• Analytical Science and Technology
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• v.23 no.4
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• pp.347-356
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• 2010

Emission characteristics of major offensive odorants were investigated using odor samples collected from two urban stormwater catch basins with highly contrasting environmental conditions. A total of 6 major offensive odorants ($H_2S$, $CH_3SH$, DMS, DMDS, $CH_3CHO$ (AA), and $NH_3$) were measured. For this comparative analysis, odor intensity (OI) of all odorants was derived from their concentration data via empirical equations introduced by Nagata. Both the absolute magnitude of odorant concentrations and their OI values were used concurrently to evaluate the occurrence pattern of each individual odorant. According to our analysis, RSCs including $CH_3SH$, $H_2S$, and DMS tend to exhibit the highest odor strengths among all 6 compounds investigated. The overall results of our study suggest that the emissions of major offensive odorants from urban stormwater catch brains can be explained at least partially by the temporal trend of human activity.

• Proceedings of the KIEE Conference
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• 1997.07e
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• pp.1761-1763
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• 1997

Because of internal voids in insulators give rise to partial discharge (PD), which cause local breakdown and even entire insulation breakdown. Treeing due to PD is one of the main causes of breakdown of the insulating materials and reduction of the insulation life. Therefore the necessity for establishing a method to diagnose the aging of insulation materials and to predict the breakdown of insulation has become important. From this viewpoint, our studies diagnose insulation degradation using the method of computer sensing system, which has the advantages of PD and acoustic emission (AE) sensing system. To use advantages of these two methods can be used effectively to search for treeing location and PD in some materials. In analysis method of degradation, We analyzed the PD pulse and AE pulses by regression analysis, compared to these obtained the correlation coefficient and determination coefficient by T-distribution and saw that PD and AE pulses show a similar pattern on the whole. This is in agreement with the results of the research by Yoshimura and Fujita.

• Korean Journal of Materials Research
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• v.23 no.11
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• pp.661-665
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• 2013

We investigated the characteristics of electroless plated Cu films on screen printed Ag/Anodized Al substrate. Cu plating was attempted using neutral electroless plating processes to minimize damage of the anodized Al substrate; this method used sodium hypophosphite instead of formaldehyde as a reducing agent. The basic electroless solution consisted of $CuSO_4{\cdot}5H_2O$ as the main metal source, $NaH_2PO_2{\cdot}H_2O$ as the reducing agent, $C_6H_5Na_3O_7{\cdot}2H_2O$ and $NH_4Cl$ as the complex agents, and $NiSO_4{\cdot}6H_2O$ as the catalyser for the oxidation of the reducing agent, dissolved in deionized water. The pH of the Cu plating solutions was adjusted using $NH_4OH$. According to the variation of pH in the range of 6.5~8, the electroless plated Cu films were coated on screen printed Ag pattern/anodized Al/Al at $70^{\circ}C$. We investigated the surface morphology change of the Cu films using FE-SEM (Field Emission Scanning Electron Microscopy). The chemical composition of the Cu film was determined using XPS (X-ray Photoelectron Spectroscopy). The crystal structures of the Cu films were investigated using XRD (X-ray Diffraction). Using electroless plating at pH 7, the structures of the plated Cu-rich films were typical fcc-Cu; however, a slight Ni component was co-deposited. Finally, we found that the formation of Cu film plated selectively on PCB without any lithography is possible using a neutral electroless plating process.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.494-500
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• 2014

Indium-doped zinc oxide nanocrystals (IZO NCs), capped with stearic acid (SA) of different sizes, were synthesized using a hot injection method in a noncoordinating solvent 1-octadecene (ODE). The ligand exchange process was employed to modify the surface of IZO NCs by replacing the longer-chain ligand of stearic acid with the shorter-chain ligand of butylamine (BA). It should be noted that the ligand-exchange percentage was observed to be 75%. The change of particle size, morphology, and crystal structures were obtained using a field emission scanning electron microscope (FE-SEM) and X-ray diffraction pattern results. In our study, the 5 nm and 10 nm IZO NCs capped with stearic acid (SA-IZO) were ligand-exchanged with butylamine (BA), and were then spin-coated on a thermal oxide ($SiO_2$) gate insulator to fabricate a thin film transistor (TFT) device. The films were then annealed at various temperatures: $350^{\circ}C$, $400^{\circ}C$, $500^{\circ}C$, and $600^{\circ}C$. All samples showed semiconducting behavior and exhibited n-channel TFT. Curing temperature dependent on mobility was observed. Interestingly, mobility decreases with the increasing size of NCs from 5 to 10 nm. Miller-Abrahams hopping formalism was employed to explain the hopping mechanism insight our IZO NC films. By focusing on the effect of size, different curing temperatures, electron coupling, tunneling rate, and inter-NC separation, we found that the decrease in electron mobility for larger NCs was due to smaller electronic coupling.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.1
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• pp.22-26
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• 2008

Red long persistent phosphors of $CaZrO_3$ : Pr was synthesized by a solid reaction method. $CaCO_3\;and\;ZrO_2$ were used as hosting materials and Pr was doped as luminescence center element, and $B_2O_3$ was used as flux. The XRD pattern confirmed crystalline phase of the phosphor, and photoluminescence investigation showed emission spectrum at $480{\sim}570nm\;and\;590{\sim}700nm$. Phosphor samples were synthesized with $B_2O_3$ flux concentration of 1, 5, 10%, and luminescent peak of maximum intensity at 494 nm was obtained for 1% $B_2O_3$. Luminescent peak of red color at 620 nm was of highest intensity for 10% $B_2O_3$.

• Journal of Hydrogen and New Energy
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• v.23 no.4
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• pp.412-419
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• 2012

Increasing demand for natural gas and higher natural gas prices in the recent decades have led many people to pursue unconventional methods of natural gas production. POSCO-Gwangyang synthetic natural gas (SNG) project was launched in 2010. As the market price of natural gas goes up, the increase of its price gets more sensitive due to the high cost of transportation and liquefaction. This project can make the SNG economically viable. In parallel with this project, KEPCO (Korea Electric Power Corporation) joined in launching the SNG Quality Standard Bureau along with KOGAS (Korea Gas Corporation), POSCO and so on. KEPCO Research Institute is in charge of SNG fueled gas turbine combustion test. In this research, several combustion tests were conducted to find out the effect of hydrogen contents in SNG on gas turbine combustion. The hydrogen in synthetic natural gas did not affect on gas turbine combustion characteristics which are turbine inlet temperature including pattern factor and emission performance. However, flame stable region in ${\Phi}$-Air flow rate map was shifted to the lean condition due to autocatalytic effect of hydrogen.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.5
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• pp.60-69
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• 2013

An optimum configuration of the hybrid/dual swirl jet combustor for a micro-gas turbine was investigated experimentally. Location of pilot nozzle, angle and direction of swirler vane were varied systematically as main parameters under the conditions of constant thermal load. The results showed that the variation in locations of inner fuel nozzle and pilot burner resulted in significant change in flame shape and swirl intensity due to the changes in recirculating flow pattern and minimum flow area near burner exit, in particular, with the significant reduction of CO emission near lean-flammability limit. In addition, it was observed that the co-swirl configuration produced less CO and NOx emissions compared to the counter-swirl configuration.

• Journal of Environmental Science International
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• v.27 no.7
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• pp.611-620
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• 2018

In this study, a metal-organic framework (MOF) material $NH_2$-MIL-101(Fe) was synthesized using the solvothermal method, and characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), UV-visible spectrophotometry, field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and surface area measurements. The XRD pattern of the synthesized $NH_2$-MIL-101(Fe) was similar to the previously reported patterns of MIL-101 type materials, which indicated the successful synthesis of $NH_2$-MIL-101(Fe). The FT-IR spectrum showed the molecular structure and functional groups of the synthesized $NH_2$-MIL-101(Fe). The UV-visible absorbance spectrum indicated that the synthesized material could be activated as a photocatalyst under visible light irradiation. FE-SEM and TEM images showed the formation of hexagonal microspindle structures in the synthesized $NH_2$-MIL-101(Fe). Furthermore, the EDS spectrum indicated that the synthesized material consisted of Fe, N, O, and C elements. The synthesized $NH_2$-MIL-101(Fe) was then employed as an adsorbent and photocatalyst for the removal of Indigo carmine and Rhodamine B from aqueous solutions. The initial 30 min of adsorption for Indigo carmine and Rhodamine B without light irradiation achieved removal efficiencies of 83.6% and 70.7%, respectively. The removal efficiencies thereafter gradually increased with visible light irradiation for 180 min, and the overall removal efficiencies for Indigo carmine and Rhodamine B were 94.2% and 83.5%, respectively. These results indicate that the synthesized MOF material can be effectively applied as an adsorbent and photocatalyst for the removal of dyes.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.2
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• pp.357-361
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• 2011

The terminal current in voltage driven systems is an essential role for characterizing the pattern of electric discharge such as corona, breakdown, etc. Until now, to evaluate this terminal current, Sato's equation has been widely used in areas of high voltage and plasma discharge. Basically Sato's equation was derived by using the energy balance equation and its final form described physical meaning explicitly. To give more general abilities in Sato's equation, we present a generalized approach by directly using the Poynting's theorem incorporating the finite element method. When the magnetic field effect or the time-dependent voltage source is considered, this generalized energy method can be easily applicable to those problems with any dielectric media such as gas, fluid, and solid. As an alternative approach, the integral Ohm's law resulting in small numerical errors has an ability to be applied to multi-port systems. To test the generalized energy method and integral Ohm's law, first, the results from two prosed methods were compared to those from Sato's approach and an analytic solution in parallel plane electrodes. After verification, the generalized method was applied to the tip-sphere electrodes for evaluating the terminal current with three carriers and the Fowler-Nordheim field emission condition. From these results, we concluded that the generalized energy method can be a consistent technique for evaluating the discharge current with various dielectric materials or large magnetic field.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.13 no.1
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• pp.39-45
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• 1999

Because of internal voids in insulators give rise to partial discharge(PD), which cause local breakdown and even entire insulation breakdown. Treeing due to PD is one of the main causes of breakdown of the insulating materials and nrluction of the insulation life. 1berefore the necessity for establishing a rrethod to diagnose the aging of insulation materials and to predict the breakdown of insulation has becorne irrportant. From this viewpoint, our studies diagnose insulation degradation using the rrethod of computer sensing system, which has PD and acoustic emission(AE) sensing system. To use advantages of these two methods can be used effectiveiy to search for treeing location and PD in sorre materials. In analysis rrethod of degradation, we analyzed the PD and AE pulses by regression analysis, corrpared to these obtained the correlation coefficient and retermination coefficient by T-distribution and saw that PD and AE pulses show a similar pattern on the whole. This has a similar teIlrency to the results of the research by Yoshimura and Fujita.Fujita.