• Title/Summary/Keyword: energy potential

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Photocatal~ic Hydrogen Evolution with Platinum Loaded Cadmium-Iron-Sulfide Mixed Crystal Powders in Aque-ous Media

  • Jo, Cheol Rae;Park, Se Jin;Kim, Ha Seok
    • Bulletin of the Korean Chemical Society
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    • v.21 no.8
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    • pp.805-808
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    • 2000
  • Mixed crystal powders based on Cd,Fe, and S have been synthesized by varying the ratio of CdS and $FeS_2in$ order to find a suitable material usefuI for the effectivc conversion of solar energy. Hydrogen gas was evolved only with CdS/Ptby photocatal ytic reaction under white light in an aqueous 1 M sodiumsulfite solution. From electrochemical studies of semiconductor electrodes. itwas shown that the onset potential shifted to the positive direction and that the bandgap energy also decreased as the molar ratio of Fe increased. A hydrogen evolution mechanism in terms of the conduction band potential and hydrogen evolution potential is proposed.

Electrochemical behavior of dissolved hydrogen at Pt electrode surface in a high temperature LiOH-H3BO3 solution: Effect of chloride ion on the transient current of the dissolved hydrogen

  • Myung-Hee Yun;Jei-Won Yeon
    • Nuclear Engineering and Technology
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    • v.55 no.10
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    • pp.3659-3664
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    • 2023
  • The electrochemical behavior of dissolved hydrogen (H2) was investigated at a Pt electrode in a high temperature LiOH-H3BO3 solution. The diffusion current of the H2 oxidation was proportional to the concentration of the dissolved H2 as well as the reciprocal of the temperature. In the polarization curve, a potential region in which the oxidation current decreases despite an increase in the applied potential between the H2 oxidation and the water oxidation regions was observed. This potential region was interpreted as being caused by the formation of a Pt oxide layer. Using the properties of the Cl- ion that reduces the growth rate of the Pt oxide layer, it was confirmed that there is a correlation between the Cl- ion concentration and the transient current of the H2 oxidation.

Memory of Initial States in Scattering over Attractive Potential Energy Surface for Atom-Diatom Collisions

  • Seung-Ho Choi;Hyung-Rae Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.4
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    • pp.423-429
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    • 1991
  • Global and local memory functions, defined by Quack and Troe, were calculated for the rotationally inelastic collision of O + SO(v, j)→ [O--S--O]→O + SO(v, j'). It is seen to decrease steadily as total energy increases. Distribution of scattering cross section over product rotational states also shows the decreasing memory of initial state as total energy is increased. These results are interpreted in terms of energy scrambling at high energy due to the availability of more phase space and also the influence of strong dynamical constraints.

Are Flywheels Right for Rail?

  • Read, M.G.;Smith, R.A.;Pullen, K.R.
    • International Journal of Railway
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    • v.2 no.4
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    • pp.139-146
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    • 2009
  • Vehicle braking in non-electrified rail systems wastes energy. Advanced flywheel technology presents a way to capture and reuse this braking energy to improve vehicle efficiency and so reduce the operating costs and environmental impact of diesel trains. This paper highlights the suitability of flywheels for rail vehicle applications, and proposes a novel mechanical transmission system to apply regenerative braking using a flywheel energy storage device. A computational model is used to illustrate the operation and potential benefits of the energy storage system.

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Corrosion Behavior of Stainless Steel 304, Titanium, Nickel and Aluminium in Non-Aqueous Electrolytes

  • Dilasari, Bonita;Park, Jesik;Kusumah, Priyandi;Kwon, Kyungjung;Lee, Churl Kyoung
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.26-29
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    • 2014
  • The corrosion behavior of stainless steel 304 (SS 304), titanium, nickel and aluminium is studied by immersion and anodic polarization tests in non-aqueous electrolytes. Tetraethyl ammonium tetrafluoroborate is used as a supporting electrolyte in the three kinds of solvents. The immersion test shows that chemical corrosion rate in propylene carbonate-based electrolyte is lower than those in acetonitrile- or ${\gamma}$-butyrolactone-based electrolytes. Surface analyses do not reveal any corrosion product formed after the immersion test. In the anodic polarization tests, a higher concentration of supporting electrolyte gives a higher current density. In addition, a higher temperature increases the current density in the active region and reduces the potential range in the passive region. SS 304 shows the highest corrosion potential while Al shows the lowest corrosion potential and the highest current density in all studied conditions. Based on the conducted corrosion tests, the corrosion resistance of metal substrates in the organic solvents can be sorted in descending order as follows: SS 304 - Ti - Ni - Al.

Emulsification of Chloroprene Rubber (CR) by Interfacial Chemistry; Stabilization and Enhancement of Mechanical Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.257-265
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    • 2017
  • In this work, CR (Chloroprene Rubber) was emulsified by phase-inversion emulsification with nonionic surfactants (NP-1025, LE-1017, and OP-1019) and an anionic surfactant (SDBS; sodium dodecylbenzenesulfonate), and its stabilization was investigated through a study of its adsorption characteristics, zeta potential, and flow behavior. As the amount of the mixed surfactant increased, the droplet size decreased, resulting in the increase of viscosity. In particular, a CR emulsion with a lower absorbance in the UV spectrum exhibited the highest zeta potential. The results of this experiment showed that the CR emulsion prepared using (LE-1017) and SDBS was the most stable. In this study, calcium hydroxide and aluminum hydroxide were added to enhance the mechanical properties of the CR emulsion, and the relationship between tensile strength, tear strength and surface free energy were investigated. The tensile and tear strengths of the CR emulsion incresed as the amount of calcium hydroxide and aluminum hydroxide increased. The highest tensile and tear strengths and surface free energy were observed for additions of 1.0% calcium hydroxide and 0.80% aluminum hydroxide, respectively. It was concluded that the interfacial bonding strength was improved by the even dispersion of calcium hydroxide and aluminum hydroxide in the CR emulsion.

Research on the Performance of Regenerator using Hot Water from Solar Water Heater(1st paper : On the Effect of Solution Temperature to Regeneration Rate) (태양열 온수기를 이용한 다목적 공조시스템의 재생효율에 관한 연구(제1보 액체흡수제 온도가 재생량에 미치는 영향))

  • Woo, Jong-Soo;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.24 no.1
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    • pp.53-61
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    • 2004
  • Absorption potential of desiccant solution significantly decreases after absorbing moisture from humid air, and a regeneration process requires a great amount of energy to recover absorption potential of desiccant solution. In an effort to develop an efficient solar water heater, this study examines a regeneration process using hot water obtained from solar water heater to recover absorption potential by evaporating moisture in the liquid desiccant. In this paper, a solar absorption dehumidifying system with solar water heater is suggested to save the electricity for operating an air conditioner. LiGl(lithium chloride) solution was adopted as a liquid desiccant in the proposed system, and hot water obtained from the solar water heater was used for regenerating the liquid desiccant. As a result, it was clear that the dilute LiCl solution could be regenerated by hot water, and the regeneration rate depends mostly on temperature level of liquid desiccant. The regeneration rates were about 2.4kg/h with $40^{\circ}C$, 4.0kg/h with $50^{\circ}C$, and 6.2kg/h with $60^{\circ}C$ of hot water respectively.

Tourism Attitude of Deagu Citizens toward the Sustainable Ecotourism (지속가능한 생태관광을 위한 대구시민의 관광태도)

  • Cho, Jin-Hee;Kim, Soo-Bong;Jeon, Eun-Jeong
    • Journal of Environmental Science International
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    • v.18 no.2
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    • pp.177-186
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    • 2009
  • The changes in the worldwide paradigm of the sustainable development have started to be applied in the entire industry fields, and they come out as the sustainable tourism in the field of tourism. And the ecotourism has emerged as a practical method to meet the needs of the actual practice and the intellectual system for the sustainable tourism. In the type of tourists based on tourist attitude, 82.3% has the environment-friendly tourist attitude as a potential ecological tourist or an ecological tourist. In addition, there are the potentials of increase in ecological tourists as well as the revitalization of ecological tourism. First, the ecological tourists are mostly the well-educated and married professional workers at 40, housewives, and people earning a high income. Next, the potential ecological tourists are mainly the well-educated and married professional workers at 30, workers in the service industry, and middle-class citizens. Lastly, the general tourists are the students at 20 who are single, earn a low income, and has low level of education. This study presents useful data to the tourist business in terms of the development, operation and management of sustainable ecological tourism.

A Study on the Floating House for New Resilient Living (새로운 탄력적인 생활을 위한 플로팅 주택에 대한 연구)

  • Moon, Changho
    • Journal of the Korean housing association
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    • v.26 no.5
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    • pp.97-104
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    • 2015
  • This paper aims to discuss the concept of resilience in floating housing, to investigate the resilient features of floating houses & to review the possibility of floating housing as a new form of resilient living, and to suggest some reference ideas for the planning and design of floating housing projects. Resilient features of the floating house can be summarized as the buoyant characteristics for natural disasters, the easy employment & potential use of renewable and nearly self-sufficient energy systems in locations subject to limited energy sources, the movability, mobility, long life, water recycle system, prefabrication and modular construction with the potential for reduced environmental impact. Additional benefits include the potential for a peaceful and comfortable atmosphere due to direct connections with nature, good relationship with neighbors, a solid social spirit of unity, and sense of security. Considering the resilient features of floating house at a time of serious climate change requires a new paradigm, and floating/amphibious/floatable housing has great possibility as a new form of resilient living.

Evaluation of wind loads and the potential of Turkey's south west region by using log-normal and gamma distributions

  • Ozkan, Ramazan;Sen, Faruk;Balli, Serkan
    • Wind and Structures
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    • v.31 no.4
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    • pp.299-309
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    • 2020
  • In this study, wind data such as speeds, loads and potential of Muğla which is located in the southwest of Turkey were statistically analyzed. The wind data which consists of hourly wind speed between 2010 and 2013 years, was measured at the 10-meters height in four different ground stations (Datça, Fethiye, Marmaris, Köyceğiz). These stations are operated by The Turkish State Meteorological Service (T.S.M.S). Furthermore, wind data was analyzed by using Log-Normal and Gamma distributions, since these distributions fit better than Weibull, Normal, Exponential and Logistic distributions. Root Mean Squared Error (RMSE) and the coefficients of the goodness of fit (R2) were also determined by using statistical analysis. According to the results, extreme wind speed in the research area was 33 m/s at the Datça station. The effective wind load at this speed is 0.68 kN/㎡. The highest mean power densities for Datça, Fethiye, Marmaris and Köyceğiz were found to be 46.2, 1.6, 6.5 and 2.2 W/㎡, respectively. Also, although Log-normal distribution exhibited a good performance i.e., lower AD (Anderson - Darling statistic (AD) values) values, Gamma distribution was found more suitable in the estimation of wind speed and power of the region.