• 제목/요약/키워드: energy gap

검색결과 1,650건 처리시간 0.031초

주파수 필터링 함수에 따른 시간 및 주파수 영역 광음향 측정에 대한 신호 대 잡음비 분석 (Signal-to-noise Ratio in Time- and Frequency-domain Photoacoustic Measurements by Different Frequency Filtering)

  • 강동열
    • 한국광학회지
    • /
    • 제30권2호
    • /
    • pp.48-58
    • /
    • 2019
  • 구면 초점 초음파 측정기에 의해 구형의 광 흡수체로부터 측정된 시간(즉, 펄스 형태 광원) 및 주파수 영역(즉, 처프 형태 광원) 광음향 신호의 신호 대 잡음비(signal-to-noise ratio)를 이론 및 시뮬레이션으로 분석하였다. 이전 문헌과 마찬가지로 시간 영역 광음향 측정에 의한 신호 대 잡음비 값이 주파수 영역 광음향 측정의 경우보다 더 높았는데 이 근본적인 이유를 최대허용노광량(maximum permissible exposure)에 따른 광원의 세기와 주파수 필터링을 통한 두 측정 모드의 광음향 스펙트럼들에 대한 분석을 통해 이해하였다. 또한, 분석의 결과로서 주파수 영역 광음향의 처프 형태 광원에 대한 정합 필터링에 더해 DC 스펙트럼 부분을 제거하니 신호 대 잡음비가 5 dB 정도 상승하는 것을 발견하였다. 특히, 주파수 필터 함수의 주파수 상한 값의 변화에 따라 신호대 잡음비 값이 급격하게 변동하였는데 신호 대 잡음비가 최대가 되는 주파수 상한 값이 두 광음향 측정 모드에서 서로 다르게 나타남을 관찰하였다.

Synergy study on charge transport dynamics in hybrid organic solar cell: Photocurrent mapping and performance analysis under local spectrum

  • Hong, Kai Jeat;Tan, Sin Tee;Chong, Kok-Keong;Lee, Hock Beng;Ginting, Riski Titian;Lim, Fang Sheng;Yap, Chi Chin;Tan, Chun Hui;Chang, Wei Sea;Jumali, Mohammad Hafizuddin Hj
    • Current Applied Physics
    • /
    • 제18권12호
    • /
    • pp.1564-1570
    • /
    • 2018
  • Charge transport dynamics in ZnO based inverted organic solar cell (IOSC) has been characterized with transient photocurrent spectroscopy and localised photocurrent mapping-atomic force microscopy. The value of maximum exciton generation rate was found to vary from $2.6{\times}10^{27}m^{-3}s^{-1}$ ($J_{sat}=79.7A\;m^{-2}$) to $2.9{\times}10^{27}m^{-3}s^{-1}$ ($J_{sat}=90.8A\;m^{-2}$) for devices with power conversion efficiency ranging from 2.03 to 2.51%. These results suggest that nanorods served as an excellent electron transporting layer that provides efficient charge transport and enhances IOSC device performance. The photovoltaic performance of OSCs with various growth times of ZnO nanorods have been analysed for a comparison between AM1.5G spectrum and local solar spectrum. The simulated PCE of all devices operating under local spectrum exhibited extensive improvement with the gain of 13.3-3.7% in which the ZnO nanorods grown at 15 min possess the highest PCE under local solar with the value of 2.82%.

RF 마그네트론 스퍼터 방법으로 제조한 Al 도핑된 ZnO 박막의 구조 및 광학적 특성에 미치는 산소 분압비의 영향 (Effect of oxygen partial pressure on the optical and structural properties of Al doped ZnO thin films prepared by RF magnetron sputtering method)

  • 신승욱;박현수;문종하;김태원;김진혁
    • 대한금속재료학회지
    • /
    • 제46권4호
    • /
    • pp.249-256
    • /
    • 2008
  • 0.5 wt% Al doped ZnO thin films (AZO) were prepared on glass substrates using RF magnetron sputtering method. Thin films were grown at substrate temperature of $250^{\circ}C$, RF power of 75W, working pressure of 10 mTorr, by changing the $O_2/Ar$ pressure ratio from 0% to 16.7%. The effects of oxygen partial pressure during the deposition process on structural and optical properties of the films were investigated using XRD, SEM, AFM, EPMA and UV-visible spectroscopy. All the AZO thin films were grown as hexagonal wurtzite phase with the c-axis preferred out-of-plane orientation. The surface roughness and grain size of AZO films decreased with increasing oxygen ratio from 10.6 nm to 3.2 nm and 94.9 nm to 30.9 nm, respectively. On the other hand, the transmittance and band gap energy of the AZO films increased from 84.7% to 92.6% and 3.24 eV to 3.28 eV, respectively with increasing the $O_2/Ar$ pressure ratio.

[2-(diphenyl hydroxy-methyl)pyrrolidine]-AlH 유도체와 방향족 케톤의 선택적 환원에 대한 이론적 연구 (Theoretical Study on the Selective Reduction of Chiral [2-(diphenyl hydroxy-methyl)pyrrolidine]-AlH Derivatives and Aromatic Ketone)

  • 이철재;김종미
    • 문화기술의 융합
    • /
    • 제7권2호
    • /
    • pp.389-394
    • /
    • 2021
  • 본 연구에서는 알콕시-아민-알루미늄 유도체인 DPHMP-AlH와 프로피오페논, 부티로페논과의 분자구조 및 경계궤도함수의 특성을 알아보았다. 또한, 전이상태의 입체구조 및 열역학적 파라미터를 계산하여 최종 생성물인 (R),(S)-페닐프로판올과 (R),(S)-페닐부탄올의 선택적 환원에 미치는 영향을 조사하였다. 그 결과 입체 분자구조적 안정성을 고려해 볼 때 (S)형 DPHMP-AlH와 알킬페논의 전이상태가 더 안정한 것으로 나타났으며, 이 결과로부터 DPHMP-AlH와 알킬페논의 선택적 환원으로 얻어진 최종 결과물은 (S)-(1)-페닐프로판올과 (S)-(1)-페닐부탄올의 형성이 유리한 것을 확인하였다.

중성자선과 감마선 동시측정이 가능한 휴대용 계측시스템 개발에 관한 연구 (Development of a Portable Detection System for Simultaneous Measurements of Neutrons and Gamma Rays)

  • 김희경;홍용호;정영석;김재현;박수연
    • 대한방사선기술학회지:방사선기술과학
    • /
    • 제43권6호
    • /
    • pp.481-487
    • /
    • 2020
  • Radiation measurement technology has steadily improved and its usage is expanding in various industries such as nuclear medicine, security search, satellite, nondestructive testing, environmental industries and the domain of nuclear power plants (NPPs). Especially, the simultaneous measurements of gamma rays and neutrons can be even more critical for nuclear safety management of spent nuclear fuel and monitoring of the nuclear material. A semiconductor detector comprising cadmium, zinc, and tellurium (CZT) enables to detect gamma-rays due to the significant atomic weight of the elements via immediate neutron and gamma-ray detection. Semiconductor sensors might be used for nuclear safety management by monitoring nuclear materials and spent nuclear fuel with high spatial resolution as well as providing real-time measurements. We aim to introduce a portable nuclide-analysis device that enables the simultaneous measurements of neutrons and gamma rays using a CZT sensor. The detector has a high density and wide energy band gap, and thus exhibits highly sensitive physical characteristics and characteristics are required for performing neutron and gamma-ray detection. Portable nuclide-analysis device is used on NPP-decommissioning sites or the purpose of nuclear nonproliferation, it will rapidly detect the nuclear material and provide radioactive-material information. Eventually, portable nuclide-analysis device can reduce measurement time and economic costs by providing a basis for rational decision making.

Structural and Electrical Properties of (La,Nd,Sr)MnO3 Ceramics for NTC Thermistor Devices

  • Shin, Kyeong-Ha;Park, Byeong-Jun;Lim, Jeong-Eun;Lee, Sam-Haeng;Lee, Myung-Gyu;Park, Joo-Seok;Lee, Sung-Gap
    • 한국전기전자재료학회논문지
    • /
    • 제35권3호
    • /
    • pp.292-296
    • /
    • 2022
  • (La0.5Nd0.2Sr0.3)MnO3 specimens were prepared by a solid-state reaction. In all specimens, X-ray diffraction patterns of an orthorhombic structure were shown. The fracture surfaces of (La0.5Nd0.2Sr0.3)MnO3 specimens showed a transgranular fracture pattern be possibly due to La ions (0.122 nm) as a perovskite A-site dopant substituting for Nd ions (0.115 nm) having a small ionic radius. The full-width at half maximum (FWHM) of the Mn 2p XPS spectra showed a value greater than that [8] of the single valence state, which is believed to be due to the overlapping of Mn2+, Mn3+, and Mn4+ ions. The dependence of Mn 2p spectra on the Mn3+/Mn4+ ratio according to sintering time was not observed. Electrical resistivity resulted in the minimum value of 100.7 Ω-cm for the specimen sintered for 9 hours. All specimens show a typical negative temperature coefficient of resistance (NTCR) characteristics. In the 9-hour sintered specimen, TCR, activation energy, and B25/65-value were -1.24%/℃, 0.19 eV, and 2,445 K, respectively.

니들 코팅을 이용한 OLED 광 추출용 구형 마이크로렌즈 어레이 제작 (Fabrication of Spherical Microlens Array Using Needle Coating for Light Extraction of OLEDs)

  • 김주안;신영균;김기은;홍송은;박종운
    • 반도체디스플레이기술학회지
    • /
    • 제21권2호
    • /
    • pp.25-31
    • /
    • 2022
  • By an aid of needle coating, we have fabricated a spherical microlens array using poly(methyl methacrylate) for potential applications in light extraction of organic light-emitting diodes. With an attempt to achieve high-density and high-aspect-ratio microlens arrays, we have investigated the coating behaviors by varying the material parameters such as the solute concentration and wettability of the poly(methyl methacrylate) solution and process parameters such as the dwell time of needle near the substrate, retract distance of needle from the substrate, and coating gap between the needle and substrate. Under the optimized coating conditions, it is demonstrated that high-aspect-ratio microlens arrays can be obtained using a coating solution with high solute concentration and a small amount of a hydrophobic solvent. It is found that the diameter and height of microlens array are decreased with increasing poly(methyl methacrylate) concentration, yet the overall aspect ratio is rather enhanced. By the addition of 5 wt% hexylamine in 35 wt% poly(methyl methacrylate) solution, we have achieved a spherical microlens with the height of 7.7 ㎛ and the width of 94.24 ㎛ (the aspect ratio of 0.082). To estimate the capability of light extraction by the microlens array, we have performed ray tracing simulations and demonstrated that the light extraction efficiency of organic light-emitting diode is expected to be enhanced up to 24%.

외부부착형 BCM공법으로 보강된 철근콘크리트 기둥의 내진보강 (Seismic Retrofitting of Existing Reinforced Concrete Columns Using Binding Column Method)

  • 허무원;박태원;이상현;박현수
    • 한국구조물진단유지관리공학회 논문집
    • /
    • 제26권5호
    • /
    • pp.119-126
    • /
    • 2022
  • 본 연구는 내진설계가 되어 있지 않은 필로티 건축물의 부족한 횡력을 보강할 수 있는 외부부착형 내진보강공법(Binding Column Method, BCM)을 제안하였다. 또한, 제안된 내진보강공법을 대상으로 보강실험체 4개, 기준 실험체 1개를 제작하여 반복가력 실험을 통하여 보강 전·후의 내진성능향상 효과를 검토하였다. 실험 결과, 기준 실험체(SC1)는 급격한 강도저하와 함께 취성적인 전단파괴의 양상을 나타낸 반면, BCM 공법을 적용한 실험체(SC2, SC3, SC4, SC5)는 강도 및 강성의 증가와 함께 에너지 흡수 능력이 큰 타원형의 이력특성을 나타내었다. 또한, 간격이 좁고 토크가 크며, L자형 강판의 두께가 두꺼울수록 보강효과가 향상됨을 알 수 있다. BCM공법 중 전단보강간격이 작고, 조임력 값이 크며, 연결철물이 두꺼운 SC4실험체가 가장 뛰어난 내진성능보강 효과를 나타내었다.

Dynamic punching shear tests of flat slab-column joints with 5D steel fibers

  • Alvarado, Yezid A.;Torres, Benjamin;Buitrago, Manuel;Ruiz, Daniel M.;Torres, Sergio Y.;Alvarez, Ramon A.
    • Structural Engineering and Mechanics
    • /
    • 제81권3호
    • /
    • pp.281-292
    • /
    • 2022
  • This study aimed to analyze the dynamic punching shear performance of slab-column joints under cyclic loads with the use of double-hooked end (5D) steel fibers. Structural systems such as slab-column joints are widely found in infrastructures. The susceptibility to collapse of such structures when submitted to seismic loads is highly dependent on the structural performance of the slab-column connections. For this reason, the punching capacity of reinforced concrete (RC) structures has been the subject of a great number of studies. Steel fibers are used to achieve a certain degree of ductility under seismic loads. In this context, 5D steel hooked fibers provide high levels of fiber anchoring, tensile strength and ductility. However, only limited research has been carried out on the performance under cyclic loads of concrete structural members containing steel fibers. This study covers this gap with experimental testing of five different full-scale subassemblies of RC slab-column joints: one without punching reinforcement, one with conventional punching reinforcement and three with 5D steel fibers. The subassemblies were tested under cyclic loading, which consisted of applying increasing lateral displacement cycles, such as in seismic situations, with a constant axial load on the column. This set of cycles was repeated for increasing axial loads on the column until failure. The results showed that 5D steel fiber subassemblies: i) had a greater capacity to dissipate energy, ii) improved punching shear strength and stiffness degradation under cyclic loads; and iii) increased cyclic loading capacity.

GaN증폭기의 본드 와이어 용융단선 현상분석과 과도전류를 고려한 전류용량 선정에 대한 연구 (A Study on Bond Wire Fusing Analysis of GaN Amplifier and Selection of Current Capacity Considering Transient Current)

  • 유우성;석연수;황규혁;김기준
    • 전기전자학회논문지
    • /
    • 제26권4호
    • /
    • pp.537-544
    • /
    • 2022
  • 본 논문은 최근 전자전, 레이더, 기지국 및 위성통신분야에서 각광받고 있는 GaN HEMT(Gallium Nitride High Electron Mobility Transistor) die를 이용한 고출력증폭기의 제작에 사용되는 본드 와이어의 용융단선 현상과 원인을 분석하였다. 고출력증폭기의 주요 성능인 최대 출력전력을 얻기 위해서는 최적의 임피던스 정합이 필요하고 정격전류뿐만 아니라 과도전류에 대한 발열을 고려하여 본드 와이어 소재에 부합하는 직경과 가닥수가 정해져야 한다. 특히, GaN과 같이 에너지 밴드 갭이 넓은 화합물반도체는 설계효율이 낮거나 방열이 부족하면 열 저항 증가로 인해 본드 와이어의 용융단선을 촉발하는 현상을 확인하였다. 본 자료는 발열조건에 대한 모의시험을 수행하고, IR현미경 측정을 통한 검증으로 GaN소자를 이용한 응용분야에 참고자료로 활용이 기대된다.