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A Study on the Modification of NH4+Y-zeolite for Improving Adsorption/Desorption Performance of Benzene (NH4+Y-zeolite의 개질을 통한 벤젠 흡·탈착 성능 증진 연구)

  • Jang, Young Hee;Noh, Young Il;Lee, Sang Moon;Kim, Sung Su
    • Clean Technology
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    • v.25 no.1
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    • pp.33-39
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    • 2019
  • A.C (activated carbon) is mainly used to remove VOCs (volatile organic compounds), however, it has many problems such as fire risk due to increasing of adsorbent surface temperature during VOCs ad/desorption, increased cost by frequent replacement cycles requirement and performance degradation when containing moisture. In order to solve these problems, many researches, hydrophobic zeolite adsorbents, have been reported. In this study, $NH_4{^+}Y$-zeolite was synthesized with Y-zeolite through steam treatment and acid treatment, which is one of the hydrophobic modification methods, to secure high surface area, thermal stability and humidity resistance. The Y, Y-550-HN, Y-600-HN and Y-650-HN had adsorption capacities of $23mg\;g^{-1}$, $38mg\;g^{-1}$, $77mg\;g^{-1}$, $61mg\;g^{-1}$. The change of Si/Al ratio, which is an index to confirm the degree of modification, was confirmed by XRF (X-ray fluorescence spectrometer) analysis. As a result, the adsorbtion performance was improved when Y-zeolite modified, and the Si/Al ratio of Y, Y-550-HN, Y-600-HN, Y-650-HN were increased to 3.1765, 6.6706, 7.3079, and 7.4635, respectively. Whereas it was confirmed that structural crystallization due to high heat treatment temperature affected performance degradation. Therefore, there is an optimal heat treatment temperature of Y-zeolite, optimum modification condition study could be a substitute for activated carbon as a condition for producing an adsorbent having high durability and stability.

Effect of Aromatic Additives on the Coke Reduction and the Asphaltene Conversion in a Slurry-phase Hydrocracking (슬러리상 수첨분해 반응에서 아로마틱 유분 첨가에 따른 코크 저감 및 아스팔텐 전환 특성)

  • Lim, Suk Hyun;Go, Kang Seok;Nho, Nam Sun;Lee, Jae Goo
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.244-252
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    • 2019
  • This study investigated the effect of addition of aromatics such as Toluene/LCO/resin on the coke depression and asphaltene conversion. The experiment was carried out with vacuum residue as a feedstock with Molybdenum dispersed catalysts under the slurry-phase hydrocracking condition (Temp. of $425^{\circ}C$, $H_2$ pressure of 80 bar at $80^{\circ}C$, reaction time of 4 hr, Mo-concentration of 500 ppm). As results, the coke reduction was shown to be similar irrespective of types of aromatics, while asphaltene was more converted to gas and maltene when LCO and resin with higher dipole moment were added. The addition of aromatics with change of reaction time showed no difference in terms of depression of coke formation. But the addition of LCO rather increased the coke yield after 2 hr. And it was found that asphaltene in liquid phase had the higher aromaticity index so that asphaltene is difficult to disperse in oil phase.

Analysis and Evaluation of CPC / COLSS Related Test Result During YGN 3 Initial Startup (영광 3호기 초기 시운전 동안 CPC / COLSS 관련시험 결과 분석 및 평가)

  • Chi, S.G.;Yu, S.S.;In, W.K.;Auh, G.S.;Doo, J.Y.;Kim, D.K.
    • Nuclear Engineering and Technology
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    • v.27 no.6
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    • pp.877-887
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    • 1995
  • YGN 3 is the first nuclear power plant to use the Core Protection Calculator (CPC) as the core protection system and the Core Operating Limit Supervisory System (COLSS) as the core monitor-ing system in Korea. The CPC is designed to provide on-line calculations of Departure from Nucleate Boiling Ratio (DNBR) and Local Power Density (LPD) and to initiate reactor trip if the core conditions exceed the DNBR or LPD design limit. The COLSS is designed to assist the operator in implementing the Limiting Conditions for Operation (LCOs) in Technical Specifications for DNBR/Linear Heat Rate (LHR) margin, azimuthal tilt, and axial shape index and to provide alarm when the LCOs are reached. During YGN 3 initial startup testing, extensive CPC/COLSS related tests ore peformed to ver-ify the CPC/COLSS performance and to obtain optimum CPC/COLSS calibration constants at var, -ious core conditions. Most of test results met their specific acceptance criteria. In the case of missing the acceptance criteria, the test results ore analyzed, evaluated, and justified. Through the analysis and evaluation of each of the CPC/COLSS related test results, it can be concluded that the CPC/COLSS are successfully Implemented as designed at YGN 3.

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The effect of rear side etching for crystalline Si solar cells (후면식각이 결정질 실리콘 태양전지에 미치는 영향에 관한 연구)

  • Shin, Jeong Hyun;Kim, Sun Hee;Lee, Hongjae;Kim, Bum Sung;Lee, Don Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.72.2-72.2
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    • 2010
  • Nowadays, the crystalline Si Solar cell are expected for economical renewable energy source. The cost of the crystalline Si solar cell are decreasing by improvement of its efficiency and decrease of the cost of the raw Si wafers for Solar cells. This Si wafer based crystalline Si solar cell is the verified technology from several decade of its history. Now, I will introduce one method that can be upgrade the efficiency by using simple and economical method. The name of this method is Rear Side Etching(RSE). The purpose of rear side etching is the elimination of n+ layer of rear side and increase of the flatness. The effects of rear side etching are the improvement of Voc and increase of efficiency by reducement series resistance and forming of uniform BSF. The experimental procedure for rear side etching is very simple. After anti-reflection coating on solar cell wafer, Solar cell wafer is etched by the etching chemical that react with only rear side not front side. This special chemical is no harmful to anti-reflection coating layer. It can only etched rear side of solar cell wafer. We can use etching image by optical microscope, minority carrier life time by WCT 120, SiNx thickness and refractive index by ellipsometer, cell efficiency for the RSE effect measurement. The key point of rear side etching is development of etching process condition that react with only rear side. If we can control this factor, we can achieve increase of solar cell efficiency very economically without new device.

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Quasi-static test of the precast-concrete pile foundation for railway bridge construction

  • Zhang, Xiyin;Chen, Xingchong;Wang, Yi;Ding, Mingbo;Lu, Jinhua;Ma, Huajun
    • Advances in concrete construction
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    • v.10 no.1
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    • pp.49-59
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    • 2020
  • Precast concrete elements in accelerated bridge construction (ABC) extends from superstructure to substructure, precast pile foundation has proven a benefit for regions with fragile ecological environment and adverse geological condition. There is still a lack of knowledge of the seismic behavior and performance of the precast pile foundation. In this study, a 1/8 scaled model of precast pile foundation with elevated cap is fabricated for quasi-static test. The failure mechanism and responses of the precast pile-soil interaction system are analyzed. It is shown that damage occurs primarily in precast pile-soil interaction system and the bridge pier keeps elastic state because of its relatively large cross-section designed for railways. The vulnerable part of the precast pile with elevated cap is located at the embedded section, but no plastic hinge forms along the pile depth under cyclic loading. Hysteretic curves show no significant strength degradation but obvious stiffness degradation throughout the loading process. The energy dissipation capacity of the precast pile-soil interaction system is discussed by using index of the equivalent viscous damping ratio. It can be found that the energy dissipation capacity decreases with the increase of loading displacement due to the unyielding pile reinforcements and potential pile uplift. It is expected to promote the use of precast pile foundation in accelerated bridge construction (ABC) of railways designed in seismic regions.

Novel steel bracket and haunch hybrid system for post-earthquake retrofit of damaged exterior beam-column sub-assemblages

  • Kanchanadevi, A.;Ramanjaneyulu, K.
    • Structural Engineering and Mechanics
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    • v.73 no.3
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    • pp.239-257
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    • 2020
  • In the present study, an innovative steel bracket and haunch hybrid scheme is devised, for retrofitting of earthquake damaged deficient beam-column sub-assemblages. Formulations are presented for evaluating haunch force factor under combined load case of lateral and gravity loads for the design of double haunch retrofit. The strength hierarchies of control and retrofitted beam-column sub-assemblages are established to showcase the efficacy of the retrofit in reversing the undesirable strength hierarchy. Further, the efficacy of the proposed retrofit scheme is demonstrated through experimental investigations carried out on gravity load designed (GLD), non-ductile and ductile detailed beam-column sub-assemblages which were damaged under reverse cyclic loading. The maximum load carried by repaired and retrofitted GLD specimen in positive and negative cycle is 12% and 28% respectively higher than that of the control GLD specimen. Further, the retrofitted GLD specimen sustained load up to drift ratio of 5.88% compared with 2.94% drift sustained by control GLD specimen. Repaired and retrofitted non-ductile specimen, could attain the displacement ductility of three during positive cycle of loading and showed improved ductility well above the expected displacement ductility of three during negative cycle. The hybrid haunch retrofit restored the load carrying capacity of damaged ductile specimen to the original level of control specimen and improved the ductility closer to the expected displacement ductility of five. The total cumulative energy dissipated by repaired and retrofitted GLD, non-ductile and ductile specimens are respectively 6.5 times, 2.31 times, 1.21 times that of the corresponding undamaged control specimens. Further, the damage indices of the repaired and retrofitted specimens are found to be lower than that of the corresponding control specimens. The novel and innovative steel bracket and haunch hybrid retrofit scheme proposed in the present study demonstrated its effectiveness by attaining the required displacement ductility and load carrying capacity and would be an excellent candidate for post-earthquake retrofit of damaged existing RC structures designed according to different design evolutions.

Effect of Food Consumption Monitoring Using a Smartphone on Weight Changes in Obese Women (스마트폰을 이용한 식이섭취 모니터링이 비만여성의 체중변화에 미치는 효과 분석)

  • Kim, Young-Suk;On, Jeong-Ja;Hong, Yang-Hee;Hong, In-Sun;Chang, Un-Jae
    • Journal of the Korean Dietetic Association
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    • v.20 no.2
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    • pp.123-132
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    • 2014
  • This study investigated the effect of food consumption monitoring and real-time communication-based weight control program using a smartphone on weight reduction and maintenance in obese women. This study consisted of two phases: an 8-week weight control program with food consumption monitoring and real-time communication using a smartphone and an 8-week follow-up. Sixteen obese female college students (>30% body fat) participated in this program, and we measured changes in body composition and dietary intake volume. Follow-up analysis focused on weight maintenance after 8 weeks of no contact. Total energy intake (P<0.01), body weight (P<0.001), percent body fat (P<0.001), body fat (P<0.05), and body mass index (P <0.001) decreased significantly after the 8-week weight control program. However, we could not observe total energy intake or body composition regain after the follow-up period. These results suggest that food consumption monitoring and real-time communication using a smartphone can be effective for weight control and maintenance.

Photo-Induced Scalar Phenomena according to Thickness Dependence of Chalcogenide $As_{40}Ge_{10}Se_{15}S_{35}$ Thin Film (칼코게나이트 $As_{40}Ge_{10}Se_{15}S_{35}$ 박막에서 두께에 따른 광유기 스칼라 현상)

  • 이현용;박수호;정홍배
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.467-472
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    • 1997
  • In this study, we investigated the thickness dependence of thermal bleaching(TB) effect as well as photo-induced scalar phenomena, such as photodrakening(PD) effect and photorefraction(PR) change, in chalcogenide A $s_{40}$ G $e_{10}$S $e_{15}$ $S_{35}$ thin films. We found that when these films were exposed for 15 minutes using blue-pass filtered Hg lamp(~4300$\AA$) after annealing for 30 minutes around the glass transition temperature Tg(20$0^{\circ}C$), the refractive index change ($\Delta$n) was varied up to 0.02~0.46 according to each thickness condition and the optical energy gap ($\Delta$ $E_{op}$ ) was shifted to a longer wavelength of approximately 0.67eV, especially for 1000$\AA$-thickness. Also, the TB PD effects have been understood by the results related to optical absorption characteristics. The TB effect could be estimated as increasing the stabilization of amorphous chalcogenide films since absorption slope of extended regions(U) was not changed by annealing. On the other hand, the PD effect could be understood as due to the enhancement of disorder since U and the slope of Urbachs tail(1/F) around an absorption edge were decreased by exposing.ing.n edge were decreased by exposing.

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Study on Behavior Analysis of Crash Cushion Using Analysis Data of High-Speed Camera (고속카메라 영상분석 데이타를 이용한 충격흡수시설의 충돌거동 분석에 관한 연구)

  • Jang, Dae-Young;Ko, Man-Gi;Lee, Yoon-Ki;Joo, Jae-Woong
    • International Journal of Highway Engineering
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    • v.11 no.2
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    • pp.75-83
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    • 2009
  • Collision behavior of clash cushion occurs for a second of less than 0.4sec usually so that it is too hard to calculate numerically. Therefore, for development of trash cushion, it rely on full-scale vehicle crash test without any design procedure. Occupant safety indices if calculated from acquired data by data measurement system and collision behavior of vehicle and crash cushion is filming using high-speed camera in the crash test. But practical ufo scope of high-speed camera is limited and it is not using to calculated the occupant safety indices or analyzed the energy dissipated mechanism of crash cushion. This work is to estimate to be suitable or not for compare the data from measurement system with the data from high-speed camera. And also it is to grope for practical use scheme to calculation of occupant safety indices or analysis of collision behavior.

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The Effects of Uncooked Powdered Food on Nutrient Intake, Serum Lipid Level, Dietary Behavior and Health Index in Healthy Women (생식 제품의 섭취가 건강한 성인여성의 영양섭취상태, 식행동, 혈청지질농도 및 건강지표에 미치는 영향)

  • 박성혜;한종현
    • Journal of Nutrition and Health
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    • v.36 no.1
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    • pp.49-63
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    • 2003
  • The purpose of this study was to obtain the nutritional values and objective data of uncooked powdered food (UPF) in korea. We interviewed 27 healthy female subjects aged over 25 years living in the lksan area. We just replaced common breakfast and dinner of the subjects with UPF. Their dietary intake status was evaluated by 24-hour recall method. Their body compositions were measured using body fat analyzer. Also we conducted hematological and clinical analysis of blood. The intake of energy, lipid and protein has decreased as people started to take UPF, but the intake of vitamins and minerals has increased. The quality of meals has improved after taking UPF. Due to the energy loss by taking UPF, weight and body fat gradually lessened. Among the lost weight the percentage of the body fat was high and we judged that the process of losing weight was successful. It is hard to predict whether weight loss will occur to people who are already in shape or not, but if overweight and obesity people regularly take UPF instead of other food products, we assume that UPF will help lessening body fat. The most positive change among biochemical changes by taking UPF was decreasing of serum lipid contents. The concentrations of total cholesterol and LDL-cholesterol gradually decreased and decreased intently after 12weeks. Serum HDL-cholesterol gradually increased and serum triglyceride showed gradual decrement. When healthy adult women replaced two of three meals with UPF for 3months, we were able to see some useful changes like decrement of body fat and serum lipid control and during this 3month period, no significant nutritional problems occurred. Complete judgement on UPF may be difficult with these conclusions but if people take a nomal meal once and replenish iron from taking UPF twice a day, we assume that replacing UPF with regular meal not be a problem in nutritional status. If other experiments on the effects of UPF proceed, we believe that those experiments will be very helpful in judging the nutritional value of UPF. (Korean J Nutrition 36(1) : 49-63, 2003)