• Title/Summary/Keyword: energy gap

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Effects of High Neutral Beam Energy on the Properties of Amorphous Carbon Films

  • Lee, Dong-Hyeok;Jang, Jin-Nyeong;Gwon, Gwang-Ho;Yu, Seok-Jae;Lee, Bong-Ju;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.477-477
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    • 2012
  • The effects of argon neutral beam (NB) energy on the amorphous carbon (a-C) films were investigated, while the a-C films were deposited by neutral particle beam assisted sputtering (NBAS) system. The deposition characteristics of these films were studied as a function of NB energy (or reflector bias voltage). The film structures were investigated by Raman spectroscopy. The hardness was measured by nano-indentation tests and the optical band gap was measured by UV-visible spectroscopy.

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A study on the magnetic flux distribution of 3-phase 4-pole induction motor by finite element method (유한요소법에 의한 삼상유도전동기의 자속분포해석에 관한 연구)

  • 임달호;현동석;임태빈
    • 전기의세계
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    • v.30 no.4
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    • pp.219-226
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    • 1981
  • The magnetic field distribution in saturable iron part of electromagnetic energy conversion divices is defined by the nonlinear quasi-Poisson enquation that is described the electromagnetic field characteristics and satisfied the natural boundary condition. The solution of this equation is obtained by minimizing an energy functional by means of trial function that defined in triangular subregion of two-dimensional field region. As a result, the accuracy of the machine design is increased by use of its solution. In this respect, this study is developed the basic theory to analyze the magnetic flux distribution in saturable iron part and air gap of induction motor that its secondary part is short circuit by the variational principle, the minimized theory of energy functional, the application of F.E.M., and treatment of computer. As theoritical data compared with the practics, the validity of the theory in this study is supported by experimental findings.

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Use of High-Temperature Gas-Tight Electrochemical

  • Park, Jong-Hee;Beihai Ma;Park, Eun-Tae
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.103-113
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    • 1998
  • By using a gas-tight electrochemical cell, we can perform high-temperature coulometric titration and measure electronic transport properties to determine the elecronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilitized zirconia(YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressure ($pO_2=10^{-35}$ to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria $(Ca-CeO_2 \;and\; CeO_2)$, copper oxides and copper-oxide-based ceramic superconductors, transition metal oxides, $SrFeCo_{0.5}O_x,\; and \;BaTiO_2$.

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Estimation of Beam Mode Frequencies of Co-axial Cylinders Immersed in Fluid by Equivalent Mass Approach

  • Kim, Tae-Wan;Park, Suhn;Park, Keun-Bae
    • Nuclear Engineering and Technology
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    • v.35 no.1
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    • pp.1-13
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    • 2003
  • In this study, an effective method to estimate the fundamental frequencies of co-axial cylinders immersed in fluid is proposed. The proposed method makes use of the equivalent mass or density that is derived from the added mass matrix caused by the fluid-structure interaction (FSI) phenomenon. The equivalent mass is defined from the added mass matrix based on a 2-D potential flow theory. The theory on two co-axial cylinders extended to the case of three cylinders. To prove the validity of the proposed method, the eigenvalue analyses upon coaxial cylinders coupled with fluid gaps are peformed using the equivalent mass. The analyses results upon various fluid gap is conditions reveal that the present method could provide accurate frequencies and be suitable for expecting the fundamental frequencies of fluid coupled cylinders in beam mode vibration.

Heat Transfer in a Horizontal Mantle Heat Exchanger for a Thermosyphon-driven Flat Plate Collector (자연대류형 태양열 온수기용 맨틀 축열조의 열전달 현상에 관한 연구)

  • Cho, H.J.;Seo, T.B.;Kang, Y.H.
    • Journal of the Korean Solar Energy Society
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    • v.21 no.3
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    • pp.43-50
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    • 2001
  • A horizontal mantle heat exchanger for a thermosyphon-driven SDHW(solar domestic hot water) was numerically simulated and fluid flow and heat transfer in the annulus of the mantle heat exchanger were quantitatively investigated. The Reynolds number, the location of the inlet, and the gap of the annulus were selected as the important design variables. The effects of the design variables on the heat transfer characteristics were thoroughly studied. Based on the numerical results, a correlation for predicting the heat transfer coefficient was suggested as the conclusion of this study.

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A Theoretical Study of Some Bicyclic Azoalkanes

  • Chung, Gyu-Sung;Lee, Duck-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.2051-2054
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    • 2006
  • The molecular structures of the ground and lowest triplet states of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH), 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) and their fused ring derivatives are investigated with an ab initio method and the density functional theory. Unlike the singlet DBH and DBO, the azo skeletal structures of the triplet counterparts are turned out to be quite sensitive to the change of the electronic structure of the fused ring. The B3LYP C-N=N-C dihedral angles of the triplet DBH and DBO are estimated to be about 28.0 and $40.4{^{\circ}}$, respectively. The B3LYP singlet-triplet energy gaps for DBH and DBO are predicted to be 58.4 and 48.4 kcal/mol, respectively. The triplet state energy can be lowered drastically by the presence of the remote $\Pi-\Pi$ interaction as in the case of 1bb'.

Effects of Al Concentration on Structural and Optical Properties of Al-doped ZnO Thin Films

  • Kim, Min-Su;Yim, Kwang-Gug;Son, Jeong-Sik;Leem, Jae-Young
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1235-1241
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    • 2012
  • Aluminium (Al)-doped zinc oxide (AZO) thin films with different Al concentrations were prepared by the solgel spin-coating method. Optical parameters such as the optical band gap, absorption coefficient, refractive index, dispersion parameter, and optical conductivity were studied in order to investigate the effects of the Al concentration on the optical properties of AZO thin films. The dispersion energy, single-oscillator energy, average oscillator wavelength, average oscillator strength, and refractive index at infinite wavelength of the AZO thin films were found to be affected by Al incorporation. The optical conductivity of the AZO thin films also increases with increasing photon energy.

OPTICAL PROPERTIES OF AMORPHOUS CN FILMS

  • Park, Sung-Jin;Lee, Soon-Il;Oh, Soo-Ghee;Bae, J.H.;Kim, W.M.;Cheong, B.;Kim, S.G.
    • Journal of Surface Science and Engineering
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    • v.29 no.5
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    • pp.556-562
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    • 1996
  • Carbon nitride (CN) films were synthesized on silicon substrates by a combined ion-beam and laser-ablation method under various conditions; ion-beam energy and ion-beam current were varied. Raman spectroscopy and spectroscopic ellipsometry (SE) were employed to characterize respectively the structural and the optical properties of the CN films. Raman spectra show that all the CN films are amorphous independent of the ion-beam current and the ion-beam energy. Refractive indices, extinction coefficients and optical band gaps which were determined from the measured SE spectra exhibit a significant dependence on the synthesis conditions. Especially, the decrease of the refractive indices and the shrinkage of the optical band gap is noticeable as the ion-beam current and/or the ion-beam energy increase.

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SCC Inhibitors for SG Tube Materials in Nuclear Power Plants

  • Kim, Kyung-Mo;Lee, Eun-Hee;Kim, Uh-Chul
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.585-586
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    • 2006
  • Several chemicals were studied to suppress the damage due to stress corrosion cracking (SCC) of steam generator (SG) tubes in nuclear power plants. The effects on the SCC of the compounds, $TiO_2$, TyzorLA and $CeB_6$, were tested for several types of SG tubing materials. The test with the addition of $TiO_2$ and $CeB_6$ showed an effect in decreasing the SCC for the SG tubing material. However, $CeB_6$ caused some more SCC for Alloy 800. The penetration property into a crevice of the inhibitors was investigated by using Alloy 600 specimens with different gap.

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Electrical and Structural Properties of $CuInS_2$ thin films fabricated by EBE(Electronic Beam Evaporator) Method (전자빔 증착기로 증착된 $CuInS_2$ 박막의 전기적 구조적 특성)

  • Yang, Hyeon-Hun;Kim, Young-Jun;Jeong, Woon-Jo;Park, Gye-Choon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.170-173
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    • 2006
  • [ $CuInS_2$ ] filims were appeared from 0.84 to 1.27 of Cu/In composition ratio and sulfur composition ratios of $CuInS_2$ thin films fabricated, Also when Cu/In composition ratio was 1.03, $CuInS_2$ thin film with chalcopyrite structure had the highest XRD peak (112). And lattice constant (a) of and grain size of the film tin s ambient were appeared a little larger than those in only Vacuum The films in S ambient were p-type with resistive of around $10^{-1}{\Omega}cm$ and optical energy band gaps of the films in S ambient were appeared a little larger than those in only Vacuum. Analysis of the optical energy band gap of $CuInS_2$ thin films a value of 1.53eV.

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