• Journal of the Korean Chemical Society
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• v.9 no.1
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• pp.8-15
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• 1965

Justifications for the use of ${\sigma}$ and Y as independent potential energy variables in the general equation have been reviewed and some mechanistic significances of the relationship discussed. Analysis of the activation parameters for the solvolysis of benzyl chlorides in ethanol-water mixture showed that there are two distinct series of substrate constants ${\alpha}'$, which can be correlated linearly within a series with the substituent constants ${\sigma}$ conforming to the generally accepted concept of change in mechanism from $S_N1$ to $S_N2$.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1999.04a
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• pp.169-176
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• 1999

An improved formulation for spatial stability md free vibration of thin-walled curved beams with variable curvature and non-symmetric cross sections are presented based on the displacement field considering the second order terms of finite semitangential rotations. By introducing Vlasov's assumptions, the total potential energy is derived from the principle of linearized virtual work for a continuum. In this formulation, all displacement parameters and the warping function are defined at the centroid axis so that the coupled terms of bending and torsion are added to the elastic strain energy. Also, the potential energy due to initial stress resultants is consistently derived corresponding to the semitangential rotation and moment. The cubic Hermitian polynomials are utilized as shape functions for development of the curved thin-walled beam element having eight degrees of freedom. In order to illustrate the accuracy and practical usefulness of this study, . numerical solutions for free vibration of arches are presented and compared with resells of other researchers and solutions analyzed by the ABAQUS's shell element.

• Proceedings of the KIEE Conference
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• 1995.11a
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• pp.472-474
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• 1995

A Sputter ion Plating(SIP) system with a r.f. coil electrode and the Facing Target Sputter(FTS) source was designed for high-quality thin film formation. The rf discharge was combined with DC facing target sputtering in order to enhance ionization degree of a sputtered atoms. The energy of ions incident on the substrate depended on the health potential of DC biased substrate. The mean impact ion energy increased with negative bias voltage and rf power. The adhesive force of the TiN film formed was in the range of 30$\sim$50N, and markedly influenced by substrate bias voltage.

• Structural Engineering and Mechanics
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• v.76 no.1
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• pp.27-56
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• 2020

In this paper, the deflection and buckling analyses of porous nano-composite piezoelectric plate reinforced by carbon nanotube (CNT) are studied. The equations of equilibrium using energy method are derived from principle of minimum total potential energy. In the research, the non-local strain gradient theory is employed to consider size dependent effect for porous nanocomposite piezoelectric plate. The effects of material length scale parameter, Eringen's nonlocal parameter, porosity coefficient and aspect ratio on the deflection and critical buckling load are investigated. The results indicate that the effect of porosity coefficient on the increase of the deflection and critical buckling load is greatly higher than the other parameters effect, and size effect including nonlocal parameter and the material length scale parameter have a lower effect on the deflection increase with respect to the porosity coefficient, respectively and vice versa for critical buckling load. Porous nanocomposites are used in various engineering fields such as aerospace, medical industries and water refinery.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.24 no.3
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• pp.19-25
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• 2016

In this study, we surveyed the Marado status of the availability of emergency runway for the LSA, through site visits. For the future progress Marado flight tour operation, for LSA of 4 models with respect to just in case there was an emergency situation analysis of the availability of emergency runway. We analyzed the problems of the sloping runway with the changing elements for the kinetic and potential energy. The Bingo and CH-650 models of LSA are usability emergency runway of Marado for take-off and landing. But the AT-4 and CTLS models of LSA are limited or impossible to use emergency runway of the Marado.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.5
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• pp.855-861
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• 1989

An inertia redistribution technique for liberalizing and reducing the complexity of manipulator dynamics with a parallel drive mechanism is presented in this paper. The dynamic design method is based on eliminating nonlinear terms, such as Coriolis, centrifugal and gravity torque in the kinetic and the potential energy of a manipulator. A set of design criteria regarding the inertia properties of links is derived. The resulting manipulator dynamics can be greatly simplified for each robot. This paper particularly presents that it is possible to completely linearize the manipulator dynamics with a parallel drive mechanism.

• Coupled systems mechanics
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• v.6 no.1
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• pp.17-28
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• 2017

In this work, we extend the previously developed split kinetic energy (dubbed KEP) method by Mineo and Chao (2012) by modifying the mass parameter to include the negative mass. We first show how to separate the total system into the subsystems with 3 attractive delta potentials by using the KEP method. For repulsive delta potentials, we introduce "negative" mass terms. Two cases are demonstrated using the "negative" mass terms for repulsive delta potential problems in quantum mechanics. Our work shows that the KEP solution scheme can be used to obtain not only the exact energies but also the exact wavefunctions very precisely.

• Bulletin of the Korean Chemical Society
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• v.19 no.9
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• pp.985-993
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• 1998

The second order effective valence shell Hamiltonian ($H^v$), which is based on quasidegencrate many-body perturbation theory, is applied to determining the potential energy surfaces and the dipole moment functions of the various valence states of $NH_2$. The $H^v$ calculated values are found to be in good agreement with those of other ab initio calculations or experiments. It signifies the fact that the $H^v$ is a good ab initio method to describe the energies and properties of various valence states with a same chemical accuracy. Furthermore, it is shown that the lowest (second order for energy and the first order for property) order $H^v$ method is very accurate for small molecules like $NH_2$ and the matrix elements of Hv which are computed only once are all we need to accurately describe all the valence states simultaneously.

• Bulletin of the Korean Chemical Society
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• v.13 no.4
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• pp.385-388
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• 1992

The transition probabilities for the thermal intramolecular electron transfer and the optical intervalence transfer band for a symmetric mixed-valence Cu(I)-Cu(II) compound were used to extract the PKS parameters $\varepsilon$ = -1.15, ${\lambda}$ = 2.839, and ${\nu}g$- = 923 $cm^{-1}$. These parameters determine the potential energy surfaces and vibronic energy levels. Three pairs of vibrational levels are below the top of the energy barrier in the lower potential surface. The contribution of each vibrational state to the intramolecular electron transfer was calculated. It is shown that the three pairs of vibrational states below the top of the barrier are responsible for most of the electron transfer at 261-306 K. So the intramolecular electron transfer in this system is a tunneling process. The transition probability exhibits the usual high-temperature Arrhenius behavior, but at lower temperature falls off to a temperature-independent value as tunneling from the lowest levels becomes the limiting process.

• Advances in Energy Research
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• v.4 no.3
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• pp.203-211
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• 2016

A good understanding of the chemical composition and structural characteristics of a carbonaceous material is essential in conversion processes. Understanding how the composition and structural changes influence the burning behaviour of coal is important when assessing a coal's potential for utilization. To explore the potentials of a typical Nigerian coal, both conventional and advanced analytical techniques such as proximate analysis, ultimate analysis, calorific value, surface area analyser, SEM, FTIR, XRD and SAXS were employed. The results obtained from these characterizations agree favourable well with a typical South African coal that is of enormous contribution to the gross domestic product (GDP) of the nation economy.