• 한국전기전자재료학회논문지
• /
• 제11권9호
• /
• pp.693-699
• /
• 1998

In this work $Cd_4GeS_6:Co^{2+}$(0.5mole%) single crystals were grown by the chemical transporting reactiov(CTR) method using high purity(6N) elements. The grown single crystals crystallized in a monoclinic structure(space group Cc). The direct optical energy gap of this single crystals was found to be 2.445eV at 300K and the temperature dependence of optical energy gap was fitted well to Varshni equation. But at temperatures lower than 70K an anomalous temperature dependence of the optical energy gap was obtained. This anomalous temperature dependence accored well with the anomalous temperature dependence of the unit cell volume. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gaps.

• 대한전자공학회논문지
• /
• 제21권2호
• /
• pp.36-46
• /
• 1984

Ga1-xlnxSe 단결정을 X=0.0∼0.1영역과 X=0.8-1.0영역에서 Bridgman방법으로 성장시켰다. 성장된 Ga1-xlnxSe 단결정은 X=0.0∼0.1영역에서는 hexagonal구조, X=0.8∼1.0영역에서는 rhombohedral 구조를 가지고 있었다. CaInSe 단결정은 간접천이형 energy gap을 가지고 있었으며, 15°K에서 250°K로 시편의 온도가 상승할 때 energy gap 은 감소되었고, 온도계수는 (-2.4∼-4.3)×10-4eV/K으로 주어졌다. Ga1-xlnxSe 단결정의, energy gap에 온도 의존성은 Schmid의 electron-phonon 상호작용의 이론으로 설명할 수 있었다.

• Nuclear Engineering and Technology
• /
• 제27권3호
• /
• pp.344-357
• /
• 1995

핵연료 소결체와 피복관 사이의 간극 크기에 크게 좌우되는 간극 열전도도는 연료봉내 초기 저장에너지 양에 중요한 영향을 끼친다. 정상상태 계산용 ELESTRES 코드에서 사용 중인 수정된 Ross-Stoute 의 간극 열전도도 모델은 단순한 열적 변형 모델에 기초한다. 최근의 실험에서 핵연료 소결체가 연소됨에 따라서 균열, 소결체 재배열 등이 발생되고, 피복관 내부의 편심에 위치하게 된다는 것이 알려졌다. 본 논문에서는, 최근에 제안된 편심형 간극 모델과 소결체 재배열형 간극 모델 등이 기술되었고, 실험 조건과 중수로 핵연료봉의 운전조건 하에서의 소결체와 피복관 사이의 간극 열전도도를 계산하는데 이용되었다. 실험 치와 계산치가 잘 일치됨으로써, 수정된 Ross-Stoute 모델이 ELESTRES 코드 내에서 사용된 열전달 관련 가정들과 잘 부합됨을 보여 주었다. 출력 경계곡선을 따라서 수정된 Ross-Stoute 모델로 계산된 간극내 열전달과 핵연료 표면 온도 등이 편심형 간극 모델과 소결체 재배열형 간극모델에 의한 예측치보다 보수적이었다.

• 펄프종이기술
• /
• 제36권2호
• /
• pp.17-23
• /
• 2004

The effects of refining consistency and plate gap on the specific energy consumption and physical properties of liner were investigated. Higher refining consistency and narrower plate gap brought about the reduction of specific energy consumption to decrease the freeness. Refining consistency and plate gap did not affect the bulk, Taber stiffness and compression index. The reduction of freeness and/or the increase of specific energy consumption caused the decrease of bulk and Taber stiffness, but increased the compression index. The effect of grammage on bulk was not observed, but Taber stiffness and compression index were increased with grammage. The bulk was decreased with the reduction of freeness rapidly at the above 400 mL CSF, and then levelled off. It is expected that the reduction of energy consumption could be obtained from the application of higher refining consistency and narrower plate gap during refining.

• E2M - 전기 전자와 첨단 소재
• /
• 제9권5호
• /
• pp.445-449
• /
• 1996

Structural and optical characteristics in Se thin film fabricated by EBE method had been studied. Se thin film was deposited with noncrystalline until substrate temperature of >$100^{\circ}C$ Color of its surface had red genealogy, and its optical energy band gap was about 2.45 eV. But Se film was grown with monoclinic at substrate temperature of over >$150^{\circ}C$ Also, color of its surface had gray genealogy, and its optical energy band gap was about 2.31 eV. Finally, after heat-treatment at >$150^{\circ}C$ for 15 min with substrate temperature of >$100^{\circ}C$ noncrystalline Se was proved to be hexagonal, and color of its surface had dark gray genealogy, and its optical energy band gap was about 2.06 eV. From the results, it was known that Se thin film for photoelectric device with the lowest optical energy band gap was accepted from hexagonal structure.

• Nuclear Engineering and Technology
• /
• 제34권4호
• /
• pp.396-405
• /
• 2002

An experimental study on counter-current flow limitation phenomena in narrow annular passages was carried out The gap sizes tested were 1, 2 and 3 mm. This is very small compared with the outer diameter of the annular passage, 500 mm. It was visually observed that a CCFL might occur in some part of the periphery while the other part is remained in a counter current flow pattern. That is, non-uniform behaviour of fluids due 4o a 2-dimensional effect appear in a large diameter facility. Because of this non-uniformity, a CCFL is defined in the present work as the situation where net water accumulation is sustained. That is, some amount of water should not be allowed to penetrate the gap and accumulate over the gap at CCFL criterion. The measured data are presented in the form of Wallis＇type correlation with characteristic length of gap size. It was found that the present correlation is in good agreement with other empirical correlation based on measurements whose test section diameter is close and the gap size is much larger than that of the present test section.

• Journal of the Optical Society of Korea
• /
• 제20권5호
• /
• pp.628-632
• /
• 2016

We studied experimentally and theoretically the vertical range of the confined electric field in the gap area of metamaterials, which was analyzed for various gap widths using terahertz time-domain spectroscopy. We measured the resonant frequency as a function of the thickness of poly(methyl methacrylate) in the range 0 to 3.2 μm to quantify the effective detection volumes. We found that the effective vertical range of the metamaterial is determined by the size of the gap width. The vertical range was found to decrease as the gap width of the metamaterial decreases, whereas the sensitivity is enhanced as the gap width decreases due to the highly concentrated electric field. Our experimental findings are in good agreement with the finite-difference time-domain simulation results. Finally, a numerical expression was obtained for the vertical range as a function of the gap width. This expression is expected to be very useful for optimizing the sensing efficiency.

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2004년도 Proceedings of the 4th Korea-China Joint Workshop on Nuclear Waste Management
• /
• pp.238-244
• /
• 2004

The relationship between the leaching and gap inventory of spent fuel has been studied. When a specimen of J44H08 spent PWR fuel with 38 GWD/MTU has been leached in the synthetic granitic groundwater in Ar atmosphere, the released fraction of cesium was increased rapidly up to 0.7% at around 500 days and stayed below 0.8% until 3 years. This 0.7% of cesium might be released from the gap in this fuel. The measurement of gap inventory with C15I08 spent PWR fuel, having 35 GWD/MTU and 0.22% of fission gas release, was also determined near 0.6% for the cesium, which is a similar fraction of cesium released from the leaching experiment with J44H08 fuel. Its gap inventories of strontium and iodine were about 0.03 and less than 0.2% respectively. Respective fractions of cesium and strontium in grain boundary of C15I08 were 0.78, 0.09%.

• Carbon letters
• /
• 제28권
• /
• pp.72-80
• /
• 2018

In this study, an empirical relationship between the energy band gap of multi-walled carbon nanotubes (MWCNTs) and synthesis parameters in a chemical vapor deposition (CVD) reactor using factorial design of experiment was established. A bimetallic (Fe-Ni) catalyst supported on $CaCO_3$ was synthesized via wet impregnation technique and used for MWCNT growth. The effects of synthesis parameters such as temperature, time, acetylene flow rate, and argon carrier gas flow rate on the MWCNTs energy gap, yield, and aspect ratio were investigated. The as-prepared supported bimetallic catalyst and the MWCNTs were characterized for their morphologies, microstructures, elemental composition, thermal profiles and surface areas by high-resolution scanning electron microscope, high resolution transmission electron microscope, energy dispersive X-ray spectroscopy, thermal gravimetry analysis and Brunauer-Emmett-Teller. A regression model was developed to establish the relationship between band gap energy, MWCNTs yield and aspect ratio. The results revealed that the optimum conditions to obtain high yield and quality MWCNTs of 159.9% were: temperature ($700^{\circ}C$), time (55 min), argon flow rate ($230.37mL\;min^{-1}$) and acetylene flow rate ($150mL\;min^{-1}$) respectively. The developed regression models demonstrated that the estimated values for the three response variables; energy gap, yield and aspect ratio, were 0.246 eV, 557.64 and 0.82. The regression models showed that the energy band gap, yield, and aspect ratio of the MWCNTs were largely influenced by the synthesis parameters and can be controlled in a CVD reactor.

• 대한화학회지
• /
• 제67권3호
• /
• pp.175-180
• /
• 2023

Tetra-aryl substituted A4-type porphyrins (TP, TD, TA) and trans-A2B2 porphyrins (DDP1, AAP1) with electron-donating or withdrawing groups were synthesized. The band gap energy of those porphyrins was calculated from their UV-Vis spectra and CV data. With an electron-withdrawing group, the band gap energy of porphyrin TA increased via the LUMO energy up. Meanwhile, the introduction of an electron-donating group decreased the band gap of porphyrin by HOMO level up as as in the case of porphyrin TD. The band gap (2.19-2.28 eV) of metalloporphyrin PP-Ni was greater than those (1.81-2.06 eV) of non-metalloporphyrins PP due to the LUMO level up.