• Title/Summary/Keyword: emulsion method

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A Study on Polyurethane Treatment of Fabric - Synthesis of Water Dispersing Agent, and Anti-static and Softening Finishing - (직물의 우레탄처리 가공 - 수분산성 가공제의 합성과 대전방지 및 유연가공에 대하여 -)

  • Ahn, Young-Moo
    • Fashion & Textile Research Journal
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    • v.3 no.1
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    • pp.42-47
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    • 2001
  • The hardening system of polyurethanes has usually caused by air pollution. bad working condition and fire hazard according to using orgarnic solvents. Therefore there have been researched on emulsion, water soluble and colloid-dispersion based water soluble instead of using organic solvents recently. This study synthesized polyurethane dispersing particle by means of mixing precursor and neutralized emulsion method. In the first step, polyurethane was preparated from isophorone diisocyanate and poly (ethylene-adipate) glycol, and got precursor by introducing dimethyl propionic acid as a hydrophilic group. Synthesized polyurethane was bonded to the surface of fiber and crosslinked as a anti-static agent, and then looked for the change of color and softening property.

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A Foundamental Study on the Solvent Dyeing Part 2. Dyeing Properties of PET Treated with Water, TCE and water/TCE Emulsion (용제염색에 관한 기초적 연구 제2보 물, TCE 및 물/TCE 처리를 한 PET의 염색성)

  • Chung Doo Jin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.3 no.2
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    • pp.37-41
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    • 1979
  • In order to obtain tasic information for solvent dyeing, polyethylene terephthalate (PET) films was pretreated with water, tetrachloroethylene (TCE) and water/TCE emulsion for three hours at $140^{\circ}C$ for stabilizing the substrate. By film roll cyliderical method, Disperse Red 60, Disperse Yellow 42, and Disperse Blue 27 were diffused in the films and examined dyeing properties. The results are summarized as follows; 1) Diffusion coefficient increases in the order, waterTCE>water/TCE 2) A linear relationship between diffusion coefficient and shrinkage was Observed 3) The temperature dependence of the diffusion coefficient can't be expressed by WLF equation.

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Synthesis of orthorhombic $LiMnO_2$ and its electrochemical properties

  • Kim, Jung-Min;Chung, Hoon-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.2
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    • pp.51-56
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    • 2005
  • We prepared orthorhombic $LiMnO_2$ by emulsion drying method. The thermo-gravimetric measurement and X-ray diffraction studies indicated that the orthorhombic $LiMnO_2$ phase was formed above $800^{\circ}C$ by oxygen evaporation process from $LiMn_2O_4$ and $Li_2MnO_3$. In this process, we could control the ordering of $LiMnO_2$ with heating rate. It was observed that electrochemical properties depended on the ordering of this material; the ordered one exhibited good capacity retention, whereas the disordered one suffered capacity fading upon cycling, especially in the 3 V region. Transmission electron microscopic (TEM) study showed that this difference is related with difference in the stress relieving effects in the samples.

Functional Properties of Sesame Protein Concentrates Produced by Ultrafiltration (한외여과에 의해 제조된 참깨박 농축단백질의 기능적 특성)

  • 전정례;박정룡
    • Journal of the East Asian Society of Dietary Life
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    • v.10 no.5
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    • pp.394-403
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    • 2000
  • The functional properties of sesame protein concentrate(SPC) using different size of ultrafiltration(UF) membranes were examined and compared with those of conventional acid-precipitated sesame protein concentrate. The protein contents of SPC by UF with molecular size of 10K, 30K and look dalton membranes were 84.2%, 82.7%, and 76.4%, respectively, and that of acid-precipitated SPC was 88.7%. The nitrogen solubility of SPC by UF was higher than that of conventional SPC at various pH levels. Especially, it showed three-fold increase at near isoelectric point. However, water absorption capacity and fat absorption capacity of SPC by UF were decreased. For emulsion and foam properties, there were no significant differences between SPC by acid precipitation and SPC by UF method. At various pH levels, SPC by membrane with pore size of 30K dalton showed the highest emulsion properties. The SPC by UF had slightly higher viscosity than defatted sesame flour and SPC by acid precipitation.

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Flame Characteristics of Surface Part of Composite Emulsion Exterior Finishes (복합 에멀젼 외장마감재 표면부의 화염 특성)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Song, Sung-Yong;Kim, Deuck Mo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.133-134
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    • 2019
  • As part of recent low-energy policies, thermal insulation standards for buildings are being tightened every year. The importance of external insulation methods is increasing due to the strengthening of insulation standards. Among the main materials used in the external insulation method, dry bit material is a finishing material composed of an organic binder and aggregate. When the fire occurs, the ignition of the surface part causes a direct fire on the thermal insulation material at the rear side when heat energy is concentrated. Therefore, it is important that the finishing material in dry insulation using a dry bit has a low fire spreading property in case of a fire and does not have a sustained combustion. The purpose of this study was to evaluate the fire spreadability by changing the internal fillers while using alkoxide-based acrylic emulsions, hybrid acrylic emulsions, and general acrylic emulsions in order to suppress the fire spreading properties of exterior finish materials.

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Evaluation of alginate microspheres prepared by emulsion method for protein delivery system

  • Park, Ji-Hyun;Lee, Chang-Moon;Kim, Gwang-Yun;Rhee, Joon-Haeng;Lee, Ki-Young
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.574-578
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    • 2005
  • The purpose of the study is to research the proper conditions to prepare the calcium-alginate microspheres using a emulsion method. The calcium-alginate microspheres were prepared at distinct concentrations (alginate; 1%, 1.5%, 2% (w/v), calcium chloride; 2%, 4%, 8%, 10%(w/v)). The shape of the microspheres prepared was spherical. With increasing alginate and calcium chloride concentration the mean size of the microspheres decreased gradually. In release test, the amount of ovalbumin released from the calcium-alginate mcirospheres was decreased by the increasing of alginate and calcium chloride concentration. In this study the best result was obtained at a 2% of alginate concentration and 10% of calcium chloride concentration.

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Effects of Preparation Method and Evaluations on Structural Integrity in Model Antigen-Containing Biodegradable Microspheres for Vaccine Delivery

  • Cho Seong-Wan;Kim Young-Kwon
    • Biomedical Science Letters
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    • v.12 no.3
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    • pp.177-183
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    • 2006
  • To demonstrate the effect of formulation conditions and evaluations of structural integrity from ovalbumin containing poly lactide glycolide copolymer (PLGA) microspheres for Vaccine delivery, OVA microspheres were prepared by a W/O/W multiple emulsion solvent extraction technique. Dichloromethan (DCM) and Ethyl acetate (EA) were applied as an organic phase and poly vinyl alcohol (PVA) as a secondary emulsion stabilizer. Microspheres were characterized for particle size, morphology (optical microscopy and Scanning Electron Microscope (SEM)). Protein denaturation was evaluated by size exclusion chromatography (SEC), SDS-PAGE and isoelectric focusing (IEF). Residual organic solvent was estimated by gas chromatography (GC) and differential scanning calorimetry (DSC). Optical photomicrograph and SEM revealed that micro spheres were typically spherical but various morphologies were observed. Mean particle size $(d_{vs})$ of microspheres were in the range of $3{\sim}50{\mu}m$. Also, The protein stability was not affected by the fonnulation process and residual organic solvent was beyond the detection below 0.1ppm. These results demonstrated that micro spheres might be a good candidate for the parenteral vaccine delivery system.

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