• Title/Summary/Keyword: emission pattern

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Integrated Environment Impact Assessment of Brick Kiln using Environmental Performance Scores

  • Pokhrel, Rajib;Lee, Heekwan
    • Asian Journal of Atmospheric Environment
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    • v.8 no.1
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    • pp.15-24
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    • 2014
  • The capital city of Himalayan Country Nepal, Kathmandu Valley is surrounded by consecutive high mountains, which limits the air distribution and mixing effects significantly. It in turn generates steady air flow pattern over a year except in monsoon season. The air shed in the Valley is easily trapped by the surrounded mountains and the inversion layer formulated as the cap. The $PM_{10}$ concentration was noticeably higher than the standard level (120 ${\mu}g/m^3$) in urban and suburban area of Kathmandu valley for all seasons except monsoon period. The Valley area experiences similar wind patterns (W, WWS, and S) for a year but the Easterly wind prevails only during the monsoon period. There was low and calm wind blows during the winter season. Because of this air flow structure, the air emission from various sources is accumulated within the valley air, high level of air pollution is frequently recorded with other air polluted cities over the world. In this Valley area, brick kilns are recognized as the major air pollution source followed by vehicles. Mostly Bull Trench Kiln (BKT), Hoffman Kiln and Vertical Shaft Brick Kiln (VSBK) are in operation for brick firing in Kathmandu valley where the fuels such as crushed coal, saw dust, and natural gas are used for processing bricks in this study. Tool for the Reduction and Assessment of Chemical and Other Environmental Impacts (TRACI) was used for screening and quantifying the potential impacts of air emission from firing fuels. The total Environmental Performance Score (EPS) was estimated and the EPS of coal was approximately 2.5 times higher than those of natural gas and saw dust. It is concluded that the crushed coal has more negative impact to the environment and human health than other fuel sources. Concerning the human health and environment point of view, alternative environment friendly firing fuel need to be used for brick industry in the kiln and the air pollution control devices also need to be applied for minimizing the air emissions from the kilns.

Agent-Based Modeling and Design of Water Reuse Network in Eco-Industrial Park (EIP) (생태산업단지에서 용수재이용 네트워크의 에이전트 기반 모델링 및 설계)

  • Kim, HyunJoo;Yoo, ChangKyoo;Ryu, Jun-Hyung;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.369-375
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    • 2008
  • To achieve zero-emission, one of the main goals of an eco-industrial park (EIP), it is needed to develop an effective water exchange network. The network includes various subsystems and decision making processes, which make the modeling process extremely complicated. Agent-based modeling was used to simulate water exchange network in an EIP. Firm agents were created based on the behavior pattern of firms, and an agent-based model (ABM) was made with the agents, showing the growth of the exchange network. An existing steel and iron making industrial park was chosen as a case study, and the ABM model shows eco-efficient behavior with a decreased environmental cost. Water reuse network based on the ABM model results in 35% decrease of the fresh water supply and 50% reduction of the wastewater generation in EIP. A case study shows that agent-based model can be a powerful tool in modeling and designing complex eco-industrial parks, especially when a part of the system needs to be changed.

STRATOSPHERIC IMAGES OF JUPITER DERIVED FROM HYDROCARBON EMISSIONS IN VOYAGER 1 AND 2 IRIS SPECTRA

  • Seo, Haing-Ja;Kim, Sang-Joon;Choi, W.K.;Kostiuk, T.;Bjoraker, G.
    • Journal of The Korean Astronomical Society
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    • v.38 no.4
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    • pp.471-478
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    • 2005
  • Spectroscopic data obtained by the Infrared Interferometer Spectrometer (IRIS) aboard Voyager 1 and 2 have been re-visited. Using the spectroscopic data and footprints of the IRIS aperture on the planet, we constructed images of the stratosphere of Jupiter at the emission bands of hydrocarbons including $CH_4,\;C_2H_6,\;C_2H_2,\;C_3H_4,\;C_6H_6$, and $C_2H_4$. Thermal emission from the hydrocarbons on Jupiter originates from a broad region of the stratosphere extending from 1 to 10 millibars. We averaged the data using a bin of 20 degrees of longitude and latitudes in order to increase signal-to-noise ratios. The resultant images show interesting wave structure in Jupiter's stratosphere. Fourier transform analyses of these images yield wavenumbers 5 - 7 at mid-Northern and mid-Southern latitudes, and these results are different from those resulted from previous ground-based observations and recent Cassini CIRS, suggesting temporal variations on the stratospheric infrared pattern. The comparisons of the Voyager 1 and 2 spectra also show evidence of temporal intensity variations not only on the infrared hydrocarbon polar brightenings of hydrocarbon emissions but also on the stratospheric infrared structure in the temperate regions of Jupiter over the 4 month period between the two Voyager encounters. Short running title: Stratospheric Images of Jupiter derived from Voyager IRIS Spectra.

Different Types of Active Region EUV Bright Points by Hinode/EIS

  • Lee, Kyoung-Sun;Moon, Yong-Jae;Kim, Su-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.28.2-28.2
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    • 2010
  • We have investigated seven Extreme-Ultraviolet (EUV) bright points in the active region (AR 10926) on 2006 December 2 by the EUV imaging spectrometer (EIS) onboard Hinode spacecraft. We determined their Doppler velocities and non-thermal velocities from 15 EUV spectral lines (log T=4.7-7.2) by fitting each line profile to a Gaussian function. We present the Doppler velocity map as a function of temperature which corresponds to a different height. As a result, these active region bright points show two different types of characteristics. Type 1 bright point shows a systematic increase of Doppler velocity from -68 km/s (blue shift) at log T=4.7 to 27 km/s (red shift) at log T=6.7, while type 2 bright points have Doppler velocities in the range of -20 km/s and 20 km/s. Using MDI magnetograms, we found that only type 1 bright point was associated with the canceling magnetic feature at the rate of $2.4{\times}10^{18}$ Mx/hour. When assuming that these bright points are caused by magnetic reconnection and the Doppler shift indicates reconnection out flow, the pattern of the Doppler shift implies that type 1 bright point should be related to low atmosphere magnetic reconnection. We also determined electron densities from line ratio as well as temperatures from emission measure loci using CHIANTI atomic database. The electron densities of all bright points are comparable to typical values of active regions (log Ne=9.9-10.4). For the temperature analysis, the emission loci plots indicate that these bright points should not be isothermal though background is isothermal. The DEM analysis also show that while the background has a single peak distribution (isothermal), the EUV bright points, double peak distributions.

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Preparation and Properties of Eu3+ Doped Y2O3 Nanoparticles with a Solvothermal Synthesis Using the Ethylene Glycol (에틸렌 글리콜을 이용하여 용매열 합성으로 Eu3+가 도핑된 Y2O3 나노 입자의 제조 및 특성)

  • 신수철;조태환
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.709-714
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    • 2003
  • Eu doped $Y_2$ $O_3$ nanoparticles were prepared with the solvothermal synthesis using the ethyleneglycol solvent at 20$0^{\circ}C$ for 3-5 h and then annealed in air at 1000-140$0^{\circ}C$ for 2-4 h. The X-ray diffraction pattern of annealed crystals at 100$0^{\circ}C$ for 2 h could be indexed as pure cubic cell of $Y_2$ $O_3$ phase with lattice parameters a=10.5856 $\AA$ which is very close to the reported data (JCPDS Card File, 41-1105 a=10.6041 $\AA$). Average size of prepared phosphor particles have about 100 nm, which were spherical morphology. The phosphor particle sizes decreased and the emission intensity increased at the annealing temperature. Though PL spectrum analysis, the 3% Eu doped $Y_{2-x}$ $O_3$:E $u_{x}$ $^{3+}$(x=0.06) phosphor showed the excitation spectrum at 250 nm wavelength and the maximum emission spectrum at 611 nm wavelength.

Electroluminescent Properties of White Light-Emitting Device Using Photoconductive Polymer and Anthracene Derivatives (광전도성 고분자와 안트라센 유도체를 이용한 백색 전계발광소자의 발광 특성)

  • Lee Jeong-Hwan;Choi Hee-Lack;Lee Bong
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.543-547
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    • 2005
  • Organic electroluminescence devices were made from 1,4-bis-(9-anthrylvinyl)benzene (AVB) and 1,4-bis-(9-aminoanthryl)benzene (AAB) anthracene derivatives. Device structure was ITO/AVB/PANI(EB)/Al (multi-layer device) and ITO/AAB:DCM/Al(single-layer device). In these devices, AVB, polyaniline(emeraldine base) (PANI(EB)) and AAB were used as the emitting material. 4-(dicyanomethylene)-2-methyl-6-p-(dimethylamino)styryl-4H -pyran(DCM) was used as red fluorescent dopant. We studied change of fluorescence wavelength with concentration of DCM doped in AAB. The ionization potential (IP) and optical band gap (Eg) were measured by cyclic voltammetry and UV-visible spectrum. We compared with difference of emitting wavelength between photoluminescence and electroluminescence spectrum. In case of the multi-layer device, PANI and AVB EL spectra have similar wave pattern to each PL spectrum and when PAM and AVB were used at the same time, and multi-layer device showed that a balanced recombination and radiation kom PANI and AVB. In case of the single-layer device, with the increase of DCM concentration, the blue emission decreases and red emission increases. This indicates that DCM was excited by the energy transfer from AAB to DCM or the direct recombination at the dopant sites due to carrier trapping, or both. The device with $1.0wt\%$ DCM concentration gave white light.

Characteristics of Corrosion Damages in Bottom Plate of Above Ground Tank by Acoustic Emission Signal (지상탱크 저판부의 부식손상 평가를 위한 음향방출 신호의 분석)

  • Kim, Sung-Dai;Jung, Woo-Gwang;Lee, Jong-O
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.64-72
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    • 2007
  • Under the AE methods, the valid condition analysis and evaluation the leak etc, resulted by the AE signal pattern on the bottom plate of ground tank at full. In next more, the gradient of accumulation amplitude distribution analysis and comparison the energy, count, and duration time that noise of EMI signal were removed. EMI signal showed height-energy, count, and duration time, it also appeared great gradient of accumulation distribution. Then, with the pure remaining AE signals cluster analysis and location. It would possibly assume of damage with corrosion. Total cluster 20 and energy showed between the maximum 11,990 and 8,565 which is much lower than above figure and event number showed from 8 to 5. Even when it difficult to certify damage by open, as it is raised higher height-sensitivity and threshold by 60 dB. It would possibly presume of location source more accurately.

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Study on the Current Spreading Effect of Blue GaN/InGaN LED using 3-Dimensional Circuit Modeling (3차원의 회로 모델링을 이용한 청색 GaN/InGaN LED의 전류 확산 효과에 관한 연구)

  • Hwang, Sung-Min;Shim, Jong-In
    • Korean Journal of Optics and Photonics
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    • v.18 no.2
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    • pp.155-161
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    • 2007
  • A new and simple method of 3-dimensional circuit modeling and analysis is proposed and verified experimentally for the first time by determining 3-dimensional current flow and 2-dimensional light distribution in blue InGaN/GaN multi-quantum well (MQW) light emitting diode (LED) devices. Circuit parameters of the LED consist of the resistance of the metallic film and epitaxial layer, and the intrinsic diode which represents the active region emitting the light. The circuit parameters are extracted from the transmission line model (TLM) and current-voltage relation. We applied the >> proposed method and extracted circuit parameters to obtain the light emission pattern in a top-surface emitting-type LED. The current spreading effect is analyzed theoretically and quantitatively with a variation of the resistance of metallic and epitaxial layers. The emitting-light distribution of the fabricated blue LED showed a good agreement with the analyzed result, which shows the dark emission intensity at the corner of the p-electrode.

Layered Metal Hydroxides Containing Calcium and Their Structural Analysis

  • Kim, Tae-Hyun;Heo, Il;Paek, Seung-Min;Park, Chung-Berm;Choi, Ae-Jin;Lee, Sung-Han;Choy, Jin-Ho;Oh, Jae-Min
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1845-1850
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    • 2012
  • Layered metal hydroxides (LMHs) containing calcium were synthesized by coprecipitation in solution having two different trivalent metal ions, iron and aluminum. Two mixed metal solutions ($Ca^{2+}/Al^{3+}$ and $Ca^{2+}/Fe^{3+}$ = 2/1) were added to sodium hydroxide solution and the final pH was adjusted to ~11.5 and ~13 for CaAl-and CaFe-LMHs. Powder X-ray diffraction (XRD) for the two LMH samples showed well developed ($00l$) diffractions indicating 2-dimensional crystal structure of the synthesized LMHs. Rietveld refinement of the X-ray diffraction pattern, the local structure analysis through X-ray absorption spectroscopy, and thermal analysis also confirmed that the synthesized precipitates show typical structure of LMHs. The chemical formulae, $Ca_{2.04}Al_1(OH)_6(NO_3){\cdot}5.25H_2O$ and $Ca_{2.01}Fe_1(OH)_6(NO_3){\cdot}4.75H_2O$ were determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Particle morphology and thermal behavior for the synthesized LMHs were examined by field emission scanning electron microscopy and thermogravimetricdifferential scanning calorimetry.

Toxic Effects and Distribution of Mercury in Barley Seedlings (보리 유식물에 처리한 수은의 분포 및 독성 연구)

  • 이춘환;장호식
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.13-21
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    • 1992
  • The inhibitory effects of mercury ions on the growth of barley seedlings were studied and the distribution of metal elements in the organs of treated plants was investigated by using synchrotron radiation induced X-ray emission (SRIXE). Although the treatment of mercury ions caused growth inhibition, the mercury-specific increase in variable fluorescence and the abolishment of energy-dependent quenching in broken barley chloroplasts as shown by Moon et at. (1992) were not observed in the leaves of growth-inhibited seedlings. Instead the treatment of mercury decreased Fmax and Fo values. However, Fmax/Fo ratio and photochemical and nonphotochemical quenching coefficients were not affected significantly. By SRIXE analysis of $10\mu\textrm{m}$ mercury chloride treated seedlings, accumulation of mercury in roots was observed after 1 hour of treatment and similar concentration was sustained for 48 hours. Relative contents of mercury was high in roots and underground nodes where seeds were attachedl but was very low in leaves. Iron and zinc were also distributed mainly in the lower parts of the seedlings. However after 72 hours of treatment the contents of these metals in roots decreased and their distribution became more uniform, which may lead to death of the plants. These results suggest that the observed inhibitory effects on barley seedlings upto 48 hours after the treatment is not due to direct damages in the photosynthetic apparatus, but due to its accumulation in roots and the consequent retardation of the growth of barley seedlings. The decrease in Fmax and Fo is probably due to the decrease in chlorophyll and protein contents caused by the retardation of growth. The observed slow expansion of primary leaves could be also explained by the retardation of growth, but the fluorescence induction pattern from the leaves did not show characteristic symptoms of leaves under water stress.

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