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A Study on the Reaction Characteristics of Steam Reforming Reaction over Catalyzed Porous Membrane (다공성 촉매 분리막을 이용한 수증기 개질 반응 특성 연구)

  • Hong, Sung Chang;Lee, Sang Moon
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.198-203
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    • 2014
  • In this study, steam reforming reaction and surface characteristics of Ni metal foam plate were investigated. Valence state of Ni could be changed by pretreatment, and metallic Ni species exposed on surface as a active site play important role in steam reforming reaction. Porous catalytic membrane also was prepared by mixing of Ni metal foam plate and Ni-YSZ catalyst to control the pore size and assign the catalytic function in Ni metal foam plate. In SEM analysis results, Pore size of Ni metal foam plate could be controlled and Ni-YSZ catalyst well dispersed on surface. Ni based porous catalytic membrane had a similar steam reforming activity regardless of space velocity.

Curved Hull Plate Forming based on SOAP Internet Services (인터넷 서비스 기반의 선체외판 가공 연구)

  • Kim, Chan Suk;Son, Seung Hyeok;Shin, Jong Gye;Lee, Philippe
    • Journal of the Society of Naval Architects of Korea
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    • v.53 no.1
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    • pp.69-75
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    • 2016
  • Fabrication of the hull plate demands a lot of man-hour and a high degree of technology. In recent years, commercial shipping orders have been fallen because of intensifying competition with low price of order and labor cost. In order to solve this problem, a countermeasure such as a cost reduction is required. In this study, we are dealing with the method of supplying the forming information of the hull to the production site. We reviewed studies of hull forming that have been proposed so far to develop a method for providing hull forming information. On the basis of given production plans from the production site of shipyard, we discuss how to convert shell plate to production plan. Then, we will discuss the efficiency of the distribution method through the network about the method of hull forming. Thus, we have modified the distribution method which was proposed before. Finally, we will introduce the enhanced method for providing fabrication information of the hull plate to the small and medium-sized shipyards.

Inactivation of Brain Succinic Semialdehyde Reductase by o-Phthalaldehyde

  • Song, M.S.;Lee, B.R.;Jang, S.H.;Cho, S.W.;Park, S.Y.
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1995.04a
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    • pp.75-75
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    • 1995
  • Succinic semialdehyde reductase, one of key enzyme of GABA shunt in CNS, is inactivated by o-phthalaldehyde, The inactivation followed pseudo first-order kinetics, and the second-order rate constant for the inactivation process was 28 M$\^$-1/s$\^$-1/ at pH 7.4 and 25$^{\circ}C$. The absorption spectrum(λ$\_$max/=377nm), fluorescence exitation(λ$\_$max/=340nm) and fluorescence emission spectra (λ$\_$max/=409nm) were consistent with the formation of an isoindole derivative in the catalytic site between a cysteine and a lysine residues about 3${\AA}$ apart. The substrate, succinic semialdehyde, did not protect the enzymatic activity against inactivation, whereas the coenzyme, NADPH, protected against o-phthalaldehyde induced inactivation of the enzyme. About 1 isoindole group per moi of the enzyme was formed following complete loss of the enzymatic activity. These results suggest that the amino acid residues of the enzyme participating in reaction with o-phthalaldehyde more likely residues at or near the coenzyme binding site.

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The Effects of Al-substitution on Thermoelectric and Charge Transport Properties of BiCuOSe Compounds (Al 치환이 BiCuOSe의 열전 특성에 미치는 영향)

  • An, Tae-Ho;Lim, Young Soo;Seo, Won-Seon;Park, Cheol-Hee;Park, Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.847-851
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    • 2015
  • The effects of Al-substitution on thermoelectric and charge transport properties of BiCuOSe compounds were investigated. The compounds were prepared by a solid-state reaction and consolidated by SPS (spark plasma sintering). In spite of the increase in the hole concentration with increasing Al amounts in BiCuOSe compound, the electrical conductivity at room temperature was kept constant due to the reduction of mobility. However, electrical conductivities of Al-substituted BiCuOSe compounds at elevated temperature (> 600 K) were higher than those of BiCuOSe, and this result was discussed in terms of it's the band gap energy. The Seebeck coefficient was drastically reduced when Al was substituted in Bi site, which indicated that the electronic structure was influenced by the Al-substitution into Bi-site.

Analysis on Correlation Coefficient of Surface Image Velocimeter (SIV) Using On-site Runoff Image (현장유출영상을 활용한 표면영상유속계(SIV)의 상관계수 분석)

  • Kim, Yong-Seok;Yang, Sung-Kee;Kim, Dong-Su;Kim, Seojun
    • Journal of Environmental Science International
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    • v.24 no.4
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    • pp.403-414
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    • 2015
  • This study is daytime and nighttime runoff image data caused by heavy rain on May 27, 2013 at Oedo Water Treatment Plant of Oedo-Stream, Jeju to compute runoff by applying Surface image velocimeter (SIV) and analyzing correlation according to current. At the same time, current was comparatively analyzed using ADCP observation data and fixed electromagnetic surface current meter (Kalesto) observed at the runoff site. As a result of comparison on resolutions of daytime and nighttime runoff images collected, correlation coefficient corresponding to the range of 0.6~0.7 was 6.8% higher for nighttime runoff image compared to daytime runoff image. On the contrary, correlation coefficient corresponding to the range of 0.9~1.0 was 17% lower. This result implies that nighttime runoff image has lower image quality than daytime runoff image. In the process of computing current using SIV, a rational filtering process for correlation coefficient is needed according to images obtained.

Development of a quality evaluation method and computer program of Sand Compaction Pile (모래다짐말뚝의 품질평가 방법과 프로그램의 개발)

  • Jeon, Heung-Soo;Im, Jong-Chul;Kang, Yeoun-Ike;Kwon, Jeong-Geun;Joo, In-Gon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1132-1140
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    • 2009
  • Recently soil improvement methods are using in many ways such as costal and soft ground of inland. Among them, sand compaction pile be widely used because of quiet few advantages. There are two ways for quality evaluation method of sand compaction pile. Especially standard penetration test is used the most general method. However, Current method have problems in that it is not consider the condition of construction site. Therefore this study is propose new quality evaluation method. Relation of N-$\Phi$ is always not fixed but changing by condition of construction site. By through the Laboratory test we can know relationship between relative density and internal friction. Also this study propose revision for effective stress. From these study, we can acquire more accurate and reasonable result than current method.

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Effect of PBD to improve soft marine sedimentary ground

  • Jeong, Jin-Seob;Hwang, Woong-Ki;Jeong, Choong-Gi;Kim, Tae-Hyung
    • Journal of Navigation and Port Research
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    • v.33 no.2
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    • pp.119-125
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    • 2009
  • The effect of plastic board drains (PBDs)on ground improvement was checked out considering three crucial factors: ground settlement, undrained shear strength, and residual water head. First, the settlement analysis including initial settlement induced by reclamation of sand mat was conducted by back calculation analysis with measured data. Its result showed toot the PBDs used for this site worked well on improving soft ground. Secondly, the undrained shear strength was investigated by laboratory and in-situ tests including unconsolidated-undrained triaxial compression (UU) tests, unconfined compression tests, in-situ vane tests, and cone penetration tests. From the test results, they showed that the undrained shear strength of the improved ground by PBDs was significantly increased as well as the strength increasing ratio especially $10{\sim}15m$ below the ground surface on site. Thirdly, the residual water head measurement from the in situ dissipation test was found the same as the static water head, which indicated primary consolidation was completed and the effect of soil improvement with PBDs can be confirmed.

A Genetic Algorithm for Directed Graph-based Supply Network Planning in Memory Module Industry

  • Wang, Li-Chih;Cheng, Chen-Yang;Huang, Li-Pin
    • Industrial Engineering and Management Systems
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    • v.9 no.3
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    • pp.227-241
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    • 2010
  • A memory module industry's supply chain usually consists of multiple manufacturing sites and multiple distribution centers. In order to fulfill the variety of demands from downstream customers, production planners need not only to decide the order allocation among multiple manufacturing sites but also to consider memory module industrial characteristics and supply chain constraints, such as multiple material substitution relationships, capacity, and transportation lead time, fluctuation of component purchasing prices and available supply quantities of critical materials (e.g., DRAM, chip), based on human experience. In this research, a directed graph-based supply network planning (DGSNP) model is developed for memory module industry. In addition to multi-site order allocation, the DGSNP model explicitly considers production planning for each manufacturing site, and purchasing planning from each supplier. First, the research formulates the supply network's structure and constraints in a directed-graph form. Then, a proposed genetic algorithm (GA) solves the matrix form which is transformed from the directed-graph model. Finally, the final matrix, with a calculated maximum profit, can be transformed back to a directed-graph based supply network plan as a reference for planners. The results of the illustrative experiments show that the DGSNP model, compared to current memory module industry practices, determines a convincing supply network planning solution, as measured by total profit.

Characteristics of crater formation due to explosives blasting in rock mass

  • Jeon, Seokwon;Kim, Tae-Hyun;You, Kwang-Ho
    • Geomechanics and Engineering
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    • v.9 no.3
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    • pp.329-344
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    • 2015
  • Cratering tests in rock are generally carried out to identify its fragmentation characteristics. The test results can be used to estimate the minimum amount of explosives required for the target volume of rock fragmentation. However, it is not easy to perform this type of test due to its high cost and difficulty in securing the test site with the same ground conditions as the site where blasting is to be performed. Consequently, this study investigates the characteristics of rock fragmentation by using the hydrocode in the platform of AUTODYN. The effectiveness of the numerical models adopted are validated against several cratering test results available in the literature, and the effects of rock mass classification and ground formation on crater size are examined. The numerical analysis shows that the dimension of a crater is increased with a decrease in rock quality, and the formation of a crater is highly dependent on a rock of lowest quality in the case of mixed ground. It is expected that the results of the present study can also be applied to the estimation of the level and extent of the damage induced by blasting in concrete structures.

Reaction of Tri-methylaluminum on Si (001) Surface for Initial Aluminum Oxide Thin-Film Growth

  • Kim, Dae-Hee;Kim, Dae-Hyun;Jeong, Yong-Chan;Seo, Hwa-Il;Kim, Yeong-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3579-3582
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    • 2010
  • We studied the reaction of tri-methylaluminum (TMA) on hydroxyl (OH)-terminated Si (001) surfaces for the initial growth of aluminum oxide thin-films using density functional theory. TMA was adsorbed on the oxygen atom of OH due to the oxygen atom’s lone pair electrons. The adsorbed TMA reacted with the hydrogen atom of OH to produce a di-methylaluminum group (DMA) and methane with an energy barrier of 0.50 eV. Low energy barriers in the range of 0 - 0.11 eV were required for DMA migration to the inter-dimer, intra-dimer, and inter-row sites on the surface. A unimethylaluminum group (UMA) was generated at each site with low energy barriers in the range of 0.21 - 0.25 eV. Among the three sites, the inter-dimer site was the most probable for UMA formation.