• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.604-610
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• 2023

The nitrogen reduction reaction (NRR), which produces NH₃ by reducing N₂ under ambient conditions, is attracting attention as a promising technology that can reduce energy consumption in industrial processes. We investigated the adsorption behaviors at various active sites on the Ni (100) surface, which is widely used among catalytic metal surfaces capable of adsorbing and activating N₂, based on density-functional theory calculations. We also investigated two N₂ adsorption structures, so-called end-on and side-on structures. We find that for the end-on case, N₂ is adsorbed on a top site, and the reaction proceeded in a distal pathway, while for the side-on case, N₂ is adsorbed on a bridge site, and the reaction proceeded with enzymatic pathway. Finally, this study provides insight into the adsorption of metal catalyst surfaces for the NRR reactions based on the calculated Gibbs free energy profiles of the thermodynamically most favorable pathways.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.803-810
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• 1998

We have studied the catalytic combustion of soot particulate over perovskite-type oxides prepared by malic acid method. The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxide. In addition, the reaction conditions, such as temperature, $O_2$ concentration, space velocity have been studied. The effect of $SO_2$ pretreatment and water introduced into reactants were also examined. In the $LaCoO_3$ catalyst, the partial substitution of alkali metals into A site enhanced the catalytic activity in the combustion of soot particulate and the activity was shown in the order : Cs>K>Na; In the $La_{0.6}Cs_{0.4}CoO_3 $; catalyst, the substitution of Fe or Mn showed no effect on the ignition temperature. The ignition temperature decreased with increasing $O_2$ concentration and contact time. The introduction of water into reactants feed decreased the ignition temperature and the pretreatment of $SO_2$ showed no effect on the catalytic activity.

• Journal of the Earthquake Engineering Society of Korea
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• v.14 no.4
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• pp.1-15
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• 2010

In this study, the reduction factor of the code-defined site coefficient due to the embedment of a foundation was estimated for the seismic analysis of a building built on a soft soil site. This was done by utilizing the in-house finite element software P3DASS, which has the capability of pseudo 3D seismic analysis with nonlinear soil layers. A 30m thick soft soil site laid on the rock was assumed to be homogeneous, elastic, viscous and isotropic, and equivalent circular rigid foundations with radii of 10-70m were considered to be embedded at 0, 10, 20 and 30m in the soil layer. Seismic analyses were performed with 7 bedrock earthquake records deconvoluted from the outcrop records of which the effective ground acceleration was scaled to 0.1g. The study results showed that the site coefficients are gradually reduced except in the case of a small foundation embedded deeply in the weak soil layer, and it was estimated that the deviation of the site coefficients due to the foundation size was not significant. The standard reduction factor due to the foundation embedment were calculated adding the standard deviation to the average of 5 reduction factors calculated for 5 different foundation radii. Standard reduction factors for the site amplification factor were proposed for the practical amplification and the codes of KBC, etc., in accordance with the average shear wave velocity of the site, and the site class.

• International conference on construction engineering and project management
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• 2022.06a
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• pp.1243-1244
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• 2022

In recent years, the growing interest in off-site construction has led to factories scaling up their manufacturing and production processes in the construction sector. Consequently, continuous large-scale site monitoring in low-variability environments, such as prefabricated components production plants (precast concrete production), has gained increasing importance. Although many studies on computer vision-based site monitoring have been conducted, challenges for deploying this technology for large-scale field applications still remain. One of the issues is collecting and transmitting vast amounts of video data. Continuous site monitoring systems are based on real-time video data collection and analysis, which requires excessive computational resources and network traffic. In addition, it is difficult to integrate various object information with different sizes and scales into a single scene. Various sizes and types of objects (e.g., workers, heavy equipment, and materials) exist in a plant production environment, and these objects should be detected simultaneously for effective site monitoring. However, with the existing object detection algorithms, it is difficult to simultaneously detect objects with significant differences in size because collecting and training massive amounts of object image data with various scales is necessary. This study thus developed a large-scale site monitoring system using edge computing and a small-object detection system to solve these problems. Edge computing is a distributed information technology architecture wherein the image or video data is processed near the originating source, not on a centralized server or cloud. By inferring information from the AI computing module equipped with CCTVs and communicating only the processed information with the server, it is possible to reduce excessive network traffic. Small-object detection is an innovative method to detect different-sized objects by cropping the raw image and setting the appropriate number of rows and columns for image splitting based on the target object size. This enables the detection of small objects from cropped and magnified images. The detected small objects can then be expressed in the original image. In the inference process, this study used the YOLO-v5 algorithm, known for its fast processing speed and widely used for real-time object detection. This method could effectively detect large and even small objects that were difficult to detect with the existing object detection algorithms. When the large-scale site monitoring system was tested, it performed well in detecting small objects, such as workers in a large-scale view of construction sites, which were inaccurately detected by the existing algorithms. Our next goal is to incorporate various safety monitoring and risk analysis algorithms into this system, such as collision risk estimation, based on the time-to-collision concept, enabling the optimization of safety routes by accumulating workers' paths and inferring the risky areas based on workers' trajectory patterns. Through such developments, this continuous large-scale site monitoring system can guide a construction plant's safety management system more effectively.

• Journal of the Korean Geotechnical Society
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• v.28 no.5
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• pp.109-120
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• 2012

In marine site surveys, drilling boreholes are restrictively conducted, while geophysical surveys are used with ease. To overcome the limitations of marine site survey, various site survey data should be collected and analysed by adopting complementary pros and cons. In this study, the integration assessment was established to digitize 2D geo-layer based on the overlapping of a few borehole data to seismic refraction tomography and to determine 3D geo-information based on the kriging for the design of offshore-foundation. And the overlapping method was proposed considering spatial variability of the tomography and separation distance from borehole position to determine the 2D geo-layer. Finally, the integration assessment was applied to offshore wind-turbine site in Jeju-do, and its applicability was verified based on the cross-validation.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.349-360
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• 2009

The cone penetration test(CPT) has gained its popularity in site characterization indebted by its reliability, speed, economy, and automatic measurement system since its development in the 1930s. The CPT results, commonly consisting of cone tip resistance, sleeve friction, and pore water pressure measurements, allow us to classify soils as well as to reveal their engineering characteristics. The site condition at which the CPT is allowable is often dependent on the capacity of a CPT system. In Korea, it has been considered that the CPT could be appled only to soft soils in most cases because CPT systems available for stiff soils are very rare due to their expensive procurement and maintenance cost. Luoisiana Transportation Research Center(LTRC) has developed and implemented a field-rugged continuous intrusion miniature cone penetration test(CIMCPT) system since the late 1990s. The miniature cone penetrometer has a sectional cone area of $2cm^2$ allowing system capacity reduction compared to the standard $10cm^2$ cone penetrometer. The continuous intrusion mechanism allows fast and economic site investigation. Samsung Engineering & Construction has recently developed and implemented a similar CIMCPT system based on its original version developed in LTRC. The performance of the Samsung CIMCPT system has been investigated by calibration with the standard CPT system at a well-characterized test site in Pusan, Korea. In addition, scale effect between the miniature cone penetrometer and the standard cone penetrometer has been investigated by comparing the field test results using the both systems.

• The Proceeding of the Korean Institute of Electromagnetic Engineering and Science
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• v.3 no.1
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• pp.28-32
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• 1992

The site attenuation for vertical polarization was theoretically calculated using EMF(electro- Motive force) method and measured for 3-m method in the KRISS semi-anechoic chamber. Agreement within .+-. 4 dB has been obtained between measured and calculated values in the frequency range of 30 MHz to 1000 MHz except 250 MHz and around 100 MHz.

• Annual Conference of KIPS
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• 2002.11c
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• pp.1915-1918
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• 2002

Managing semistructured data needs fine granularity such as markup elements. XML has major effect in managing web content, it enables content reusability, enriches information with metadata, ensures valid document links, etc. We introduce our content model as an integrated work which handles content objects as controllable units. The paper concerns on modeling news site and how the content is classified due to the site structure, aggregated content and reusability. The model stores instance XML document into relation database using fragmentation strategy.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2009.04a
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• pp.155-156
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• 2009

Construction companies can easily understand present noise condition of their construction site via C-Noise. C-Noise is noise simulation software that simple to use. Construction companies spend time and cost for public complaints about construction noise. Construction site noise management using noise simulation software like C-Noise can reduce public complaint. achieve cost reduction to treat it.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2001.09a
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• pp.28-35
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• 2001

Liquefaction potential on the specific site of nuclear power plant is analyzed and reviewed. The layered site fur this study consists of silt and sand. Based on the limited available soil data, maximum shear strength at critical locations using Seed & Idriss method and computer program SHAKE is calculated, and liquefaction potential is reviewed. Seismic input motion used fur the assessment of liquefaction is the artificial time history compatible with the US NRC regulatory Guider .60. Assessment results of the liquefaction are validated by analyzing to the other typical soil fecundations which can show the effects of foundation depth and soil data.