title/Summary/Keyword: environmental diffusion

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The coupling effect of drying shrinkage and moisture diffusion in concrete

  • Suwito, A.;Ababneh, Ayman;Xi, Yunping;Willam, Kaspar
    • Computers and Concrete
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    • v.3 no.2_3
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    • pp.103-122
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    • 2006
  • Drying shrinkage of concrete occurs due to the loss of moisture and thus, it is controlled by moisture diffusion process. On the other hand, the shrinkage causes cracking of concrete and affects its moisture diffusion properties. Therefore, moisture diffusion and drying shrinkage are two coupled processes and their interactive effect is important for the durability of concrete structures. In this paper, the two material parameters in the moisture diffusion equation, i.e., the moisture capacity and humidity diffusivity, are modified by two different methods to include the effect of drying shrinkage on the moisture diffusion. The effect of drying shrinkage on the humidity diffusivity is introduced by the scalar damage parameter. The effect of drying shrinkage on the moisture capacity is evaluated by an analytical model based on non-equilibrium thermodynamics and minimum potential energy principle for a two-phase composite. The mechanical part of drying shrinkage is modeled as an elastoplastic damage problem. The coupled problem of moisture diffusion and drying shrinkage is solved using a finite element method. The present model can predict that the drying shrinkage accelerates the moisture diffusion in concrete, and in turn, the accelerated drying process increases the shrinkage strain. The coupling effects are demonstrated by a numerical example.

Diffusive Estimation of the Conservative Contaminant in River Estuary (하구의 보존성 오염물질 확산 예측)

  • Yoon, Jong-Su;Shin, Chan-Ki;Hwang, Dong-Jin
    • Journal of environmental and Sanitary engineering
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    • v.23 no.3
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    • pp.47-57
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    • 2008
  • This study was predicted the diffusion of the conservative contaminant using a two-dimensional hydraulic model. The research area is upper basin of Jakwang river where the possibility where the pollutant of vast quantity will flow is high. Using SMS model, we calculated two-dimensional stream flow. And using this result, predicted the conduct of the conservative contaminant by pollutant transfer diffusion calculation. And also we predicted flow and contaminant diffusion in the near estuary by constructed guide bank. As a result of study, pollutant effect scope of the conservative contaminant was predicted with the fact that will broaden because of interception by guide bank. As discharge was increased from the Jakwang river, The diffusion of the pollutant is accelerated, also the effect scope increases.

A WSR-88D Radar Observation of Chaff Transport and Diffusion in Clear Sky

  • Lee, Dong-In
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.263-271
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    • 2000
  • To investigate the distribution of air pollutants dispersion in the horizontal wind fields, a chaff release experiment was carried out by an airplane. The temporal and spatial variations of a chaff plume from an elevated point source using the WSR-88D(NEXRAD) radar. The observed profiles of radar reflectivity were compared with the Gaussian diffusion model at slightly unstable atmospheric condition. The present study shows that the distributions of radar reflectivity from chaffs and their concentration by the model are in general agreement with time variation. The dispersion coefficients in downwind($\sigma$(sub)x) and crosswind($\sigma$(sub)y) spread data exceeded what has generally been found at Pasquill and Brigg\`s estimates. As a result, it was clearly shown that horizontal and vertical diffusion coefficients are more accurately determined as compared with theoretical coefficients. At longer diffusion distances(than 10km), a radar observation provided the determination of maximum range and diffusion height more qualitatively, too.

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The Determination of Diffusion and Partition Coefficients of PUF (폴리우레탄 폼의 휘발성 유기화합물 확산 및 분배계수 산정)

  • Park, Jin-Soo;Little, John C.;Kim, Shin-Do;Lee, Hee-Kwan;Kong, Boo-Ju
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.77-84
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    • 2010
  • The diffusion and partition coefficients of polyurethane foam (PUF) are estimated using a microbalance experiment and small chamber test. The microbalance is used to measure sorption/desorption kinetics and equilibrium data. When the diffusion condition is controlled in the chamber of the sample, interactions between volatile organic compounds (VOCs) and PUF can lead to the estimation of a relatively homogenous rate of mass transfer in the interiors and surfaces of PUF. The estimates of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) are shown to be independent of the concentrations of VOCs. This approach, if applied to a diffusion-controlled or physically-based model, can facilitate more precise prediction of their source/sink behavior. Although further research and more rigorous validation is needed, an emission model applied with the diffusion and partition coefficients from this research holds promise for the improvement of reliability in predicting the behavior of VOCs emitted from porous building materials by D and K.

Classification of Nanoparticles by Inertial/Diffusion Filter (관성/확산필터를 이용한 나노입자의 분류기술 연구)

  • Kim, Yonggu;Lee, Sangyul;Kim, Hannah;Noh, Hakjae;Bong, Choonkeun;Kim, Daesung
    • Particle and aerosol research
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    • v.11 no.2
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    • pp.29-36
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    • 2015
  • The purpose of this research is to find out the collection property of nanoparticle in diffusion filter to know particle size dispersion of nanomaterial using inertial force and principle of Brownian diffusion motion. We used inertial filters which are two different type and diffusion filters made by various kinds of Wiremesh and the different pieces of filter to compare with particle size distribution using NaCl particles. Finally, We made a conclusion as follows : (1) the bigger available charging volume is and the larger specific surface area of inertial filter is, the better collection efficiency is. (2) The higher wire-mesh number of filter is, the more collection efficiency of small particle is increasing because the wire of the higher Wiremesh number filter is thinner and denser. (3) The more pieces of wire-mesh filter, the more collection efficiency is increasing because it makes the residence time longer.

Forward and Back Diffusion from Low Permeability Zone: A Review of Analytical Solutions with Different Boundary Conditions (저투수성 매체 내 오염물질의 정확산과 역확산: 경계조건에 따른 용질이동 해석해의 소개)

  • Kim, Changmin;Yang, Minjune
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.99-110
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    • 2020
  • It is a global trend to consider contaminated low-permeability zones as one of the primary management targets for the remediation of DNAPL contaminated sites. In addition, studies on the persistence caused by back diffusion of DNAPLs from low-permeability zones have been actively conducted worldwide. On the other hand, the studies for domestic groundwater contamination with the low-permeability zones are insufficient. Therefore, this study introduces the forward and back diffusions of DNAPL through low-permeability zones and suggests the importance of them by reviewing representative previous studies, especially on back diffusion and plume persistence. We proposed six diffusion scenarios and analytical solutions based on various boundary conditions of low-permeability zones. FI (forward diffusion into infinite domain) and BI (back diffusion form infinite domain) scenarios illustrate forward and back diffusion in which the depths of a low-permeability layer are assumed to be infinite. FFN (forward diffusion into finite domain with no flux boundary) and BFN (back diffusion from finite domain with no flux boundary) scenarios describe forward and back diffusion for a finite domain of a low-permeability layer with no flux boundary at the bottom. When the bottom of a low-permeability layer is considered as flux boundary, forward and back diffusion scenarios correspond to FFF (forward diffusion into finite domain with flux boundary) and BFF (back diffusion from finite domain with flux boundary). The scenarios and analytical solutions in this study may contribute to the determination of an efficient remediation method based on site characteristics such as a thickness of low-permeability zones or duration of contamination exposure.

Comparison study of turbulent diffusion coefficient using Smagorinsky method and 2-level method (Smagorinsky method와 2-level method를 이용한 난류 확산계수의 비교 연구)

  • 이화운;오은주;정우식;최현정;임주연
    • Journal of Environmental Science International
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    • v.11 no.7
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    • pp.679-686
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    • 2002
  • Turbulence greatly influence on atmospheric flow field. In the atmosphere, turbulence is represented as turbulent diffusion coefficients. To estimate turbulent diffusion coefficients in previous studies, it has been used constants or 2-level method which divides surface layer and Ekman layer. In this study, it was introduced Smagorinsky method which estimates turbulent diffusion coefficient not to divide the layer but to continue in vertical direction. We simulated 3-D flow model and TKE equation applied turbulent diffusion coefficients using two methods, respectively. Then we showed the values of TKE and the condition of each term to TKE. The results of Smagorinsky method were reasonable. But the results of 2-level method were not reasonable. Therefor, it had better use Smagorinsky method to estimate turbulent diffusion coefficients. We are expected that if it is developed better TKE equation and model with study of computational method in several turbulent diffusion coefficients for reasonably turbulent diffusion, we will able to predict precise wind field and movements of air pollutants.

The Determination of Diffusion and Partition Coefficients of Indoor Bottom Finishing Materials (바닥재의 확산계수 및 분배계수 산정)

  • Park, Jin-Soo;Little, John C.;Kim, Shin-Do;Yun, Joong-Seop
    • Journal of Environmental Health Sciences
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    • v.34 no.3
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    • pp.219-225
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    • 2008
  • Many building materials may contain high concentrations of volatile organic compounds (VOCs) and other hazardous pollutants(HAPs). Specifically, VOCs discharged by indoor building material may cause "new house" syndrome, atopic dermatitis etc. The diffusion coefficient and initially contained total VOC quantity were determined using microbalance experiments and small chamber tests. Interactions between volatile organic compounds (VOCs) and vinyl flooring (VF), a relatively homogenous, diffusion-controlled building material, were characterized. Rapid determination of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) for each VOC was achieved by placing thin VF slabs in a dynamic microbalance and subjecting them to controlled sorption/desorption cycles. K and D are shown to be independent of concentration for all of the VOCs and water vapor. This approach can be applied to other diffusion-controlled materials and should facilitate the prediction of their source/sink behavior using physically-based models.

Realtime Air Diffusion Prediction System

  • Kim Youngtae;Kim Tae KooK;Oh Jai-Ho
    • 한국전산유체공학회:학술대회논문집
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    • 2003.10a
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    • pp.88-90
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    • 2003
  • We implement Realtime Air Diffusion Prediction System which is designed for air diffusion simulations with four-dimensional data assimilation. For realtime running, we parallelize the system using MPI (Message Passing Interface) on distributed-memory parallel computers and build a cluster computer which links high-performance PCs with high-speed interconnection networks. We use 162­CPU nodes and a Myrinet network for the cluster

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Removal of Phenols by Granular Activated Carbon in Aqueous Solution (수용액에서 입상활성탄에 의한 페놀류의 제거)

  • 권성헌;강원석
    • Journal of Environmental Science International
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    • v.7 no.4
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    • pp.541-548
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    • 1998
  • Aqueous phase adsorption of phenols by granular activated carbon was studied in a batch adsorption vessel. Adsorption Isotherms of phenol(Ph), p-chlorophenol(PCP) and p-nitrophenol (PNP) from aqueous solution on granular activated carbon have been obtained. The experimental data were analyzed by the surface and pore diffusion models. Both models could be applied to predict the adsorption phenomena. However, the pore diffusion model was slightly better than the surface diffusion model In representing the experimental data for the initial concentration changes. Therefore, the pore diffusion model was used to predict the change of operating variables such as the agitation speed and Particle size of adsorbent which have influence on the film resistance and intraparticle diffusion.

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